Hydration products of calcium aluminoferrite

1983 ◽  
Vol 13 (5) ◽  
pp. 696-702 ◽  
Author(s):  
J.M. Fortune ◽  
J.M.D. Coey
Keyword(s):  
Hydration Products ◽  
Calcium Aluminoferrite

scholarly journals Component Modification of Basic Oxygen Furnace Slag with C4AF as Target Mineral and Application

2021 ◽  
Vol 13 (12) ