Influence of the exchangeable cations on SO2 adsorption capacities of clinoptilolite-rich natural zeolite

Adsorption ◽  
2011 ◽  
Vol 17 (4) ◽  
pp. 739-745 ◽  
Author(s):  
Meryem Sakizci ◽  
Burcu Erdoğan Alver ◽  
Ertuğrul Yörükoğullari
Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 486
Author(s):  
Alcina Johnson Sudagar ◽  
Slávka Andrejkovičová ◽  
Fernando Rocha ◽  
Carla Patinha ◽  
Maria R. Soares ◽  
...  

Metakaolins (MKs) prepared from low-grade kaolins located in the Alvarães (A) and Barqueiros (B) regions of Portugal were used as the aluminosilicate source to compare their effect on the compressive strength and heavy metal adsorption of geopolymers. Natural zeolite, an inexpensive, efficient adsorbent, was used as an additive in formulations to enhance geopolymers’ adsorption capacities and reduce MK utilization’s environmental footprint. Geopolymers were synthesized with the replacement of MK by zeolite up to 75 wt.% (A25, B25—25% MK 75% zeolite; A50, B50—50% MK 50% zeolite; A75, B75—75% MK 25% zeolite; A100, B100—100% MK). The molar ratios of SiO2/Al2O3 and Na2O/Al2O3 were kept at 1 to reduce the sodium silicate and sodium hydroxide environmental impact. Geopolymers’ crystallography was identified using X-ray diffraction analysis. The surface morphology was observed by scanning electron microscopy to understand the effect of zeolite incorporation. Chemical analysis using X-ray fluorescence spectroscopy and energy dispersive X-ray spectroscopy yielded information about the geopolymers’ Si/Al ratio. Compressive strength values of geopolymers obtained after 1, 14, and 28 days of curing indicate high strengths of geopolymers with 100% MK (A100—15.4 MPa; B100—32.46 MPa). Therefore, zeolite did not aid in the improvement of the compressive strength of both MK-based geopolymers. The heavy metal (Cd2+, Cr3+, Cu2+, Pb2+, and Zn2+) adsorption tests exhibit relatively higher adsorption capacities of Barqueiros MK-based geopolymers for all the heavy metals except Cd2+. Moreover, zeolite positively influenced divalent cations’ adsorption on the geopolymers produced from Barqueiros MK as B75 exhibits the highest adsorption capacities, but such an influence is not observed for Alvarães MK-based geopolymers. The general trend of adsorption of the heavy metals of both MK-based geopolymers is Pb2+ > Cd2+ > Cu2+ > Zn2+ > Cr3+ when fitted by the Langmuir isotherm adsorption model. The MK and zeolite characteristics influence geopolymers’ structure, strength, and adsorption capacities.


2012 ◽  
Vol 253-255 ◽  
pp. 960-964 ◽  
Author(s):  
Xiao Dan Fan ◽  
Xiang Kai Zhang

The simultaneous removal of SO2 and NO was investigated with the activated carbon from sewage sludge (referred as ACS) modified by chitosan (referred as CS).The effects of CS loading and operating conditions on the simultaneous removal of SO2 and NO were analyzed. The results indicate that compared with the ACS, impregnating CS results in significant increase in SO2 or NO removal. Relative humidity enhances SO2 adsorption capacities, but not for NO. The SO2 adsorption capacities of the CS / ACS show no obvious decrease at small amount of NO in the feed. However, higher amounts of NO reduce the SO2 adsorption capacities. The opposite phenomenon appears for NO when a small amount of SO2. So a competitive sorption consists between NO and SO2. Simultaneous adsorptions for NO and SO2 is due to more active sites from CS.


2006 ◽  
Vol 518 ◽  
pp. 223-228 ◽  
Author(s):  
V. Jovanović ◽  
V. Dondur ◽  
Lj. Damjanović ◽  
J. Zakrzewska ◽  
M. Tomašević-Čanović

The surface properties of zeolites A, X, Y and natural zeolite clinoptilolite (CLI) functionalized by cationic surfactants were investigated. The quaternary ammonium type surfactants, such as hexadecyltrimethylammonium (HDTMA) chloride, stearildimethylbenzylammonium (SDMBA) chloride and distearildimethylammonium (DSDMA) chloride, replaced inorganic cations like Na+ and Ca2+ on the external surface of zeolites. The adsorption capacities of all organic cations followed the order of CLI>CaY>CaX>CaA>NaY>NaX>NaA and increased with the increase of Si/Al molar ratio in zeolite structure. This modification resulted in an alteration in the surface property of zeolites - it changed from hydrophilic to hydrophobic. The adsorption of selected pesticides with different hydrophobicity on surfactant-modified zeolites was studied. It is shown that surfactant-modified zeolites can be used for removal of pesticides from the environment. The increase in hydrophobicity of pesticides resulted in an increase in pesticide adsorption on SDMBA and DSDMA modified zeolites.


