Fabrication and catalytic performance of meso-ZSM-5 zeolite encapsulated ferric oxide nanoparticles for phenol hydroxylation

2020 ◽  
Author(s):  
Zhenheng Diao ◽  
Lushi Cheng ◽  
Wen Guo ◽  
Xu Hou ◽  
Pengfei Zheng ◽  
...  
Keyword(s):  
Ferric Oxide ◽  
Catalytic Performance ◽  
Oxide Nanoparticles ◽  
Phenol Hydroxylation

Differential Pulse Voltammetric Determination of Piroxicam on Lanthanide Ferric Oxide Nanoparticles-Carbon Paste Modified Electrode

2018 ◽  
Vol 14 (3) ◽  
pp. 271-276 ◽  
Author(s):  
Isaac Yves Lopes de Macedo ◽  
Morgana Fernandes Alecrim ◽  
Luane Ferreira Garcia ◽  
Aparecido Ribeiro de Souza ◽  
Wallans Torres Pio dos Santos ◽  
...  
Keyword(s):  
Modified Electrode ◽  
Ferric Oxide ◽  
Differential Pulse ◽  
Voltammetric Determination ◽  
Oxide Nanoparticles ◽  
Carbon Paste ◽  
Carbon Paste Modified Electrode

BIOCOMPATIBILITY STUDY OF α-Fe2O3 NANOPARTICLES PREPARED BY HYDROTHERMAL METHOD

2019 ◽  
Vol 26 (09) ◽  
pp. 1950058
Author(s):  
SADEQ H. LAFTA ◽  
ALI ABDULRAHMAN TAHA ◽  
MUHAMMAD M. FARHAN ◽  
SHAIMA Y. ABDULFATTAH
Keyword(s):  
Tumor Cell ◽  
Cell Line ◽  
Hydrothermal Method ◽  
Ferric Oxide ◽  
Tumor Cell Line ◽  
Oxide Nanoparticles ◽  
Average Particle ◽  
Normal Cells ◽  
Prepared Nanoparticles ◽  
Biocompatibility Study

Nanoparticles of alpha ferric oxide ([Formula: see text]-Fe2O3) were prepared by the hydrothermal method. Structural properties of [Formula: see text]-Fe2O3 were determined by XRD, SEM and AFM measurements. The particles had a good matching with standard pattern. Average particle size was about 90[Formula: see text]nm and the distribution extended from about 20[Formula: see text]nm to 120[Formula: see text]nm. Biocompatibility study of ferric oxide nanoparticles against bacteria, parasites, tumor cell line and normal cells was determined. No antibacterial activity was observed for the concentration, of ferric oxide nanoparticles in distilled water, up to 1.5[Formula: see text]mg/ml vs. E. coli and S. aureus. Moreover, MTT assay was used to determine the cytotoxicity against parasites and cells. Intermediate cytotoxicity (53.30%) of 1.5[Formula: see text]mg/ml of prepared nanoparticles was noted against L. tropica, while weak cytotoxicity of 5.20% was observed against L. donovani at the same concentration of ferric oxide nanoparticles. On the other hand, the prepared nanoparticles revealed low cytotoxicity (47.28%) against SR tumor cell line, while no cytotoxicity was shown against lymphocytes, as a model of normal cells.

scholarly journals Exploiting the Potential of Biosilica from Rice Husk as Porous Support for Catalytically Active Iron Oxide Nanoparticles

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1259
Author(s):  
Ana Franco ◽  
Rafael Luque ◽  
Carolina Carrillo-Carrión
Keyword(s):  
Iron Oxide ◽  
Iron Oxide Nanoparticles ◽  
Rice Husk ◽  
Heterogeneous Catalysts ◽  
Catalytic Performance ◽  
Added Value ◽  
Oxide Nanoparticles ◽  
Porous Support ◽  
Green Materials ◽  
Catalytically Active

Biomass-derived materials are put forward as eco-friendly alternatives to design heterogeneous catalysts. To contribute in this field, we explored the potential of mesoporous biogenic silica (RH-Silica) obtained from lignocellulosic waste, in particular from rice husk, as an inorganic support to prepare heterogenized iron oxide-based catalysts. Mechanochemistry, considered as a green and sustainable technique, was employed to synthetize iron oxide nanoparticles in pure hematite phase onto the biosilica (α-Fe2O3/RH-Silica), making this material a good candidate to perform catalyzed organic reactions. The obtained material was characterized by different techniques, and its catalytic activity was tested in the selective oxidation of styrene under microwave irradiation. α-Fe2O3/RH-Silica displayed a good catalytic performance, achieving a conversion of 45% under optimized conditions, and more importantly, with a total selectivity to benzaldehyde. Furthermore, a good reusability was achieved without decreasing its activity after multiple catalytic cycles. This work represents a good example of using sustainable approaches and green materials as alternatives to conventional methods in the production of high-added value products.

scholarly journals The Effects of Magnetic Nanoparticles Incorporated in Polyelectrolyte Capsules

2017 ◽  
Vol 54 (4) ◽  
pp. 630-634
Author(s):  
Carmen Stavarache ◽  
Mircea Vinatoru ◽  
Timothy Mason ◽  
Larysa Paniwnyk
Keyword(s):  
Iron Oxide ◽  
Magnetic Nanoparticles ◽  
Calcium Carbonate ◽  
Ferric Oxide ◽  
Iron Content ◽  
Single Layer ◽  
Oxide Nanoparticles ◽  
Polyelectrolyte Multilayer ◽  
The Core ◽  
Calcium Carbonate Template

Polyelectrolyte multilayer capsules are synthesized comprising of 12 total layers each containing a single layer of iron oxide nanoparticles in shells 4, 6, 8 or 10. A protein-labelled dye is embedded in the calcium carbonate template core as a model for the encapsulation of a drug. The core is dissolved after 6 layers are formed. Two types of magnetic nanoparticles are incorporated into various capsule shells: ferric oxide (Fe2O3, 50 nm) and iron oxide (Fe3O4, 15 nm), a 1:1 (vol.) mixture of the two types of nanoparticles suspensions is also used. Nanoparticle inclusion reduces the capsule sizes in all cases with the order of effect Fe3O4 [ Fe2O3 [ Fe2O3/Fe3O4 mixture. When Fe3O4 or a Fe2O3/Fe3O4 mixture is incorporated in layer 6 the reduction in size of the final capsules is less than expected. The number of surviving capsules containing nanoparticles are lower than control regardless of which of the nanoparticles is used but here the effect of Fe3O4 or a mixture of the two types of nanoparticles incorporated in layer 6 was slightly out of step. The amount of iron incorporated is almost the same regardless of which shell the nanoparticles were incorporated but the iron content using 50 nm nanoparticles is generally slightly higher than that obtained with 15 nm nanoparticles.

Preparation of Fe/activated carbon directly from rice husk pyrolytic carbon and its application in catalytic hydroxylation of phenol

RSC Advances ◽  
2015 ◽  
Vol 5 (7) ◽  
pp. 4984-4992 ◽  
Author(s):  
Xian Zhang ◽  
Yaxin Li ◽  
Guiying Li ◽  
Changwei Hu
Keyword(s):  
Activated Carbon ◽  
Rice Husk ◽  
Pyrolytic Carbon ◽  
Catalytic Performance ◽  
Phenol Hydroxylation ◽  
Hydroxylation Of Phenol ◽  
One Step

The loading of iron and the formation of activated carbon were combined to one step and the thus-obtained Fe/activated carbon showed good catalytic performance for phenol hydroxylation.

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