Thermal Analysis and X-Ray Diffraction of Rice Husk Ash Blended Cement Under Sodium Sulfate with Wetting and Drying Cycles

2021 ◽  
pp. 165-173
Author(s):  
P. J. Ramadhansyah ◽  
M. R. Hainin ◽  
O. Rokiah ◽  
R. Noram Irwan ◽  
W. I. Mohd Haziman ◽  
...  
Keyword(s):  
Thermal Analysis ◽  
Rice Husk ◽  
Sodium Sulfate ◽  
Rice Husk Ash ◽  
Blended Cement ◽  
X Ray Diffraction ◽  
Wetting And Drying ◽  
X Ray ◽  
Wetting And Drying Cycles

scholarly journals Solidification and Leachability of Cr (VI) in Rice Husk Ash-Blended Cement

2011 ◽  
Vol 2011 ◽  
pp. 1-6 ◽  
Author(s):  
Neeraj Jain
Keyword(s):  
Rice Husk ◽  
Rice Husk Ash ◽  
Setting Time ◽  
Blended Cement ◽  
X Ray Diffraction ◽  
Retention Capacity ◽  
Allowable Limit ◽  
X Ray ◽  
Curing Period ◽  
Leaching Procedure

Investigations carried out to study the effect of Cr (VI) (1000–3000 mg/l) on solidification and hydration behavior of Ordinary Portland cement (OPC) and rice husk ash (RHA) blended (10%, 20%, and 30%) cement show that addition of RHA accelerates final setting as compared to control samples (OPC) and retardation in setting time has been observed on increase in rice husk ash concentration (10%–30%). Solidification studies show that the compressive strength of controls and rice husk ash blended samples increases with increase in the curing period and maximum strength was observed with 20% RHA blended samples. With the increase in Cr (VI) concentrations, the strength of OPC and RHA blended samples decreases as compared to controls (without chromium). The results of Toxicity Characteristics Leaching Procedure (TCLP) test, (pH≅3), show that the retention capacity of OPC and RHA blended samples was in the range of 92% to 99% and the leached Cr (VI) concentration was under the allowable limit (5 mg/l) of U.S. EPA. The chemistry of influence of Cr (VI) on hydration of cement was examined by X-ray diffraction which shows the formation of various crystalline phases during solidification in rice hush ash blended cement.

Development of Ternary Concrete Utilizing Agricultural Waste Material

2022 ◽  
Author(s):  
Sunita Kumari ◽  
Dhirendra Singhal ◽  
Rinku Walia ◽  
Ajay Rathee
Keyword(s):  
Rice Husk ◽  
Rice Husk Ash ◽  
Agricultural Waste ◽  
Xrd Analysis ◽  
Sem Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Concrete Mix ◽  
Maize Cob

Abstract The present project proposes to utilize rice husk and maize cob husk ash in the cement to mitigate the adverse impact of cement on environment and to enhance the disposal of waste in a sustainable manner. Ternary concrete / MR concrete was prepared by using rise husk and maize cob ash with cement. For the present project, five concrete mixes MR-0 (Control mix), MR-1 (Rice husk ash 10% and MR-2.5%), MR-2 (Rice husk ash 10% and MR-5%), MR-3 (Rice husk ash 10% and MR-2.5%), MR-4 (Rice husk ash 10% and MR-2.5%) were prepared. M35 concrete mix was designed as per IS 10262:2009 for low slump values 0-25mm. The purpose is to find the optimum replacement level of cement in M35 grade ternary concrete for I – Shaped paver blocks.In order to study the effects of these additions, micro-structural and structural properties test of concretes have been conducted. The crystalline properties of control mix and modified concrete are analyzed by Fourier Transform Infrared Spectroscope (FTIR), Scanning Electron Microscopy (SEM), and X-Ray Diffraction (XRD). The results indicated that 10% Rice husk ash and 5% maize cob ash replaced with cement produce a desirable quality of ternary concrete mix having good compressive strength. The results of SEM analysis indicated that the morphology of both concrete were different, showing porous structure at 7 days age and become unsymmetrical with the addition of ashes. After 28 day age, the control mix contained more quantity of ettringite and became denser than ternary concrete. XRD analysis revealed the presence of portlandite in large quantity in controlled mix concrete while MR concrete had the partially hydrated particle of alite.

