Nucleation of cavities at second phase particles in grain boundaries

1978 ◽  
Vol 26 (6) ◽  
pp. 995-1006 ◽  
Author(s):  
Rishi Raj
2007 ◽  
Vol 551-552 ◽  
pp. 645-650
Author(s):  
Min Wang ◽  
Hong Zhen Guo ◽  
Y.J. Liu

According to the characteristic of appearing cavitation in the metals during superplastic deformation, the influence of strain rate on cavity evolvement, the influence of cavity on superplastic deformation capability, and the formation, development process of cavity were investigated for Al-Cu-Mg alloy (i.e. coarse–grained LY12). The results show that: ①The pore nucleation occurs not only at triangle grain boundaries, but also along nearby the second phase particles, and even within grains. The cavities at the triangle grain boundaries are present in V-shape, others near the second phase particles and within grains are present in O-shape. These cavities may result from disharmony slippage of grain boundaries. ②The tendency of cavity development decreases with increasing of strain-rate. In lower strain-rate condition, though Al-Cu-Mg alloy has better superplasticity, many big cavities in the specimen may reduce the room temperature properties of the alloy. In higher strain-rate condition, Al-Cu-Mg alloy has certain superplasticity and room temperature properties as well as few cavities forming. By analyzing, viscous layer on grain boundaries is very thin and grain sizes can be refined during their extruding and rotating each other in higher strain-rate superplastic deformation condition. ③Growth and coalescence of cavity are the main reason of the superplastic fracture of Al-Cu-Mg alloy. And small and a certain amount of cavities with dispersion and independence state are very useful to crystal boundary slippage.


2013 ◽  
Vol 753 ◽  
pp. 221-224 ◽  
Author(s):  
Krzysztof Sztwiertnia ◽  
Magdalena Bieda ◽  
Anna Korneva

In situ orientation mapping using TEM and calorimetric measurements were carried out to investigate the annealing behavior of cold-rolled 6013 aluminum alloy. The recrystallization of the material can be considered to be a number of processes that correspond to two separate stored energy release peaks. In the temperature range of the peak 1, the deformation zones around the large second-phase particles acted as sites for particle-stimulated nucleation. In the matrix, at the same time, some elongation of grains occurred. The elongated matrix grains appeared because of the reduction of the dislocation density and the annihilation of some low-angle grain boundaries between chains of subgrains lying in layers parallel to the sheet plane. The matrix processes in this temperatures range can be considered forms of continuous recrystallization. The matrix high-angle grain boundaries started to migrate at the temperature range of the peak 2. They moved mostly in the direction normal to the sheet plane. Heating of the sample for an appropriate time at those temperatures resulted in the complete discontinuous recrystallization of the material. The recrystallized microstructure was dominated now by elongated grains, which were a few times thicker than those obtained by annealing at the temperatures of the peak 1.


CORROSION ◽  
10.5006/2805 ◽  
2018 ◽  
Vol 74 (11) ◽  
pp. 1229-1236
Author(s):  
Feng Xiao ◽  
Jiangli An ◽  
Hui Chen ◽  
P. Li ◽  
Wei Gao

The corrosion fatigue short crack propagation (CFSCP) behavior of A7N01P-T4 Al alloy welded joints in 3.5 wt% NaCl solution has been investigated. The test results indicate that the CFSCP followed a cyclical type of growth. Microscopic study shows that almost all second-phase particles are distributed along the grain boundary areas. These particles were easily dissolved during the corrosion fatigue test, resulting in weak grain boundaries. Therefore, the fatigue short crack will grow along the winding grain boundaries. While the second-phase particles on the grain boundaries were the main factor to cause the intergranular crack. Transgranular cracking may occur to the coarse grains in the matrix, which indicate that grain size also has a strong influence on the CFSCP behavior of A7N01P-T4 Al alloy.


2007 ◽  
Vol 558-559 ◽  
pp. 1021-1028 ◽  
Author(s):  
Vladimir Yu. Novikov

Grain growth controlled by particles able to move together with grain boundaries is investigated by means of numerical simulation. The particles either located on grain boundaries or randomly distributed over the material volume are shown to retard the growth process. In the first case the growth kinetics is described by a power law Dn −D0 n = kt with the exponent n≤ 3. Growth kinetics under the influence of randomly distributed mobile particles can be approximated by the same law with the exponent n increasing with an increase in the particle volume fraction.


