Role of adsorption process during crystallization of polymers at low supercooling

Author(s):  
Jacques Rault

1993 ◽  
Vol 290 (1-2) ◽  
pp. L685-L687
Author(s):  
H.T. Liu ◽  
Z. Wu


2020 ◽  
Vol 55 (24) ◽  
pp. 10626-10642
Author(s):  
Marcin Woźnica ◽  
Monika Sobiech ◽  
Norbert Pałka ◽  
Piotr Luliński


1973 ◽  
Vol 51 (11) ◽  
pp. 1771-1781 ◽  
Author(s):  
G. A. Blomfield ◽  
L. H. Little

The interaction of ammonia with silicas prepared by a variety of methods was studied to resolve conflicting reports of the mode of ammonia adsorption and to determine the role of chlorine impurities (present in the silica) in the adsorption process. Results for the adsorption of water on silica assisted in making band assignments and competition between ammonia and water for silica adsorption sites was observed. It was concluded that dehydroxylated silicas contain sites which dissociate ammonia to form Si—NH2 groups having infrared bands at 3540, 3450, and 1550 cm−1 (the surface amine groups are not displaced by added water). The presence of chlorine in the silica is not a prerequisite for chemisorption of ammonia.



2019 ◽  
Vol 57 (4) ◽  
pp. 449
Author(s):  
Trung Tien Nguyen ◽  
Tri Ngoc Nguyen ◽  
Dai Quoc Ho

We investigated the adsorption of enrofloxacin (ENR) antibiotic on rutile-TiO2 (r-TiO2­) (110) surface using DFT calculations. Stable configurations of the adsorption of ENR on r-TiO2 (110) were observed. The origin and role of interactions in stablizing the configurations are thoroughly analyzed using NBO and AIM analyses. Obtained results indicate that the adsorption process is characterized as a strong chemisorption with an associated energy of ca. -35.1 kcal.mol-1 for the most stable configuration. Quantum chemical analysis shows that the stability of configurations is mainly determined by >C=O∙∙∙Ti5f electrostatic interaction along with supplement of H∙∙∙Ob hydrogen bond.



2017 ◽  
Vol 121 (45) ◽  
pp. 25033-25042
Author(s):  
W. Szczerba ◽  
M. Schneider ◽  
J. Żukrowski ◽  
A. Guilherme Buzanich ◽  
H. Riesemeier ◽  
...  


2014 ◽  
Vol 153 ◽  
pp. 160-164 ◽  
Author(s):  
Xiaochun Zhang ◽  
Xinrun Li ◽  
Qingrui Zhang ◽  
Qiuming Peng ◽  
Wen Zhang ◽  
...  


1980 ◽  
Vol 44 (12) ◽  
pp. 2843-2855 ◽  
Author(s):  
Goro Kato ◽  
Yoshiharu Maruyama ◽  
Michinori Nakamura
Keyword(s):  


Fuel ◽  
2012 ◽  
Vol 92 (1) ◽  
pp. 318-326 ◽  
Author(s):  
Mykola Seredych ◽  
Chi Tang Wu ◽  
Patrice Brender ◽  
Conchi O. Ania ◽  
Cathie Vix-Guterl ◽  
...  


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 407
Author(s):  
Teresa J. Bandosz

Recently, owing to the discovery of graphene, porous carbons experienced a revitalization in their explorations. However, nowadays, the focus is more on search for suitable energy advancing catalysts sensing, energy storage or thermal/light absorbing features than on separations. In many of these processes, adsorption, although not emphasized sufficiently, can be a significant step. It can just provide a surface accumulation of molecules used in other application-driving chemical or physical phenomena or can be even an additional mechanism adding to the efficiency of the overall performance. However, that aspect of confined molecules in pores and their involvement in the overall performance is often underrated. In many applications, nanopores might silently advance the target processes or might very directly affect or change the outcomes. Therefore, the objective of this communication is to bring awareness to the role of nanopores in carbon materials, and also in other solids, to scientists working on cutting-edge application of nonporous carbons, not necessary involving the adsorption process directly. It is not our intention to provide a clear explanation of the small pore effects, but we rather tend to indicate that such effects exist and that their full explanation is complex, as complex is the surface of nanoporous carbons.



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