Comparison between Rice Husk Ash and Commercial Silica as Filler in Polymeric Composites

2016 ◽  
Vol 869 ◽  
pp. 209-214 ◽  
Author(s):  
Iara Janaína Fernandes ◽  
Daiane Calheiro ◽  
Emanuele Caroline Araújo dos Santos ◽  
Roxane Oliveira ◽  
Tatiana Louise Avila de Campos Rocha ◽  
...  
Keyword(s):  
Rice Husk ◽  
Rice Husk Ash ◽  
Polymeric Materials ◽  
Fluidized Bed Reactor ◽  
Specific Weight ◽  
High Energy ◽  
Loss On Ignition ◽  
X Ray Diffraction ◽  
X Ray ◽  
Different Sources

The use of rice husk ash (RHA) as filler in polymeric materials has been studied in different polymers. Research reported that RHA may successfully replace silica. The silica production process using ore demands high energy input and produces considerable amounts of waste. Therefore, the replacement of silica by RHA may be economically and environmentally advantageous, reducing environmental impact and adding value to a waste material. In this context, this study characterizes and compares RHA of different sources (moving grate and fluidized bed reactor) with commercially available silicas to assess performance as filler in polymeric materials. Samples were characterized by X-ray fluorescence, loss on ignition, X-ray diffraction, grain size, specific surface area, specific weight, and scanning electron microscopy. The results show that RHA may be used as a filler in several polymeric materials.

Variables Involved in the Planting of Rice in the Rice Husk

2012 ◽  
Vol 517 ◽  
pp. 430-436
Author(s):  
J.L. Akasaki ◽  
E.J. Silva ◽  
L.C. Sousa ◽  
J.L.P. Melges ◽  
M.M. Tashima ◽  
...  
Keyword(s):  
Rice Husk ◽  
Large Scale ◽  
Rice Husk Ash ◽  
Scale Production ◽  
X Ray Diffraction ◽  
X Ray ◽  
Large Scale Production ◽  
Pozzolanic Materials ◽  
Different Strains ◽  
Different Origins

Rice production in Brazil in 2010 was approximately 12,2 million tons, and to reach that amount several planting techniques were used with different strains of rice in different rice-growing areas. Since Rice Husk Ash (RHA) is the pozzolan of vegetable origin most studied by researchers working in the area of pozzolanic materials, the present paper evaluates the influence that the form of planting, the climate, the soil, the strain of rice and the origin/amount of nitrogen-based fertilizers used in rice cultivation has on the chemical composition and crystallographic properties of RHA. The results obtained in this paper, confirm the importance of carrying out routine chemical analysis and X-Ray diffraction to maintain the quality control of the CCAs produced, because in situations of large-scale production, husks of different origins may be used.

scholarly journals Effects of Rice Husk Ash–Magnesium Oxide Addition on Wear Behavior of Aluminum Alloy Matrix Hybrid Composites

2018 ◽  
Vol 25 (4) ◽  
pp. 15-22
Author(s):  
Abbas Y. Awad ◽  
Mohammed N. Ibrahim ◽  
Mohamed K. Hussein
Keyword(s):  
Aluminum Alloy ◽  
Wear Rate ◽  
Apparent Density ◽  
Rice Husk ◽  
Applied Load ◽  
Rice Husk Ash ◽  
Hybrid Composites ◽  
Wear Behavior ◽  
X Ray Diffraction ◽  
X Ray

A336.0 aluminum alloy used to fabricate hybrid composites using rice husk ash (RHA) and MgO particles as reinforcement. The influence of the particles on the wear behavior of A336.0 aluminum alloy as a matrix that reinforced with MgO and RHA was investigated. Firstly, the rice husk burned at 700°C and then heat treated at 1100°C for 2 hrs. The ash characterized by X-ray florescence and X-ray diffraction. Less than 53 and 125 micron are the particle sizes of MgO and RHA respectively. The hybrid composites manufactured using stir casting method in two steps. A336.0 aluminum alloy reinforced with 4:0, 3:1, 2:2, 1:3 and 0:4 of RHA: MgO with 10 wt% total reinforcement phase. Optical microscope and X-ray diffraction were used to characterize the prepared hybrid composites. Dry sliding wear, hardness, apparent density, percentage of porosity and coefficient of friction were examined. Results indicated that porosity, apparent density and hardness enhanced with increasing MgO, while increasing wt% of RHA decreased the apparent density. Results indicated that with inceasing the applied load the wear rate of the composites was enhanced. Coefficient of friction varies inversely with applied load and wt% of RHA. Hardness increased with increasing RHA while the friction coefficient and the wear rate decreased. The minimum wear rates were at 10% RHA and Al-alloy-(RHA-MgO) [3:1] composites, while the minimum friction coefficients were at 10% RHA composites.

