scholarly journals SEM morphological analysis of irradiated polystyrene film doped by a Schiff base containing a 1,2,4-triazole ring system

2019 ◽  
Vol 9 (3-4) ◽  
pp. 169-177 ◽  
Author(s):  
Ahmed A. Ahmed ◽  
Dina S. Ahmed ◽  
Gamal A. El-Hiti ◽  
Mohammad Hayal Alotaibi ◽  
Hassan Hashim ◽  
...  

Abstract A Schiff base containing the 1,2,4-triazole moiety was synthesized and added to polystyrene at low concentration for a homogenous blend. The polystyrene film was irradiated with ultraviolet light and the surface morphology was analyzed. Micrographs of the polystyrene/Schiff base blend after irradiation indicated the fabrication of a terrestrial crack-like material. This was ascribed to the presence of the Schiff base, relatively long irradiation time, and photostability induced by the base. After irradiation, the blank polystyrene film formed a cotton-like fibrous material.

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1185 ◽  
Author(s):  
Emad Yousif ◽  
Dina Ahmed ◽  
Gamal El-Hiti ◽  
Mohammad Alotaibi ◽  
Hassan Hashim ◽  
...  

Polystyrene films containing a low concentration of three highly aromatic Schiff bases were prepared using the casting method. The polystyrene films were irradiated with ultraviolet light (300 h). The polystyrene infrared spectra, weight loss, molecular weight reduction and the surface morphology were examined upon irradiation. The Schiff bases acted as photostabilizers and reduced the photodegradation of polystyrene films to a significant level in comparison to the blank film. The images recorded of the surface of the miscible polystyrene/Schiff base blends showed novel ball-like microspheres with a diameter of 3.4–4.3 µm. The Schiff bases were able to endow excellent protection to polystyrene against ultraviolet irradiation.


IUCrData ◽  
2020 ◽  
Vol 5 (2) ◽  
Author(s):  
Nurulizzatul Ningsheh M. Shahri ◽  
Nur Halilatul Sadiqin Omar Ali ◽  
Malai Haniti Sheikh Abdul Hamid ◽  
Aminul Huq Mirza ◽  
Anwar Usman ◽  
...  

The title hemihydrate, C12H9N5·0.5H2O, was isolated from the condensation reaction of quinoline-2-carbaldehyde with 4-amino-4H-1,2,4-triazole. The Schiff base molecule adopts an E configuration about the C=N bond and is approximately planar, with a dihedral angle between the quinoline ring system and the 1,2,4-triazole ring of 12.2 (1)°. In the crystal, one water molecule bridges two Schiff base molecules via O—H...N hydrogen bonds. The Schiff base molecules are interconnected by π–π stacking interactions [centroid-centroid distances of 3.7486 (7) and 3.9003 (7) Å] into columns along [1\overline{1}0].


2020 ◽  
Vol 41 (1) ◽  
pp. 26-35
Author(s):  
Kishor Devkota ◽  
Govinda Pathak ◽  
Bhushan Shakya

Triazole ring system has attracted a continuously growing interest of synthetic organic chemists and those dealing with the medicinal compounds due to its versatile potential to interact with biological systems. Schiff bases are also considered as one of the most biologically active compounds.  The aim of the present study was to synthesize new Schiff bases bearing triazole nucleus and to assess their antimicrobial activities. Four new Schiff base derivatives of 1,2,4-triazole-3-thione were synthesized by combining two different pharmacophores viz. triazole nucleus and Schiff base moiety and were characterized by spectral techniques (UV, FT-IR, and NMR). The Schiff bases were evaluated for antibacterial (Staphylococcus aureus, Escherichia coli, and Klebsiella pneumoniae) and antifungal (Candida albicans) activities. The synthesized compounds exhibited good to moderate activities against different strains of bacteria and fungi tested.


2021 ◽  
Vol 11 (12) ◽  
pp. 5427
Author(s):  
Arturo Sanchez-Perez ◽  
Nuria Cano-Millá ◽  
María José Moya Villaescusa ◽  
José María Montoya Carralero ◽  
Carlos Navarro Cuellar

Photoactivation with ultraviolet C light can reverse the effects derived from biological ageing by restoring a hydrophilic surface. Ten titanium discs were randomly divided into three groups: a control group, a 6 W group, and an 85 W group. A drop of double-distilled, deionized, and sterile 10 µL water was applied to each of the discs. Each disc was immediately photographed in a standardized and perpendicular manner. Measurements were taken based on the irradiation time (15, 30, 60, and 120 min). UVC irradiation improved the control values in both groups. There was no difference in its effect between the 6 W group and the other groups during the first 30 min. However, after 60 min and up to 120 min, 85 W had a significantly stronger effect. The contact angles with the 85 W ultraviolet light source at 60 and 120 min were 19.43° and 31.41°, respectively, whereas the contact angles for the 6 W UVC source were 73.8° and 61.45°. Power proved to be the most important factor, and the best hydrophilicity result was obtained with a power of 85 W for 60 min at a wavelength of 254 nm.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Mohd Ann Amirul Zulffiqal Md Sahar ◽  
Zainuriah Hassan ◽  
Sha Shiong Ng ◽  
Way Foong Lim ◽  
Khai Shenn Lau ◽  
...  

Purpose The aims of this paper is to study the effects of the V/III ratio of indium gallium nitride (InGaN) quantum wells (QWs) on the structural, optical and electrical properties of near-ultraviolet light-emitting diode (NUV-LED). Design/methodology/approach InGaN-based NUV-LED is successfully grown on the c-plane patterned sapphire substrate at atmospheric pressure using metal organic chemical vapor deposition. Findings The indium composition and thickness of InGaN QWs increased as the V/III ratio increased from 20871 to 11824, according to high-resolution X-ray diffraction. The V/III ratio was also found to have an important effect on the surface morphology of the InGaN QWs and thus the surface morphology of the subsequent layers. Apart from that, the electroluminescence measurement revealed that the V/III ratio had a major impact on the light output power (LOP) and the emission peak wavelength of the NUV-LED. The LOP increased by up to 53% at 100 mA, and the emission peak wavelength of the NUV-LED changed to a longer wavelength as the V/III ratio decreased from 20871 to 11824. Originality/value This study discovered a relation between the V/III ratio and the properties of QWs, which resulted in the LOP enhancement of the NUV-LED. High TMIn flow rates, which produced a low V/III ratio, contribute to the increased LOP of NUV-LED.


2016 ◽  
Vol 45 (8) ◽  
pp. 3914-3920 ◽  
Author(s):  
Irmak Karaduman ◽  
Özlem Barin ◽  
Metin Özer ◽  
Selim Acar

2017 ◽  
Vol 10 (4) ◽  
pp. 1059
Author(s):  
Fabiana Cristina Meira Zaparoli ◽  
Nelson Vicente Lovatto Gasparetto

This research aimed to compare the surface morphology of quartz grains of the E and Bt horizons of an Ultisol of the Aratu stream basin, in the city of Floraí, Paraná. The Ultisol is derived from sandstones of the Caiuá Formation and it is subjected to mesothermal humid subtropical climate. The materials from the E horizon showed abundant porosity compared to the Bt horizon ones, due to the filling of pores by coating of clay and iron oxides. On the surface of the quartz grains of the E horizon, several features were identified such as ";craters";, pyramidal microfeatures, gulfs of dissolution, elongated cavities, and silica reprecipitation, resulting from the chemical change, and fragmented grains resulting from a phenomenon called ";plasma infusion."; In the Bt horizon, nearly all the detrital grains were surrounded by clay and iron oxide. The detrital grains of the Bt horizon were better preserved, showing little corrosion features and rare fragmented grains, compared to the E horizon. These analyzes showed that the water flow accounts for the superficial alteration of detrital quartz grains when they are under the influence of humid subtropical climate.  R E S U M OA pesquisa teve como objetivo comparar a morfologia superficial de grãos de quartzo dos horizontes E e Bt de um Argissolo da bacia do córrego Aratu, no município de Floraí, PR. O Argissolo é derivado de arenitos da Formação Caiuá e submetido a clima subtropical úmido mesotérmico. Os materiais do horizonte E apresentam porosidade abundante quando comparados com os do horizonte Bt, em razão do preenchimento dos poros por revestimentos de argila e óxidos de ferro. Foram identificadas na superfície dos grãos de quartzo do horizonte E várias feições tipo “crateras”, microfeições piramidais, golfos de dissolução, cavidades alongadas, reprecipitação de sílica, oriundas da alteração química, e grãos fragmentados devido ao fenômeno denominado “plasma infusion”. No horizonte Bt, praticamente todos os grãos detritais estão envolvidos por argila e óxidos de ferro. Os grãos detritais do horizonte Bt estão mais preservados, exibindo poucas feições de corrosão e raros grãos fragmentados, se comparados com os do horizonte E. Essas análises demonstraram que o fluxo hídrico é o responsável pela alteração superficial dos grãos detritais de quartzo quando sob a influência de clima subtropical úmido. Palavras-chave: Argissolo, morfologia de grãos de quartzo, alteração geoquímica, fluxo hídrico 


IUCrData ◽  
2020 ◽  
Vol 5 (4) ◽  
Author(s):  
Sowmiya Carmel Y. ◽  
N. L. Prasad ◽  
Noor Shahina Begum ◽  
Hari Prasad Suresh

In the title compound, C16H19N3O2Si, the dihedral angle between the coumarin ring system (r.m.s. deviation = 0.031 Å) and the triazole ring is 73.81 (8)°. In the crystal, molecules are linked into [010] chains by weak C—H...O interactions.


2019 ◽  
Vol 22 (4) ◽  
pp. 277-282
Author(s):  
Salam A. Mohammed ◽  
Rahimi M. Yusop ◽  
Mohammed Abdulsattar Mohammed ◽  
Rasheed Abed Mohammed ◽  
Dina S. Ahmed ◽  
...  

Poly(vinyl chloride) photodecomposition films that contains melamine Schiff base (0.5% by weight) as photostabilizers upon preservation with an ultraviolet light (UV) was investigated. The photodecomposition rate constant was reduced significantly in existence of melamine Schiff base compared to PVC (blank). The Schiff base 1 was found to most effective additive in PVC photostabilization films. Photodecomposition rate content for PVC films containing Schiff base 1 was found to be 5 × 10-3 sec-1 compared to 8.7 × 10-3 sec-1 for blank film. Ultraviolet radiation aging behaviors of PVC films were studied through leaching test by measuring the degree of migration. The surface morphology of PVC films was inspected by scanning electron microscope.


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