scholarly journals Studies on the removal of copper ions from industrial effluent by Azadirachta indica powder

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Suhair Saif Al Moharbi ◽  
M. Geetha Devi ◽  
B. M. Sangeetha ◽  
Shah Jahan
Keyword(s):  
Aqueous Solutions ◽  
Azadirachta Indica ◽  
Copper Ions ◽  
Experimental Studies ◽  
Industrial Effluent ◽  
Experimental Result ◽  
Pollution Level ◽  
Solution Ph ◽  
Stirring Time ◽  
Leaf Powder

AbstractRapid industrialization, urbanization and population growth have resulted in air, water and land pollution. Water pollution is a major concern across the globe. Discharge of huge amount of industrial wastewater adversely affects the human and environment. Heavy metal pollution is considered to be one of the serious environmental problems today. Due to strict environmental regulations in the country, it is required to bring down the pollution level to a permissible limit. The present study assessed the capability of Azadirachta indica (neem leaf) powder as a natural adsorbent in the removal of copper ions from aqueous solutions. The characterization of the adsorbent was performed using X-ray diffraction, scanning electron microscopy and Fourier-transform infrared spectroscopy. Series of batch experimental studies were carried out by changing the solution pH, stirring time, adsorbent dosage and stirring speed in the removal of copper from aqueous solution using A. indica as biosorbent. The experimental result shows that the percentage removal of copper was highest at the following optimized conditions: pH 7.0, stirring time 60 min and biosorbent dosage of 1.0 g and at 125 RPM speed. The studies indicate that A. indica is considered to be a promising type of biomass for the removal of copper ions from aqueous solutions.

Adsorption of Chromium (VI) from Aqueous Solutions Using Sol-Gel Anionic Clays with Mg/ Al=7

2009 ◽  
Vol 1242 ◽  
Author(s):  
Ramos R. Esthela ◽  
Gutiérrez O. Norma ◽  
Contreras S. Cesar ◽  
Álvarez R. Javier ◽  
Fuentes R. Rosalba
Keyword(s):  
Aqueous Solutions ◽  
High Surface ◽  
Sol Gel ◽  
Toxic Heavy Metals ◽  
Solution Ph ◽  
Langmuir Adsorption ◽  
Surface Areas ◽  
Chromium Vi ◽  
Anionic Clays ◽  
Stirring Time

ABSTRACTAnionic clays has been used in the adsorption of anionic species of toxic heavy metals, such as chromium (VI), which is considered to be a dangerous pollutant, due to its deleterious effects on human health such as epithelial irritation and cancer. In this work the removal of chromium in aqueous solutions using anionic clays with Mg/Al=7 was determined. The anionic clays were synthesized by the sol-gel method at pH 10 and 11.5, and were characterized by X-ray diffraction, thermal analysis, infrared spectroscopy and N2 adsorption Brunauer-Emmett-Teller (BET). By this method, anionic clay containing brucite was obtained. The solids exhibited meso-porosity, high surface areas and thermal stability until 500°C. The data obtained from the adsorption experiments of chromium fitted to the Langmuir adsorption isotherm model and the adsorbent capacity was determined using the Langmuir adsorption equation. The maximum chromium uptake was 45 mg of Cr/g sorbent and 43 mg Cr/g sorbent for anionic clays prepared to pH 10 and 11.5, respectively. The Cr saturation point was attained after eight minutes stirring time. According to chromium adsorption values, the solution pH does not have a significant affect on the adsorption capacity of the anionic clays.

scholarly journals Removal of Organic Pollutants from Textile Mill Effluent using Azadirachta Indica Powder

2021 ◽  
Vol 18 (24) ◽  
pp. 1412
Author(s):  
Geetha Devi ◽  
Moza Saif Alkalbani ◽  
Anna Jesil ◽  
Joefel Jessica Casino Dumaran ◽  
Sonia Ibarra Buscano
Keyword(s):  
Organic Pollutants ◽  
Azadirachta Indica ◽  
Experimental Studies ◽  
Processing Conditions ◽  
Textile Mill ◽  
X Ray ◽  
Effective Removal ◽  
Stirring Time ◽  
Scanning Electron ◽  
Promising Type

