scholarly journals Mechanical and durability assessment of cement-based and alkali-activated coating mortars in an aggressive marine environment

2021 ◽  
Vol 3 (6) ◽  
Author(s):  
Salar Lashkari ◽  
Farzad Yazdipanah ◽  
Mahyar Shahri ◽  
Prabir Sarker
Keyword(s):  
Silica Fume ◽  
Marine Environment ◽  
Strength Test ◽  
High Rate ◽  
Chloride Diffusion ◽  
Strength Development ◽  
Diffusion Resistance ◽  
Capillary Absorption ◽  
Durability Analysis ◽  
Alkali Activated

AbstractCoatings are used as practical solutions against the intrusion of corrosive ions into concrete structures, particularly, in the harsh marine environment. In the present study, the effectiveness of using cement-based and geopolymer-based coatings produced using by-product materials has been evaluated. Silica fume and GGBFS at their optimum dosages were incorporated into mortar mixtures as a cement replacement, and mixtures of NaOH or KOH and sodium silicate solutions were used in the alkali-activated mortars. Shrinkage test, RCMT, and capillary absorption test as common experiments for durability analysis, as well as tests related to the mechanical and bonding properties including compressive strength test, pull-off test, and shear bonding strength test were carried out on the specimens. According to the results, both geopolymer and cement-based mortars improved the compressive and bonding strengths, and chloride diffusion resistance of coatings compared to the OPC mortar. Silica fume was found to be more effective in the strength development of mortars at young ages, while GGBFS was more responsible for acting as a filler and producing further gel in the older ages. The major drawback with geopolymer mortars is the high rate of water absorption and shrinkage coefficient in the early hours, which shows the importance of curing of these mortars at young ages. Overall, the mix design produced with 30% GGBFS and 7.5% silica fume showed the highest durability and mechanical properties and proved to be more compatible with the harsh environment of the Persian Gulf.

scholarly journals Limitations of sorptivity and water permeability for the estimation of the chloride penetration rate in concrete regarding the accomplishment of prescriptive design for durability in the marine environment

2018 ◽  
Vol 8 (3) ◽  
pp. 301-316
Author(s):  
Yury A Villagrán Zaccardi ◽  
María E Sosa ◽  
Ángel A Di Maio
Keyword(s):  
Marine Environment ◽  
Diffusion Rate ◽  
Penetration Rate ◽  
Chloride Penetration ◽  
Chloride Diffusion ◽  
Capillary Absorption ◽  
Chloride Ingress ◽  
Water Penetration ◽  
Conventional Concrete

This paper presents an analysis of experimental data from conventional concrete regarding sorptivity and penetrability under pressure comparing these parameters to chloride diffusion rate determined in the laboratory and in actual marine environment. Prescriptions for durability assurance of reinforced concrete structures is based on the qualitative characterization of transport properties. For the specific case of the marine environment, it is required to assess the resistance of concrete to chloride ingress. The results show the limitations of both parameters as prescriptive indexes, with capillary absorption rate showing some advantages over water penetration under pressure.

Prediction of long-term chloride diffusion in silica fume concrete in a marine environment

2015 ◽  
Vol 59 ◽  
pp. 10-17 ◽  
Author(s):  
Atiye Farahani ◽  
Hosein Taghaddos ◽  
Mohammad Shekarchi
Keyword(s):  
Silica Fume ◽  
Marine Environment ◽  
Chloride Diffusion

scholarly journals Alkali-activated laterite binders: Influence of silica modulus on setting time, Rheological behaviour and strength development

2021 ◽  
pp. 100175
Author(s):  
Cyriaque Rodrigue Kaze ◽  
Adeyemi Adesina ◽  
Gisèle Laure Lecomte-Nana ◽  
Thamer Alomayri ◽  
Elie Kamseu ◽  
...  
Keyword(s):  
Setting Time ◽  
Rheological Behaviour ◽  
Strength Development ◽  
Alkali Activated

scholarly journals Positive Influence of Liquid Sodium Silicate on the Setting Time, Polymerization, and Strength Development Mechanism of MSWI Bottom Ash Alkali-Activated Mortars

