scholarly journals Interface‐Structure‐Modulated CuF 2 /CF x Composites for High‐Performance Lithium Primary Batteries

Author(s):  
Lidong Sun ◽  
Cong Peng ◽  
Lingchen Kong ◽  
Yu Li ◽  
Wei Feng
2020 ◽  
Author(s):  
Ruichao Pang ◽  
Pengfei Tian ◽  
Hongliang Jiang ◽  
Minghui Zhu ◽  
Xiaozhi Su ◽  
...  

Abstract Unveiling the structural evolution and working mechanism of catalysts under realistic operating conditions is crucial for the design of efficient electrocatalysts for CO2 electroreduction, yet remains highly challenging. Here, by virtue of operando structural measurements at multiscale levels, it is identified under CO2 electroreduction conditions that an as-prepared CeO2/BiOCl precatalyst gradually evolves into CeOx/Bi interface structure with enriched Ce3+ species, which serves as the real catalytically active phase. The derived CeOx/Bi interface structure compared to pure Bi counterpart delivers substantially enhanced performance with a formate Faradaic efficiency approaching 90% for 24 hours in a wide potential window. The formate Faradaic efficiency can be further increased by using isotope D2O instead of H2O. Density functional theory calculations suggest that the regenerative CeOx/Bi interfacial sites can not only promote water activation to increase local *H species for CO2 protonation appropriately, but also stabilize the key intermediate *OCHO in formate pathway.


2013 ◽  
Vol 838-841 ◽  
pp. 170-174
Author(s):  
Guo Jun Wang

The effect on concrete strength of various kinds factor was systematically studied by orthogonal test. The amount of cementitious material, slag content, silicon content, water cement ratio, aggregate gradation and other factors was consider. By adjusting the parameters of the experiment, the C100 concrete was preparation successfully, which has high stregth and pumping perfomance. The interface structure of the C100 concrete was analyzed by scanning electron microscope (SEM) and found that C100 has a better interface structures. The concrete is a system and his strength depends on the strength of the suitability of various materials, which is a new point of view was put forward.


2022 ◽  
Vol 12 (1) ◽  
Author(s):  
Masayuki Morimoto ◽  
Shoya Kawano ◽  
Shotaro Miyamoto ◽  
Koji Miyazaki ◽  
Shuzi Hayase ◽  
...  

AbstractTo develop high-performance thermoelectric devices that can be created using printing technology, the interface of a composite material composed of MASnI3 and Bi2Te3, which individually show excellent thermoelectric performance, was studied based on first-principles calculations. The structural stability, electronic state, and interfacial thermal conductance of the interface between Bi2Te3 and MASnI3 were evaluated. Among the interface structure models, we found stable interface structures and revealed their specific electronic states. Around the Fermi energy, the interface structures with TeII and Bi terminations exhibited interface levels attributed to the overlapping electron densities for Bi2Te3 and MASnI3 at the interface. Calculation of the interfacial thermal conductance using the diffuse mismatch model suggested that construction of the interface between Bi2Te3 and MASnI3 could reduce the thermal conductivity. The obtained value was similar to the experimental value for the inorganic/organic interface.


2020 ◽  
Vol 8 (48) ◽  
pp. 26045-26054 ◽  
Author(s):  
Baolin Zhang ◽  
Haodong Shi ◽  
Zhijin Ju ◽  
Kai Huang ◽  
Cheng Lian ◽  
...  

An upright silk fibroin/lithium foil alternating array is fabricated to facilitate an unexpected SEI with a robust layered structure of lithium deposited on the anode (revealed by cryogenic electron microscopy), thus significantly suppressing dendrites.


Nanoscale ◽  
2015 ◽  
Vol 7 (9) ◽  
pp. 3971-3975 ◽  
Author(s):  
Yeru Liang ◽  
Lifeng Cai ◽  
Luyi Chen ◽  
Xidong Lin ◽  
Ruowen Fu ◽  
...  

A nitrogen-doped ordered mesoporous carbon/silica nanocomposite with a uniform carbon/silica interface structure was fabricated and demonstrated an impressive lithium ion storage capacity.


Author(s):  
Manfred P. Hentschel ◽  
Karl-Wolfram Harbich ◽  
Joerg Schors ◽  
Axel Lange

Advanced ceramics require specific methods for their nondestructive characterization. X-ray refraction techniques determine the specific surfaces and interfaces of high performance ceramics, composites and other low density materials down to nano-meter dimensions. X-ray refraction occurs due to the interference of phase shifted X-rays in ultra small angle X-ray scattering (USAXS) at objects above 100 nm size. Applications to monolithic ceramics and ceramic composites are presented. The well localized mean pore size of ceramics and the crack growth of ceramic composites are measured non-destructively.


2012 ◽  
Vol 407 (15) ◽  
pp. 2867-2870 ◽  
Author(s):  
Edwin L.H. Mayes ◽  
James G. Partridge ◽  
Matthew R. Field ◽  
Dougal G. McCulloch ◽  
Steven M. Durbin ◽  
...  

2018 ◽  
Vol 6 (25) ◽  
pp. 6755-6763 ◽  
Author(s):  
Yun-hui Wu ◽  
Shu-ting Xing ◽  
Rong-min Zheng ◽  
Shu-qi Liu ◽  
Zhi-fu Deng ◽  
...  

A novel adhesive interface structure between EGaInSn and PA with high stretchability and stable conductivity for high performance soft electronics.


Author(s):  
A. V. Crewe ◽  
M. Isaacson ◽  
D. Johnson

A double focusing magnetic spectrometer has been constructed for use with a field emission electron gun scanning microscope in order to study the electron energy loss mechanism in thin specimens. It is of the uniform field sector type with curved pole pieces. The shape of the pole pieces is determined by requiring that all particles be focused to a point at the image slit (point 1). The resultant shape gives perfect focusing in the median plane (Fig. 1) and first order focusing in the vertical plane (Fig. 2).


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