Molecular Gel as Medium or Intermediate in Functional Materials Synthesis

2021 ◽  
pp. 1-19
Author(s):  
Rong Miao ◽  
Junxia Peng
Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1364
Author(s):  
M. Carmen Herrera-Beurnio ◽  
Jesús Hidalgo-Carrillo ◽  
Francisco J. López-Tenllado ◽  
Juan Martin-Gómez ◽  
Rafael C. Estévez ◽  
...  

In the last few years, researchers have focused their attention on the synthesis of new catalyst structures based on or inspired by nature. Biotemplating involves the transfer of biological structures to inorganic materials through artificial mineralization processes. This approach offers the main advantage of allowing morphological control of the product, as a template with the desired morphology can be pre-determined, as long as it is found in nature. This way, natural evolution through millions of years can provide us with new synthetic pathways to develop some novel functional materials with advantageous properties, such as sophistication, miniaturization, hybridization, hierarchical organization, resistance, and adaptability to the required need. The field of application of these materials is very wide, covering nanomedicine, energy capture and storage, sensors, biocompatible materials, adsorbents, and catalysis. In the latter case, bio-inspired materials can be applied as catalysts requiring different types of active sites (i.e., redox, acidic, basic sites, or a combination of them) to a wide range of processes, including conventional thermal catalysis, photocatalysis, or electrocatalysis, among others. This review aims to cover current experimental studies in the field of biotemplating materials synthesis and their characterization, focusing on their application in heterogeneous catalysis.


Nanophotonics ◽  
2017 ◽  
Vol 6 (5) ◽  
pp. 881-921 ◽  
Author(s):  
Alberto Escudero ◽  
Ana I. Becerro ◽  
Carolina Carrillo-Carrión ◽  
Nuria O. Núñez ◽  
Mikhail V. Zyuzin ◽  
...  

AbstractRare earth based nanostructures constitute a type of functional materials widely used and studied in the recent literature. The purpose of this review is to provide a general and comprehensive overview of the current state of the art, with special focus on the commonly employed synthesis methods and functionalization strategies of rare earth based nanoparticles and on their different bioimaging and biosensing applications. The luminescent (including downconversion, upconversion and permanent luminescence) and magnetic properties of rare earth based nanoparticles, as well as their ability to absorb X-rays, will also be explained and connected with their luminescent, magnetic resonance and X-ray computed tomography bioimaging applications, respectively. This review is not only restricted to nanoparticles, and recent advances reported for in other nanostructures containing rare earths, such as metal organic frameworks and lanthanide complexes conjugated with biological structures, will also be commented on.


2020 ◽  
Vol 73 (7) ◽  
pp. 587
Author(s):  
Sitong Guo ◽  
Wen Tan ◽  
Jiyicheng Qiu ◽  
Jinlong Du ◽  
Zhanxu Yang ◽  
...  

As a popular material synthesis method, spatially confined reactions have been gradually recognised for their excellent performance in the field of current materials synthesis. In recent years, molybdenum-based catalysts have gradually gained recognition due to high natural reserves of Mo, its low cost, and many other advantages, and they have wide applications in the area of functional materials, especially in topical areas such as batteries and electrocatalysts. In this context, spatially confined reactions have become widely to obtain various types of molybdenum-based electrode materials and electrocatalysts which result in an excellent morphology, structure, and performance. In this review, the concept of a spatially confined reaction system and the electrochemical application (electrode materials and electrocatalyst) of molybdenum-based materials synthesised in this way are comprehensively discussed. The current problems and future development and application of molybdenum-based materials are also discussed in this review.


Crystals ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 12 ◽  
Author(s):  
Mathieu Gonidec ◽  
Josep Puigmartí-Luis

Materials science is a fast-evolving area that aims to uncover functional materials with ever more sophisticated properties and functions. For this to happen, new methodologies for materials synthesis, optimization, and preparation are desired. In this context, microfluidic technologies have emerged as a key enabling tool for a low-cost and fast prototyping of materials. Their ability to screen multiple reaction conditions rapidly with a small amount of reagent, together with their unique physico-chemical characteristics, have made microfluidic devices a cornerstone technology in this research field. Among the different microfluidic approaches to materials synthesis, the main contenders can be classified in two categories: continuous-flow and segmented-flow microfluidic devices. These two families of devices present very distinct characteristics, but they are often pooled together in general discussions about the field with seemingly little awareness of the major divide between them. In this perspective, we outline the parallel evolution of those two sub-fields by highlighting the key differences between both approaches, via a discussion of their main achievements. We show how continuous-flow microfluidic approaches, mimicking nature, provide very finely-tuned chemical gradients that yield highly-controlled reaction–diffusion (RD) areas, while segmented-flow microfluidic systems provide, on the contrary, very fast homogenization methods, and therefore well-defined super-saturation regimes inside arrays of micro-droplets that can be manipulated and controlled at the milliseconds scale. Those two classes of microfluidic reactors thus provide unique and complementary advantages over classical batch synthesis, with a drive towards the rational synthesis of out-of-equilibrium states for the former, and the preparation of high-quality and complex nanoparticles with narrow size distributions for the latter.