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1927
Author(s):  
Lei Jin ◽  
Guodong Huang ◽  
Yongyu Li ◽  
Xingyu Zhang ◽  
Yongsheng Ji ◽  
...  
Keyword(s):  
Sodium Silicate ◽  
Setting Time ◽  
Bottom Ash ◽  
Free Water ◽  
Polymerization Reaction ◽  
Liquid Sodium ◽  
Strength Development ◽  
Mswi Bottom Ash ◽  
Alkali Activated ◽  
Development Mechanism

Setting time and mechanical properties are key metrics needed to assess the properties of municipal solid waste incineration (MSWI) bottom ash alkali-activated samples. This study investigated the solidification law, polymerization, and strength development mechanism in response to NaOH and liquid sodium silicate addition. Scanning electron microscopy and X-ray diffraction were used to identify the formation rules of polymerization products and the mechanism of the underlying polymerization reaction under different excitation conditions. The results identify a strongly alkaline environment as the key factor for the dissolution of active substances as well as for the formation of polymerization products. The self-condensation reaction of liquid sodium silicate in the supersaturated state (caused by the loss of free water) is the major reason for the rapid coagulation of alkali-activated samples. The combination of both NaOH and liquid sodium silicate achieves the optimal effect, because they play a compatible coupling role.

The Chloride Ion Penetration Model Coupled with Temperature and Moisture Transfer in Marine Environment

2012 ◽  
Vol 591-593 ◽  
pp. 2422-2427
Author(s):  
Juan Zhao
Keyword(s):  
Marine Environment ◽  
Moisture Transfer ◽  
Regional Climate ◽  
Chloride Ion ◽  
Chloride Penetration ◽  
Chloride Diffusion ◽  
Tidal Zone ◽  
Analog Simulation ◽  
Chloride Ion Penetration ◽  
Ion Penetration

Considering the complexity of the chloride ion penetration in concrete exposed to marine environment, an integrated chloride penetration model coupled with temperature and moisture transfer is proposed. The governing equations and parameters embody fully the cross-impacts among thermal conduction, moisture transfer and chloride ion penetration. Furthermore, the four exposure conditions are classified based on the different contact with the aggressive marine environment, and then the micro-climate condition on the concrete surface is investigated according to the regional climate characteristics, therefore, a comprehensive analog simulation to the chloride penetration process is proposed. To demonstrate that the proposed numerical model can correctly simulate the chloride diffusion in concrete, the integrated chloride diffusion model is applied in reproducing a real experiment, finally the model gives good agreement with the experimental profiles, and it is proved the tidal zone exposure results in a more severe attack on the reinforcement

scholarly journals Strength and Durability Performance of Alkali-Activated Rice Husk Ash Geopolymer Mortar

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Yun Yong Kim ◽  
Byung-Jae Lee ◽  
Velu Saraswathy ◽  
Seung-Jun Kwon
Keyword(s):  
Compressive Strength ◽  
Rice Husk ◽  
Rice Husk Ash ◽  
Polymerization Reaction ◽  
Strength Development ◽  
Geopolymer Concrete ◽  
Portland Cement Concrete ◽  
Mix Proportion ◽  
Strength And Durability ◽  
Alkali Activated

This paper describes the experimental investigation carried out to develop the geopolymer concrete based on alkali-activated rice husk ash (RHA) by sodium hydroxide with sodium silicate. Effect on method of curing and concentration of NaOH on compressive strength as well as the optimum mix proportion of geopolymer mortar was investigated. It is possible to achieve compressive strengths of 31 N/mm2and 45 N/mm2, respectively for the 10 M alkali-activated geopolymer mortar after 7 and 28 days of casting when cured for 24 hours at 60°C. Results indicated that the increase in curing period and concentration of alkali activator increased the compressive strength. Durability studies were carried out in acid and sulfate media such as H2SO4, HCl, Na2SO4, and MgSO4environments and found that geopolymer concrete showed very less weight loss when compared to steam-cured mortar specimens. In addition, fluorescent optical microscopy and X-ray diffraction (XRD) studies have shown the formation of new peaks and enhanced the polymerization reaction which is responsible for strength development and hence RHA has great potential as a substitute for ordinary Portland cement concrete.

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