scholarly journals Adsorption of Flagyl on Prepared Ash from Rice Husk

2021 ◽  
Vol 22 (4) ◽  
pp. 11-17
Author(s):  
Haider Abbas ◽  
Ammar S. Abbas
Keyword(s):  
Rice Husk ◽  
Rice Husk Ash ◽  
Primary Source ◽  
Alternative Methods ◽  
X Ray Diffraction ◽  
X Ray ◽  
Adsorption Data ◽  
Pseudo Second Order ◽  
Husk Rice ◽  
Increasing Temperature

In recent years, it has been evident that searching for alternative methods with low-price and eco-friendly features that produce high-quality adsorbents is in high demand. In the present work, Rice husk from Iraqi rice named (Amber) had been used as the primary source to produce rice husk ash (RHA) for the removal of the antibiotic metronidazole (Flagyl) from water. After optimum drying of rice husk, rice husk ash (RHA) was obtained at 600 °C using an electric oven. RHA has been investigated for properties using X-ray diffraction (XRD), porosity, and surface area (SA). The experimental work adsorption data were optimized to evaluate Langmuir and Freundlich constants. The thermodynamic parameters likely a change in Gipp's energy (ΔG), enthalpy (ΔH), and entropy (ΔS). The impacts of increasing temperature on adsorption capacity were investigated, and the results indicate that the pseudo-second-order kinetics model could be presented the dynamic adsorption data that it has. The resultant values for the heat of adsorption and the free energy indicated that adsorption of Flagyl is preferred at low temperatures.

scholarly journals SYNTHESIS AND CHARACTERIZATION OF CALCIUM SILICATE FROM RICE HUSK ASH AND SNAIL SHELL

2019 ◽  
Vol 11 (2) ◽  
pp. 45
Author(s):  
Sadang Husain ◽  
Ninis Hadi Haryanti ◽  
Suryajaya Suryajaya ◽  
Antung Permitaria
Keyword(s):  
Rice Husk ◽  
Calcium Silicate ◽  
Rice Husk Ash ◽  
Wave Number ◽  
X Ray Diffraction ◽  
Solid Reaction ◽  
Snail Shell ◽  
X Ray ◽  
Infra Red

<p class="abstrak">Calcium silicate ceramics have been made using natural ingredients such as rice husk and snail shell with solid reaction techniques. The aim of this study to determine the characteristics of calcium silicate that have been sintered at a temperature of 900 <sup>°</sup>C, 1000 <sup>°</sup>C, and 1100 <sup>°</sup>C. Samples were characterized by X-Ray Diffraction (XRD), optical microscopy, and Fourier Transform Infra-Red (FTIR). The results of XRD characterization showed that CaSiO<sub>3</sub> (calcium silicate) along with the increase in calcination temperature and quantity was increased due to the increase of temperature of calcination. FTIR analysis showed that the Ca-Si-O bond was formed at wave number ranging from 848 cm<sup>-1</sup> and 999 – 1001 cm<sup>-1</sup>.</p>

Free Na and Less Fe Compositions of SiO2 Extracted from Rice Husk Ash as the Silica Source for Synthesis of White Mineral Trioxide Aggregate

2020 ◽  
Vol 840 ◽  
pp. 311-317
Author(s):  
Muhamad Ghadafi ◽  
Sri Juari Santosa ◽  
Yuichi Kamiya ◽  
Nuryono Nuryono
Keyword(s):  
Rice Husk ◽  
Rice Husk Ash ◽  
Mineral Trioxide Aggregate ◽  
Deionized Water ◽  
X Ray Diffraction ◽  
X Ray ◽  
Silica Source ◽  
Tricalcium Aluminate ◽  
White Mineral

