Effect of Heat Setting and Dyeing on Tensile Strength and Shrinkage Properties of Poly(Lactic Acid) Fibre

Author(s):  
Yuk-mei Chui ◽  
Yu-chun Chuang ◽  
Chi-wai Kan
2019 ◽  
Vol 821 ◽  
pp. 89-95
Author(s):  
Wanasorn Somphol ◽  
Thipjak Na Lampang ◽  
Paweena Prapainainar ◽  
Pongdhorn Sae-Oui ◽  
Surapich Loykulnant ◽  
...  

Poly (lactic acid) or PLA was reinforced by nanocellulose and polyethylene glycol (PEG), which were introduced into PLA matrix from 0 to 3 wt.% to enhance compatibility and strength of the PLA. The nanocellulose was prepared by TEMPO-mediated oxidation from microcrystalline cellulose (MCC) powder and characterized by TEM, AFM, and XRD to reveal rod-like shaped nanocellulose with nanosized dimensions, high aspect ratio and high crystallinity. Films of nanocellulose/PEG/PLA nanocomposites were prepared by solvent casting method to evaluate the mechanical performance. It was found that the addition of PEG in nanocellulose-containing PLA films resulted in an increase in tensile modulus with only 1 wt% of PEG, where higher PEG concentrations negatively impacted the tensile strength. Furthermore, the tensile strength and modulus of nanocellulose/PEG/PLA nanocomposites were higher than the PLA/PEG composites due to the existence of nanocellulose chains. Visual traces of crazing were detailed to describe the deformation mechanism.


2021 ◽  
Vol 22 (6) ◽  
pp. 3150
Author(s):  
Anna Masek ◽  
Stefan Cichosz ◽  
Małgorzata Piotrowska

The study aimed to prepare sustainable and degradable elastic blends of epoxidized natural rubber (ENR) with poly(lactic acid) (PLA) that were reinforced with flax fiber (FF) and montmorillonite (MMT), simultaneously filling the gap in the literature regarding the PLA-containing polymer blends filled with natural additives. The performed study reveals that FF incorporation into ENR/PLA blend may cause a significant improvement in tensile strength from (10 ± 1) MPa for the reference material to (19 ± 2) MPa for the fibers-filled blend. Additionally, it was found that MMT employment in the role of the filler might contribute to ENR/PLA plasticization and considerably promote the blend elongation up to 600%. This proves the successful creation of the unique and eco-friendly PLA-containing polymer blend exhibiting high elasticity. Moreover, thanks to the performed accelerated thermo-oxidative and ultraviolet (UV) aging, it was established that MMT incorporation may delay the degradation of ENR/PLA blends under the abovementioned conditions. Additionally, mold tests revealed that plant-derived fiber addition might highly enhance the ENR/PLA blend’s biodeterioration potential enabling faster and more efficient growth of microorganisms. Therefore, materials presented in this research may become competitive and eco-friendly alternatives to commonly utilized petro-based polymeric products.


Fibers ◽  
2020 ◽  
Vol 8 (8) ◽  
pp. 50
Author(s):  
Warren J. Grigsby ◽  
Arpit Puri ◽  
Marc Gaugler ◽  
Jan Lüedtke ◽  
Andreas Krause

This study reports on the use of poly(lactic acid) (PLA) as a renewable thermoplastic adhesive for laminated panels using birch, spruce, and pine veneers. Consolidated panels were prepared from veneer and PLA foils by hot-pressing from 140 to 180 °C to achieve minimum bondline temperatures. Evaluation of panel properties revealed that the PLA-bonded panels met minimum tensile strength and internal bond strength performance criteria. However, the adhesion interface which developed within individual bondlines varied with distinctions between hardwood and softwood species and PLA grades. Birch samples developed greater bondline strength with a higher pressing temperature using semi-crystalline PLA, whereas higher temperatures produced a poorer performance with the use of amorphous PLA. Panels formed with spruce or pine veneers had lower bondline performance and were also similarly distinguished by their pressing temperature and PLA grade. Furthermore, the potential for PLA-bonded laminated panels was demonstrated by cold water soak testing. Samples exhibiting relatively greater bondline adhesion had wet tensile strength values comparable to those tested in dry state. Our study outcomes suggest the potential for PLA bonding of veneers and panel overlays with the added benefits of being renewable and a no added formaldehyde system.


2018 ◽  
Vol 33 (3) ◽  
pp. 289-304 ◽  
Author(s):  
Kuhananthan Nanthakumar ◽  
Chan Ming Yeng ◽  
Koay Seong Chun

This research covers the preparation of poly(lactic acid) (PLA)/sugarcane leaves fibre (SLF) biofilms via a solvent-casting method. The results showed that the tensile strength and Young’s modulus of PLA/SLF biofilms increased with the increasing of SLF content. Nevertheless, the elongation at break showed an opposite trend as compared to tensile strength and Young’s modulus of biofilms. Moreover, water absorption properties of PLA/SLF biofilms increased with the increasing of SLF content. In contrast, the tensile strength and Young’s modulus of biofilms were enhanced after bleaching treatment with hydrogen peroxide on SLF, but the elongation at break and water absorption properties of bleached biofilms were reduced due to the improvement of filler–matrix adhesion in biofilms. The tensile and water properties were further discussed using B-factor and Fick’s law, respectively. Furthermore, the functional groups of unbleached and bleached SLF were characterized by Fourier transform infrared analysis.


