Nearly 100% Internal Quantum Efficiency in an Organic Blue-Light Electrophosphorescent Device Using a Weak Electron Transporting Material with a Wide Energy Gap

2009 ◽  
Vol 21 (12) ◽  
pp. 1271-1274 ◽  
Author(s):  
Lixin Xiao ◽  
Shi-Jian Su ◽  
Yuya Agata ◽  
Hsinglin Lan ◽  
Junji Kido
1970 ◽  
Vol 17 (2) ◽  
pp. 125-131 ◽  
Author(s):  
Maira INDRIKOVA ◽  
Janis LATVELS ◽  
Inta MUZIKANTE ◽  
Baiba TUROVSKA

A sandwich type structure of two dimetilaminobenziliden-1,3-indandione (DMABI) derivatives placed between metal electrodes was made to investigate the photoelectrical properties of these derivatives. DMABI is an organic isolator with a wide energy gap and high quantum efficiency of the photogeneration, DMABI derivatives have received also considerable attention because of its large dipole moment and optical nonlinearities. Besides, since it is a photosensitive material, its use in solar systems is very promising. The energy gap of each material and combined system was observed from the spectral dependence of the quantum efficiency of the photoconductivity and results are compared with results of oxidation and reduction potential of the materials. The values showed a good correlation between experimental data of the photoconductivity and voltamperometry and calculated data of the HOMO and LUMO levels of the molecules.http://dx.doi.org/10.5755/j01.ms.17.2.480


2013 ◽  
Vol 34 (1) ◽  
pp. 66-72
Author(s):  
赵芳 ZHAO Fang ◽  
张运炎 ZHANG Yun-yan ◽  
宋晶晶 SONG Jing-jing ◽  
丁彬彬 DING Bin-bin ◽  
范广涵 FAN Guang-han

2009 ◽  
Vol 97 (3) ◽  
pp. 705-708 ◽  
Author(s):  
S.-H. Yen ◽  
M.-C. Tsai ◽  
M.-L. Tsai ◽  
Y.-J. Shen ◽  
T.-C. Hsu ◽  
...  

2021 ◽  
Vol 10 (1) ◽  
Author(s):  
Alessandro Minotto ◽  
Ibrahim Bulut ◽  
Alexandros G. Rapidis ◽  
Giuseppe Carnicella ◽  
Maddalena Patrini ◽  
...  

AbstractThe energy gap law (EG-law) and aggregation quenching are the main limitations to overcome in the design of near-infrared (NIR) organic emitters. Here, we achieve unprecedented results by synergistically addressing both of these limitations. First, we propose porphyrin oligomers with increasing length to attenuate the effects of the EG -law by suppressing the non-radiative rate growth, and to increase the radiative rate via enhancement of the oscillator strength. Second, we design side chains to suppress aggregation quenching. We find that the logarithmic rate of variation in the non-radiative rate vs. EG is suppressed by an order of magnitude with respect to previous studies, and we complement this breakthrough by demonstrating organic light-emitting diodes with an average external quantum efficiency of ~1.1%, which is very promising for a heavy-metal-free 850 nm emitter. We also present a novel quantitative model of the internal quantum efficiency for active layers supporting triplet-to-singlet conversion. These results provide a general strategy for designing high-luminance NIR emitters.


Photonics ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 196
Author(s):  
Tsung-Chi Hsu ◽  
Yu-Tsai Teng ◽  
Yen-Wei Yeh ◽  
Xiaotong Fan ◽  
Kuo-Hsiung Chu ◽  
...  

High-quality epitaxial layers are directly related to internal quantum efficiency. The methods used to design such epitaxial layers are reviewed in this article. The ultraviolet C (UVC) light-emitting diode (LED) epitaxial layer structure exhibits electron leakage; therefore, many research groups have proposed the design of blocking layers and carrier transportation to generate high electron–hole recombination rates. This also aids in increasing the internal quantum efficiency. The cap layer, p-GaN, exhibits high absorption in deep UV radiation; thus, a small thickness is usually chosen. Flip chip design is more popular for such devices in the UV band, and the main factors for consideration are light extraction and heat transportation. However, the choice of encapsulation materials is important, because unsuitable encapsulation materials will be degraded by ultraviolet light irradiation. A suitable package design can account for light extraction and heat transportation. Finally, an atomic layer deposition Al2O3 film has been proposed as a mesa passivation layer. It can provide a low reverse current leakage. Moreover, it can help increase the quantum efficiency, enhance the moisture resistance, and improve reliability. UVC LED applications can be used in sterilization, water purification, air purification, and medical and military fields.


2021 ◽  
Vol 237 ◽  
pp. 118165
Author(s):  
Linyan Fu ◽  
Yunlong Yang ◽  
Yi Zhang ◽  
Xuefei Ren ◽  
Yingjie Zhu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document