Author(s):  
K. J. Morrissey ◽  
Y. Kouh ◽  
C. B. Carter

The influence of additives such as MgO, NiO, and ZrO2 and impurities such as Na, K, and Ca on the sintering of alumina compacts has been the focus of a considerable amount of research. Since these additives affect compact density and grain size it is of interest to determine the behavior of the elements during processing. That is, it is important to know whether Ca and Mg segregate to grain boundaries or are located in the second-phase particles. Current results suggest that Ca is found uniformly at the grain boundaries and that Mg is accommodated in the second-phase particles.The present investigation is concerned with identifying second-phase particles in different commercially-produced Al2O3 compacts and studying both their structure and composition. Preliminary results have been discussed previously. The investigation has dealt mainly with two different alumina compacts. One compact was prepared from an initial powder containing 0.25% MgO, a small amount of intentionally added Ni, and was prepared by hot pressing.


2007 ◽  
Vol 550 ◽  
pp. 333-338 ◽  
Author(s):  
Sandra Piazolo ◽  
David J. Prior ◽  
M.D. Holness ◽  
Andreas O. Harstad

Annealing is an important mechanism of microstructural modification both in rocks and metals. In order to relate directly changes in crystallographic orientation to migrating boundaries the researcher has the option to investigate either samples where the grain boundary motion can be directly tracked or a series of samples exhibiting successively higher degrees of annealing. Here we present results from rock samples collected from two well characterised contact aureoles (a volume of rock heated by the intrusion of a melt in its vicinity): One quartz sample in which patterns revealed by Cathodoluminescence (CL) indicate the movement of grain boundaries and a series of calcite samples of known temperature history. Electron backscatter diffraction (EBSD) analysis is used to link the movement of grain, twin boundaries and substructures with the crystallographic orientation / misorientation of a respective boundary. Results from the quartz bearing rock show: (a) propagation of substructures and twin boundaries in swept areas both parallel and at an angle to the growth direction, (b) development of slightly different crystallographic orientations and new twin boundaries at both the growth interfaces and within the swept area, and (c) a gradual change in crystallographic orientation in the direction of growth. Observations are compatible with a growth mechanism where single atoms are attached and detached both at random and at preferential sites i.e. crystallographically controlled sites or kinks in boundary ledges. Strain fields caused by defects and/or trace element incorporation may facilitate nucleation sites for new crystallographic orientations at distinct growth interfaces but also at continuously migrating boundaries. Calcite samples show with increasing duration and temperature of annealing: (a) systematic decrease of the relative frequency of low angle grain boundaries (gbs), (b) decrease in lattice distortion within grains, (c) development of distinct subgrains with little internal lattice distortion, (d) change in lobateness of gbs and frequency of facet parallel gbs and (e) change in position of second phase particles. These observations point to an increasing influence of grain boundary anisotropy with increasing annealing temperature, while at the same time the influence of second phase particles and subtle driving-force variations decrease. This study illustrates the usefulness of using samples from natural laboratories and combining different analysis techniques in microprocess analysis.


2014 ◽  
Vol 793 ◽  
pp. 1-10
Author(s):  
B. Vargas-Arista ◽  
M.A. Gómez-Morales ◽  
E. Garfias-García ◽  
F. García-Vázquez

Two fractured pins of impact wrench were evaluated by fractography using scanning electron microscopy. This pneumatic wrench is used to the fabrication of automotive components being characterized by its power and tightening capacity. The important part of the wrench is the pin clutch impact mechanism used to generate high torque. An original pin manufactured with AISI E52100 steel adjusted 2,580 nuts before fracture and a substitute pin of E52100 modified steel with S adjusted 7,095 nuts before failure. Fractographic analysis in both fracture surfaces indicated a ductile-brittle mixed fracture mode. Original pin surface exhibited a granular appearance while substitute pin surface showed fibrous and rough morphology. Precipitation of nearly rounded, elliptical and elongate second – phase particles containing Cr, C and Mn measured as intergranular and transgranular particle density was observed, promoting some brittle failure zones and ductile fracture measured as the volume fraction of grain boundaries and microvoids, respectively. A larger amount of intergranular medium precipitates was found on the original pin which favored the brittle failure among the grain boundaries compared to that of the substitute pin. The ductile fracture by larger transgranular fine particle density which acted as nucleation sites of higher volume fraction of microvoids was found in the substitute pin.


2005 ◽  
Vol 475-479 ◽  
pp. 521-524 ◽  
Author(s):  
Dae H. Kang ◽  
Min S. Yoo ◽  
Sung S. Park ◽  
Nack J. Kim

A study has been made on the tensile and creep properties of squeeze and die cast Mg alloys, with emphasis on the effect of second phase particles. Two different microstructures were compared; the microstructure with thermally unstable particles along grain boundaries (AZ91 alloy) and the microstructure with thermally stable particles along grain boundaries as well as within matrix (MX alloy). The experimental MX alloy has equivalent room temperature tensile strength to AZ91 alloy with higher ductility. Moreover, elevated temperature tensile properties and creep resistance of MX alloy are higher than those of AZ91 alloy. Such improved properties of MX alloy over those of AZ91 alloy are due to the optimized microstructure of the former.


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