2014 ◽  
Vol 20 (2) ◽  
pp. 283-293 ◽  
Author(s):  
Marija Mihajlovic ◽  
Slavica Lazarevic ◽  
Ivona Jankovic-Castvan ◽  
Bojan Jokic ◽  
Djordje Janackovic ◽  
...  

The main purpose of this research was to explain the differences in the adsorption mechanisms and adsorption capacities of natural and Fe(III)-modified zeolite for Pb2+, Zn2+ and Cd2+ ions. The adsorbents were characterized with respect to their phase composition, morphology, specific surface area, cation exchange capacity and point of zero charge. Batch adsorption experiments were performed as a function of the initial ion concentration and temperature, at constant initial pH value of 5.5 ? 0.1. The adsorption isotherms at 25, 40, 55 and 70?C suggest that the sequence of adsorption efficiency of both zeolites is Pb2+ > Zn2+ > Cd2+. The adsorption capacities of both zeolites increased with increasing temperature. The equilibrium adsorption data were best described by the Langmuir adsorption isotherm. This study revealed that the adsorption capacity of the Fe(III)-modified zeolite is much higher than that of natural zeolite for all investigated ions owing to the higher: specific adsorption caused by the new functional groups formed on the zeolite surface; ion exchange due to the presence of easily exchangeable ions; and hydroxide precipitation caused by higher point of zero charge of the Fe(III)-modified zeolite compared to natural zeolite.


Clay Minerals ◽  
2011 ◽  
Vol 46 (1) ◽  
pp. 73-83 ◽  
Author(s):  
M. Sakizci ◽  
B. Erdoğan Alver ◽  
E. Yörükoğullari

AbstractThe adsorption of sulphur dioxide (SO2) on two bentonites from Unye, Turkey (Kavaktepe and Yemişlitepe deposits – denoted below as BK and BY) and on forms treated with 1 and 2 M HCl solutions was investigated. The bentonite samples were characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), thermogravimetry (TG-DTG), differential thermal analysis (DTA) and nitrogen adsorption methods. Adsorption capacities of SO2 were obtained using a standard volumetric apparatus at 293 K and 106 kPa. The SO2 adsorption capacity of the BY-2 (1.263 mmol g–1) sample was much greater than the BK-2 (1.126 mmol g–1) sample. As the concentration of acid increased, the specific surface areas and the uptakes of SO2 gas increased.


2019 ◽  
Vol 9 (2) ◽  
pp. 142-154
Author(s):  
Imeda Rubashvili ◽  
Luba Eprikashvili ◽  
Teimuraz Kordzakhia ◽  
Marine Zautashvili ◽  
Nino Pirtskhalava ◽  
...  

Residual antibiotics pollution has become one of the most severe environmental problems today.  Antibiotics from hospitals and drug factories represent a potential risk for human and ecological health. Therefore, it has been a high exigency to develop some efficient and cost-effective treatment methods and technologies for antibiotics removal from industrial and household contaminated water. Adsorption is one of the most utilised techniques and has many competitive advantages such as the unique properties of flexibility, effectiveness, superior performance and the robustness for consecutive cycles. The present research concerns the adsorption of two frequently used fluoroquinolone antibiotics - moxifloxacin and norfloxacin on natural zeolite - clinoptilolite and its acid-modified form from aqueous solutions. For the first time, the adsorption of the antibiotics mentioned above on the selected natural zeolite was investigated under static and dynamic conditions. Adsorption experiment under dynamic conditions carried out using the specially constructed dynamic type of laboratory equipment. The effect of the inlet concentration, the flow rate and the pH value of the antibiotic solution, also, the contact time of system zeolite/antibiotic solution on the adsorption process were examined and evaluated using the Langmuir and Freundlich adsorption models. The results showed that the highest static adsorption capacities were observed at low initial concentration - 0.2 mg/mL of antibiotic solution for both adsorbents; the highest dynamic adsorption capacities - at low flow rate - 1.5 mg/mL and low inlet concentration - 0.2 mg/mL of antibiotic solution for both adsorbents. The static adsorption capacity was up to 2.71 mg/g for moxifloxacin hydrochloride; 4.14 mg/g for norfloxacin and the dynamic adsorption capacity was up to 1.20 mg/g for moxifloxacin hydrochloride; 2.10 mg/g for norfloxacin at a neutral pH value and constant temperature of 200°C. Each antibiotic was determined quantitatively in sample solutions using the developed and validated HPLC methods with a limit of quantitation - 0.05 µg/mL. Hence, this study demonstrates and proves that natural zeolite could be an effective adsorbent for the removal of the selected antibiotics from wastewaters.