Due to stringent environmental regulations and increased awareness about the environment, effluent treatment has always been a key aspect of research. Textile industry is one of the oldest and technologically advanced complex industrial sectors employing variety of chemicals and large amount of fresh water consumption. These effluents contain substantial amount of organic pollutants and suspended impurities in varying compositions and hence cannot be discharged directly into the environment. The current research work focused on the utilization of Azadirachta Indica powder as a natural adsorbent for the effective removal of organic and suspended pollutants from textile mill effluent. A series of batch experimental studies were performed by varying the pH of textile mill effluent, stirring time, stirring speed and dosage of Azadirachta Indica powder. Chemical Oxygen Demand (COD), Total Dissolved Solids (TDS), Total Suspended Solids (TSS), Dissolved Oxygen (DO), conductivity, and turbidity were estimated to study the performance of Azadirachta Indica powder in the removal of pollutants. The characterizations of Azadirachta Indica powder before and after treatment are performed using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX), X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). The best processing conditions for the effective removal of pollutants from textile mill effluent was obtained at an effluent solution pH 4.0, stirring time 90 min, stirring speed 150 rpm with 1.0 g of Azadirachta Indica powder. The surface morphological structure of Azadirachta Indica powder after batch treatment using scanning electron microscopy indicated that the pollutants are accumulated in the form of clusters on the adsorbent surface. The FTIR spectral analysis indicates the chemical interaction between adsorbent powder and organic pollutants illustrate the characteristic peaks. The study demonstrates that the Azadirachta indica is a promising type of biomass for the effective removal of pollutants from textile mill effluent. HIGHLIGHTS In this research, Azadirachta Indica powder was employed as a natural adsorbent for the effective removal of pollutants from textile mill effluent Batch experimental studies were performed by varying the pH of textile mill effluent, stirring time, stirring speed and dosage of Azadirachta Indica powder and the optimum processing conditions were established The study demonstrates that the Azadirachta indica is a promising type of biomass for the effective removal of pollutants from textile mill effluent GRAPHICAL ABSTRACT

scholarly journals An Investigation on Design and Characterization of a Highly Selective LED Optical Sensor for Copper Ions in Aqueous Solutions

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1099
Author(s):  
Sheng-Chun Hung ◽  
Chih-Cheng Lu ◽  
Yu-Ting Wu
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Copper Ions ◽  
Incident Light ◽  
Copper Ion ◽  
Intensity Change ◽  
Optical Absorbance ◽  
Sensing System ◽  
Optic Sensor ◽  
Cu Ions

The optical characteristics of copper ion detection, such as the photometric absorbance of specific wavelengths, exhibit significant intensity change upon incident light into the aqueous solutions with different concentrations of metal ions due to the electron transition in the orbit. In this study, we developed a low-cost, small-size and fast-response photoelectric sensing prototype as an optic sensor for copper (Cu) ions detection by utilizing the principle of optical absorption. We quantified the change of optical absorbance from infra-red (IR) light emitting diodes (LEDs) upon different concentrations of copper ions and the transmitted optical signals were transferred to the corresponding output voltage through a phototransistor and circuit integrated in the photoelectric sensing system. The optic sensor for copper (Cu) ions demonstrated not only excellent specificity with other metal ions such as cadmium (Cd), nickel (Ni), iron (Fe) and chloride (Cl) ions in the same aqueous solution but also satisfactory linearity and reproducibility. The sensitivity of the preliminary sensing system for copper ions was 29 mV/ppm from 0 to 1000 ppm. In addition, significant ion-selective characteristics and anti-interference capability were also observed in the experiments by the proposed approach.

Removal of Copper Ions from Aqueous Solutions via Adsorption on Carbon Nanocomposites

2015 ◽  
Vol 7 (28) ◽  
pp. 15674-15680 ◽  
Author(s):  
Anthony B. Dichiara ◽  
Michael R. Webber ◽  
William R. Gorman ◽  
Reginald E. Rogers
Keyword(s):  
Aqueous Solutions ◽  
Copper Ions ◽  
Carbon Nanocomposites

Biosorption of copper ions from aqueous solutions using the desert treeAcacia raddiana

2010 ◽  
Vol 21 (1-3) ◽  
pp. 323-327 ◽  
Author(s):  
M. F. Talhi ◽  
A. Cheriti ◽  
N. Belboukhari ◽  
L. Agha ◽  
C. Roussel
Keyword(s):  
Aqueous Solutions ◽  
Copper Ions

scholarly journals Oxytetracycline Adsorption from Aqueous Solutions on Commercial and High-Temperature Modified Activated Carbons

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3481
Author(s):  
Joanna Lach ◽  
Agnieszka Ociepa-Kubicka ◽  
Maciej Mrowiec
Keyword(s):  
Activated Carbon ◽  
Aqueous Solutions ◽  
Activated Carbons ◽  
Electricity Consumption ◽  
Solution Ph ◽  
Carbon Modification ◽  
Modification Method ◽  
Flow Through ◽  
Proposed Modification ◽  
Modified Activated Carbons

The aim of the work was to evaluate the possibility of using commercial and modified activated carbons for the removal of oxytetracycline from aqueous solutions. The kinetics and statics of adsorption as well as the effect of the activated carbon dose and solution pH on the efficiency of the oxytetracycline adsorption were analyzed. Based on the study of oxytetracycline adsorption isotherms, the activated carbons were ranked in the following order: F-300 > WG-12 > Picabiol > ROW08 > WACC 8 × 30 > F-100 > WAZ 0.6–2.4. The most effective activated carbons were characterized by large specific surfaces. The best matching results were obtained for: Redlich–Peterson, Thot and Jovanovic models, and lower for the most frequently used Freundlich and Langmuir models. The adsorption proceeded better from solutions with pH = 6 than with pH = 3 and 10. Two ways of modifying activated carbon were also assessed. A proprietary method of activated carbon modification was proposed. It uses the heating of activated carbon as a result of current flow through its bed. Both carbons modified at 400 °C in the rotary kiln and on the proprietary SEOW (Joule-heat) modification stand enabled to obtain adsorbents with higher and comparable monolayer capacities. The advantage of the proposed modification method is low electricity consumption.

