Impact of heat treatment on the mechanical properties of AISI 304L austenitic stainless steel in high-pressure hydrogen gas

2012 ◽  
Vol 47 (16) ◽  
pp. 6095-6107 ◽  
Author(s):  
Sebastian Weber ◽  
Mauro Martin ◽  
Werner Theisen
Author(s):  
Takashi Iijima ◽  
Hirotoshi Enoki ◽  
Junichiro Yamabe ◽  
Bai An

A high pressure material testing system (max. pressure: 140 MPa, temperature range: −80 ∼ 90 °C) was developed to investigate the testing method of material compatibility for high pressure gaseous hydrogen. In this study, SSRT and fatigue life test of JIS SUS304 and SUS316 austenitic stainless steel were performed in high pressure gaseous hydrogen at room temperature, −45, and −80 °C. These testing results were compared with those in laboratory air atmosphere at the same test temperature range. The SSRT tests were performed at a strain rate of 5 × 10−5 s−1 in 105 MPa hydrogen gas, and nominal stress-strain curves were obtained. The 0.2% offset yield strength (Ys) did not show remarkable difference between in hydrogen gas and in laboratory air atmosphere for SUS304 and SUS316. Total elongation after fracture (El) in hydrogen gas at −45 and −80 °C were approximately 15 % for SUS304 and 20% for SUS316. In the case of fatigue life tests, a smooth surface round bar test specimen with a diameter of 7 mm was used at a frequency of 1, 0.1, and 0.01 Hz under stress rate of R = −1 (tension-compression) in 100 MPa hydrogen gas. It can be seen that the fatigue life test results of SUS304 and SUS316 showed same tendency. The fatigue limit at room temperature in 100 MPa hydrogen gas was comparable with that in laboratory air. The room temperature fatigue life in high pressure hydrogen gas appeared to be the more severe condition compared to the fatigue life at low temperature. The normalized stress amplitude (σa / Ts) at the fatigue limit was 0.37 to 0.39 for SUS304 and SUS316 austenitic stainless steels, respectively.


Author(s):  
Akihide Nagao ◽  
Nobuyuki Ishikawa ◽  
Toshio Takano

Cr-Mo and Ni-Cr-Mo high-strength low-alloy steels are candidate materials for the storage of high-pressure hydrogen gas. Forging materials of these steels have been used for such an environment, while there has been a strong demand for a higher performance material with high resistance to hydrogen embrittlement at lower cost. Thus, mechanical properties of Cr-Mo and Ni-Cr-Mo steels made of quenched and tempered seamless pipes in high-pressure hydrogen gas up to 105 MPa were examined in this study. The mechanical properties were deteriorated in the presence of hydrogen that appeared in reduction in local elongation, decrease in fracture toughness and accelerated fatigue-crack growth rate, although the presence of hydrogen did not affect yield and ultimate tensile strengths and made little difference to the fatigue endurance limit. It is proposed that pressure vessels for the storage of gaseous hydrogen made of these seamless line pipe steels can be designed.


Author(s):  
Kazuhisa Matsumoto ◽  
Shinichi Ohmiya ◽  
Hideki Fujii ◽  
Masaharu Hatano

To confirm a compatibility of a newly developed high strength stainless steel “NSSC STH®2” for hydrogen related applications, tensile and fatigue crack growth properties were evaluated in high pressure hydrogen gas up to 90MPa. At temperatures between −40 and 85°C, no conspicuous deterioration of tensile properties including ductility was observed even in 90 MPa hydrogen gas at −40°C while strength of STH®2 was higher than SUS316L. Although a slight drop of reduction of area was recognized in one specimen tested in 90 MPa hydrogen gas at −40°C, caused by the segregation of Mn, Ni and Cu in the laboratory manufactured 15mm-thick plate, it was considerably improved in the large mill products having less segregation. Fatigue crack growth rates of STH®2 in high pressure hydrogen gas were almost the same as that of SUS316L in air. Although fatigue crack growth rate in air was considerably decelerated and lower than that in hydrogen gas at lower ΔK region, this was probably caused by crack closure brought by oxide debris formed on the fracture surfaces near the crack tip by the strong contact of the fracture surfaces after the fatigue crack was propagated. By taking the obtained results into account, it is concluded that NSSC STH®2 has excellent properties in high pressure hydrogen gas in addition to high strength compared with standard JIS SUS316L.


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