2015 ◽  
Vol 2 (2) ◽  
pp. 148-158
Author(s):  
Surianto

Spodosol soil of Typic Placorthod sub-group of East Barito District is one of the problem soils with the presence of hardpan layer, low fertility, low water holding capacity, acid reaction and it is not suitable for oil palm cultivation without any properly specific management of land preparation and implemented best agronomic practices. A study was carried out to evaluate the soil characteristic of a big hole (A profile) and no big hole (B profile) system and comparative oil palm productivity among two planting systems. This study was conducted in Spodosol soil at oil palm plantation (coordinate X = 0281843 and Y = 9764116), East Barito District, Central Kalimantan Province on February 2014, by surveying of placic and ortstein depth and observing soil texture and chemical properties of 2 (two) oil palm's soil profiles that have been planted in five years. Big hole system of commercial oil palm field planting on the Spodosol soil area was designed for the specific purpose of minimizing the potential of a negative effect of shallow effective planting depth for oil palms growing due to the hardpan layer (placic and ortstein) presence as deep as 0.25 - 0.50 m. The big hole system is a planting hole type which was vertical-sided with 2.00 m x 1.50 m on top and bottom side and 3.00 m depth meanwhile the 2:1 drain was vertical-sided also with 1.50 m depth and 300 m length. Oil palm production was recorded from the year 2012 up to 2014. Results indicated that the fractions both big hole profile (A profile) and no big hole profile (B profile) were dominated by sands ranged from 60% to 92% and the highest sands content of non-big hole soil profile were found in A and E horizons (92%). Better distribution of sand and clay fractions content in between layers of big hole soil profiles of A profile sample is more uniform compared to the B profile sample. The mechanical holing and material mixing of soil materials of A soil profile among the upper and lower horizons i.e. A, E, B and C horizons before planting that resulted a better distribution of both soil texture (sands and clay) and chemical properties such as acidity value (pH), C-organic, N, C/N ratio, CEC, P-available and Exchangeable Bases. Investigation showed that exchangeable cations (Ca, Mg, K), were very low in soil layers (A profile) and horizons (B profile) investigated. The low exchangeable cations due to highly leached of bases to the lower layers and horizons. Besides, the palm which was planted on the big hole system showed good adaptation and response positively by growing well of tertiary and quaternary roots that the roots were penetrable into deeper rooting zone as much as >1.00 m depth. The roots can grow well and penetrate much deeper in A profile compared to the undisturbed hardpan layer (B profile). The FFB (fresh fruit bunches) production of the non-big hole block was higher than the big hole block for the first three years of production. This might be due to the high variation of monthly rainfall in-between years of observation from 2009 to 2014. Therefore, the hardness of placic and ortstein as unpenetrable agents by roots and water to prevent water loss and retain the water in the rhizosphere especially in the drier weather. In the high rainfall condition, the 2:1 drain to prevent water saturation in the oil palm rhizosphere by moving some water into the drain. Meanwhile, the disturbed soil horizon (big hole area) was drier than un disturbance immediately due to water removal to deeper layers. We concluded that both big hole and 2:1 drain are a suitable technology for Spodosol soil land especially in preparing palms planting to minimize the negative effect of the hardpan layer for oil palm growth.


1976 ◽  
Vol 144 (1-6) ◽  
pp. 32-41 ◽  
Author(s):  
W. J. Mortier ◽  
J. J. Pluth ◽  
J. V. Smith

2019 ◽  
Author(s):  
Chem Int

The study aims to use an adsorbent natural based of Moroccan oil shale of Timahdit area (Y layer) in a physical-chemical adsorption process for treating industrial discharges colorful. The used adsorbent is the insoluble party of the sub-critical extraction of decarbonized oil shale of Timahdit. The tests performed on the methylene blue (MB), showed a strong elimination in the first 10 minutes. The influences of various experimental parameters were studied: mass ratio of adsorbent, time and temperature of thermal treatment, contact time, pH of MB and heating temperature of solution on the parameters of material were studied. The experimental results have shown that the adsorption of methylene blue dye by the adsorbent is more than 90% at initial pH a range 6-7 at room temperature for 30 minutes. The process is simple and the adsorbent produced is a new material with interesting adsorption capacities of moderate cost which does not require an activating agent and can be used as industrial adsorbent for the decontamination of effluents containing organic pollutants.


Sign in / Sign up

Export Citation Format

Share Document