scholarly journals Adsorption of Pollutants from Aqueous Solutions Using Activated and Non-Activated Oak Shells: Parametric and Fractional Factorial Design Study. Part II. Removal of Phenol and Dyes

2003 ◽  
Vol 21 (2) ◽  
pp. 189-198
Author(s):  
Sameer Al-Asheh ◽  
Fawzi Banat ◽  
Rana Saeidi ◽  
Salam Abu Zaid
Keyword(s):  
Methylene Blue ◽  
Aqueous Solutions ◽  
Factorial Design ◽  
Fractional Factorial Design ◽  
Sorption Process ◽  
Fractional Factorial ◽  
Phenol Concentration ◽  
Blue Dye ◽  
Batch Adsorption ◽  
Solution Ph

As in Part I, non-activated (natural) and chemically activated oak shells were evaluated for their ability to remove phenol and Methylene Blue (as a typical dye component) from aqueous solutions. Batch adsorption experiments were conducted to investigate the effect of contact time, sorbent concentration, phenol concentration and the pH of the solution on the sorption process. Activated oak shells adsorbed more phenol than natural oak shells under the same conditions. A decrease in sorbent concentration or an increase in phenol concentration or solution pH resulted in an increase in phenol uptake by the oak shells. The uptake of Methylene Blue increased with decreasing sorbent concentration and with an increase in the dye concentration, but decreased significantly with solution pH. According to the fractional factorial design technique, the sorbent type employed (natural or activated) had the most significant influence on phenol or Methylene Blue uptake followed by sorbent concentration and then sorbate concentration. Interaction amongst the different operating variables played an important role in the uptake of phenol or Methylene Blue dye by the adsorbent considered.

scholarly journals Effect Of Preserved Seeds Using Different Botanicals On Seed Quality Of Lentil

1970 ◽  
Vol 36 (3) ◽  
pp. 381-387 ◽  
Author(s):  
A Khatun ◽  
G Kabir ◽  
MAH Bhuiyan ◽  
D Khanam
Keyword(s):  
Moisture Content ◽  
Azadirachta Indica ◽  
Seed Quality ◽  
Shoot Length ◽  
Germination Capacity ◽  
Laboratory Studies ◽  
Polygonum Hydropiper ◽  
Vigour Index ◽  
Leaf Powder

Laboratory studies were conducted with leaf powder of three plants to show the preservative effect for maintaining the quality of lentil seeds in storage. After processing and drying, seeds were preserved with different botanicals and stored them in earthen pots for eight months. Botanicals, such as whole leaf powder of neem (Azadirachta indica), dholkalmi (Ipmoea sepiara), and bishkatali (Polygonum hydropiper) were used at a dose of 5% w/w (25 g botanical per 500 g of lentil seeds). The lentil seeds were stored till next planting time and seed quality, such as moisture content, germination capacity, root length, shoot length of the seedlings and vigour index were observed. The highest values for all these characters except moisture content were significant when the seeds were preserved with neem leaf powder and bishkatali. Among three botanicals, dholkalmi was less effective. Keywords: Lentil; botanicals; storage; seed quality DOI: http://dx.doi.org/10.3329/bjar.v36i3.9266 BJAR 2011; 36(3): 381-387

scholarly journals Photoreduction of Cr(VI) Ions in Aqueous Solutions by UV/ Photocatalytic Processes

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Chih Ming Ma ◽  
Yung Shuen Shen ◽  
Po Hsiang Lin
Keyword(s):  
Aqueous Solutions ◽  
Reaction Rate ◽  
Removal Rate ◽  
Experimental Results ◽  
Order Kinetic ◽  
Solution Ph ◽  
Relationship Of ◽  
The Relationship ◽  
Photocatalytic Processes ◽  
Order Kinetic Equation

This study discussed the photoreduction of Cr(VI) ions in aqueous solutions by UV/TiO2photocatalytic processes under various operational factors. Experimental results showed that the removal rate of Cr(VI) increased with decreasing solution pH values and with increasing dosages of organic compounds, indicating that the recombination rate of electrons and h+can be retarded in the reaction systems by the addition of the scavenger, thus raising the reaction rate of Cr(VI). The relationship of the chemical reaction rate of Cr(VI), TiO2dosage, and changes of Cr(VI) concentration was expressed by the pseudo-first-order kinetic equation. Comparing the experimental results of two different doping metals in modified TiO2photoreduction systems, the removal rate of Cr(VI) by the Ag/TiO2process is larger, possibly because the electron transferring ability of Ag is superior to that of Cu. However, the photoreduction rates of Cr(VI) by modified UV/TiO2processes are worse than those by a nonmodified commercial UV/TiO2process.

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