Author(s):  
Karthik Pushpavanam ◽  
Jinrong Ma ◽  
Yifeng Cai ◽  
Nada Y. Naser ◽  
François Baneyx

There is considerable interest in the development of hybrid organic–inorganic materials because of the potential for harvesting the unique capabilities that each system has to offer. Proteins are an especially attractive organic component owing to the high amount of chemical information encoded in their amino acid sequence, their amenability to molecular and computational (re)design, and the many structures and functions they specify. Genetic installation of solid-binding peptides (SBPs) within protein frameworks affords control over the position and orientation of adhesive and morphogenetic segments, and a path toward predictive synthesis and assembly of functional materials and devices, all while harnessing the built-in properties of the host scaffold. Here, we review the current understanding of the mechanisms through which SBPs bind to technologically relevant interfaces, with an emphasis on the variables that influence the process, and highlight the last decade of progress in the use of solid-binding proteins for hybrid and hierarchical materials synthesis. Expected final online publication date for the Annual Review of Chemical and Biomolecular Engineering, Volume 12 is June 2021. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.


2009 ◽  
Vol 81 (12) ◽  
pp. 2265-2307 ◽  
Author(s):  
Xiao-Yu Yang ◽  
Yu Li ◽  
Arnaud Lemaire ◽  
Jia-Guo Yu ◽  
Bao-Lian Su

Hierarchically porous materials displaying multimodal pore sizes are desirable for their improved flow performance coupled with high surface areas. In the last five years, a tremendous amount of research has focused upon the synthesis and applications of hierarchically porous materials. This review aims to open up a new avenue of research in this exciting field. At first, recent progress in the synthesis of hierarchically porous materials, targeted through templating methods, is reviewed. These synthesis methods involve a supermolecular assembly of amphiphilic polymers or surfactants combined with second surfactant systems or with macrotemplates such as solid particles, liquid drops, and air bubbles. The preparation procedures using surfactants combined with other chemical or physical methods, controlled phase-separation, or template replication will also be discussed. Subsequently, an innovative procedure concerning the self-formation of hierarchically porous materials is thoroughly examined. This self-formation procedure is based on a self-generated porogen mechanism. Porogens such as alcohol molecules can be precisely controlled at the molecular level to design new hierarchically porous materials. Most of these synthesis methods allow an easy and independent adjustment to the multiporosity of a material, i.e., its micro-, meso-, and macroporosity.


2016 ◽  
Vol 7 (3) ◽  
pp. 1674-1689 ◽  
Author(s):  
Thomas H. Epps, III ◽  
Rachel K. O'Reilly

In this perspective, we survey recent advances in the synthesis and characterization of block copolymers, discuss several key materials opportunities enabled by block copolymers, and highlight some of the challenges that currently limit further realization of block copolymers in promising nanoscale applications.


Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 394 ◽  
Author(s):  
Michelina Catauro ◽  
Federico Barrino ◽  
Giovanni Dal Poggetto ◽  
Giuseppina Crescente ◽  
Simona Piccolella ◽  
...  

The sol–gel route represents a valuable technique to obtain functional materials, in which organic and inorganic members are closely connected. Herein, four hybrid materials, containing caffeic acid entrapped in a silica matrix at 5, 10, 15, and 20 wt.%, were synthesized and characterized through Fourier-Transform Infrared (FT-IR) and Ultraviolet-Visible (UV–Vis) spectroscopy. FT-IR analysis was also performed to evaluate the ability to induce the hydroxyapatite nucleation. Despite some structural changes occurring on the phenol molecular skeleton, hybrid materials showed scavenging properties vs. 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical and 2,2′-azinobis-(3-ethylbenzothiazolin-6-sulfonic acid) radical cation (ABTS•+), which was dependent on the tested dose and on the caffeic acid wt.%. The SiO2/caffeic acid materials are proposed as valuable antibacterial agents against Escherichia coli and Enterococcus faecalis.


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