In this research, we report the use of free sodium and less Fe ion silica (SiO2) for preparation of White Mineral Trioxide Aggregate (WMTA). SiO2 was extracted from rice husk ash (RHA) using NaOH 2 M and HCl 37% (v/v) and removal of Na was performed by washing the extracted SiO2 using deionized water with various volumes and techniques. Before extraction, RHA was calcined at a temperature of 700 °C for 3 h. Preparation of WMTA began with mixing the extracted SiO2 20%, CaO 60%, Al2O3 2%, and Bi2O3 18% (w/w). The mixture was calcined at temperatures of 1100 °C for 4 h, grounded to produce WMTA 200 mesh in size and then was characterized using Fourier Transformed Infrared (FTIR) spectrophotometer, X-ray Diffraction (XRD) and Scanning Electron Microscopy-Energy Dispersion X-ray (SEM-EDX). The WMTA characteristics were compared to that of the commercial WMTA ProRoot. The result shows that the silica that was potential as the silica source for WMTA preparation was extracted from RHA involving sonication and washing with 360 mL of deionized water per 10 g of RHA. It contained SiO2 of 94.2%, Fe2O3 of 0.03%, no Na2O, and the particle size of 1.51±0.46 µm. The characterization of WMTA shows that produced WMTA contained tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A) and BiO2, which is comparable to the commercial WMTA ProRoot.

Microwave-Assisted Preparation of Sodium Silicate as Biodiesel Catalyst from Rice Husk Ash

2017 ◽  
Vol 751 ◽  
pp. 461-466 ◽  
Author(s):  
Jaturon Kumchompoo ◽  
Wasinee Wongwai ◽  
Ratchadaporn Puntharod
Keyword(s):  
Sodium Silicate ◽  
Rice Husk ◽  
Rice Husk Ash ◽  
Biodiesel Production ◽  
X Ray Diffraction ◽  
X Ray ◽  
Microwave Assisted ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Infrared Spectrophotometer

In this research, sodium silicate (Na2SiO3) was prepared by rice husk ash reacted with 10 M sodium hydroxide. The mixtures were heated by microwave at 400, 600, and 800 watt for 5 and 10 minutes. The formation of sodium silicate was characterized by Fourier transform infrared spectrophotometer. The vibrations of (Na)O–Si–O(Na) and O–Si–O were observed at 595 and 1023-986 cm-1, respectively, except at 800 watt disappeared those vibrations. The results of flame atomic absorption spectrophotometer provided the mole ratio of sodium and silicon was 2:1 as heating the product at 600 watt for 5 and 10 minutes. The phase of sodium silicate was characterized by X-ray diffraction. Sodium silicate could be used as catalyst as in biodiesel production from palm oil. The percentage of yield was 81 by volume.

Strength of Concrete Containing Rice Husk Ash Subjected to Sodium Sulfate Solution via Wetting and Drying Cyclic

2014 ◽  
Vol 534 ◽  
pp. 3-8 ◽  
Author(s):  
Che Wan Che Norazman ◽  
Ramadhansyah Putra Jaya ◽  
Sri Jayanti Dewi ◽  
Badorul Hisham Abu Bakar ◽  
M.A. Fadzil
Keyword(s):  
Compressive Strength ◽  
Rice Husk ◽  
Sodium Sulfate ◽  
Rice Husk Ash ◽  
Blended Cement ◽  
Sulfate Solution ◽  
Target Strength ◽  
Type I ◽  
Cement Concrete ◽  
Cement Replacement

The influences of different replacement levels of rice husk ash (RHA) blended cement concrete subjected to 5% Na2SO4 solution via wetting-drying cycles was evaluated in this study. RHA was used as a Portland cement Type I replacement at the levels of 0%, 10%, 20, 30%, and 40% by weight of binder. The water-to-binder ratio was 0.49 to produce concrete having target strength of 40 MPa at 28 days. The performance of RHA blended cement concrete on compressive strength, reduction in strength and loss of weight was monitored for up to 6 months. The results of the compressive strength test have been shown that use of RHA in blended cement has a significant influence on sulfate concentration. When increasing the replacement level of RHA, the strength of concrete also increases in comparison to OPC concrete (except RHA40) even exposed to 5% Na2SO4 solution. On the other hand, the reduction in strength and weight loss of specimens increased with increase in the exposure time. Generally, it can be said that the incorporation of rice husk ash as cement replacement significantly improved the resistance to sulfate penetration of concrete. Finally, RHA cement replacement in concrete mixed provided better resistance to sodium sulfate attack up to 6-month exposure.

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