2013 ◽  
Vol 647 ◽  
pp. 798-801 ◽  
Author(s):  
Wen Can Xi ◽  
Hong Mei Kang ◽  
Hua Li ◽  
He Zhou Liu ◽  
Wei Jie Wang ◽  
...  

Binary blendscomposed of polyhrdroxyalkanoates (P34HB) and poly(lactic acid) (PLA) with various P34HB weight percentage were preparedby extrusion and compressing molding.Both the thermo-oxidative agingat 80°Cand the hydrothermal aging at 80°C with 80% humidity were performed for 300 h for the P34HB/PLA blends respectively.The mechanical properties of tensile strength and elongation-at-breakrevealed that P34HB/PLA blends possessedthe balanced mechanical properties between P34HB and PLA,theblends with higher ratio of P34HBshowed thedeteriorative mechanical behavior in the aging environment faster than thoseblends with lower ratio of P34HB.


2016 ◽  
Vol 30 (10) ◽  
pp. 1650052
Author(s):  
W. D. Cheng ◽  
C. Z. Cai ◽  
Y. Luo ◽  
Y. H. Li ◽  
C. J. Zhao

According to an experimental dataset under different process parameters, support vector regression (SVR) combined with particle swarm optimization (PSO) for its parameter optimization was employed to establish a mathematical model for prediction of the tensile strength of poly (lactic acid) (PLA)/graphene nanocomposites. Four variables, while graphene loading, temperature, time and speed, were employed as input variables, while tensile strength acted as output variable. Using leave-one-out cross validation test of 30 samples, the maximum absolute percentage error does not exceed 1.5%, the mean absolute percentage error (MAPE) is only 0.295% and the correlation coefficient [Formula: see text] is as high as 0.99. Compared with the results of response surface methodology (RSM) model, it is shown that the estimated errors by SVR are smaller than those achieved by RSM. It revealed that the generalization ability of SVR is superior to that of RSM model. Meanwhile, multifactor analysis is adopted for investigation on significances of each experimental factor and their influences on the tensile strength of PLA/graphene nanocomposites. This study suggests that the SVR model can provide important theoretical and practical guide to design the experiment, and control the intensity of the tensile strength of PLA/graphene nanocomposites via rational process parameters.


2011 ◽  
Vol 675-677 ◽  
pp. 357-360
Author(s):  
Li Jun Qin ◽  
Jian Hui Qiu ◽  
Ming Zhu Liu ◽  
Sheng Long Ding ◽  
Liang Shao ◽  
...  

The modified rice straw fibers (MRSF) were prepared by suspension polymerization technique of butyl acrylate (BA) monomer and rice straw fibers (RSF) in water solution. FTIR test indicated that PBA was coated and absorbed on RSF.The biodegradable composites were prepared with the MRSF and poly(lactic acid) (PLA) by HAAKE rheometer. Mechanical properties showed that the tensile strength of PLA/MRSF composites were (W (%) =7.98%) increased by 6 MPa compared with blank sample. The possible reason was that the good interfacial adhesion between PLA and MRSF, which was demonstrated by SEM.


2017 ◽  
Vol 88 (14) ◽  
pp. 1616-1627 ◽  
Author(s):  
Shu-qiang Liu ◽  
Gai-hong Wu ◽  
Yun-chao Xiao ◽  
Hong-xia Guo ◽  
Fen-juan Shao

Poly(lactic acid) (PLA) fiber, owing to its biocompatibility and biodegradability, could be widely used in many related industrial areas. However, high brittleness has been the main obstacle to expanding its applications. So in this paper, carbon nanotube (CNT) nanocapsules were designed to toughen PLA and further reported their effect on the crystallization behavior and mechanical properties of PLA complex fiber. These designed CNT nanocapsules successfully solved the agglomeration of CNTs within the PLA matrix as well as the compatibility issue. In addition, the morphological, mechanical, optical and thermal properties of PLA complex fibers were also studied. The addition of CNT nanocapsules obviously improved the crystallization behavior of PLA fiber. Furthermore, compared with pure PLA, the tensile strength of PLA complex fiber was enhanced by 30.62% and the elongation by 32.2%, so the designed CNT nanocapsules could be used as a toughener for PLA fiber. This research benefits the extension of PLA applications where toughness is an important factor.


2011 ◽  
Vol 31 (6-7) ◽  
Author(s):  
Xiuju Zhang ◽  
Juncai Shen ◽  
Tingting Yang ◽  
Bihua Ye ◽  
Zhidan Lin ◽  
...  

Abstract In this study, waste cotton cloth (RC) was bonded with soluble starches as an adhesive, then dried, cut into particles and filled into polylactic acid (PLA) to achieve resource efficiency. The mechanical, thermal and crystallization properties of the composites were characterized. The results indicated that with the addition of RC, the tensile strength, impact strength and flexural strength of PLA composites improved. Also, the heat distortion temperatures increased slowly, indicating that RC filled into PLA can be turned back into useful items without the degradation of PLA composites. This is a good way to give direction to the resource utilization of waste clothing. The addition of RC could significantly reduce the spherulitic size of PLA.


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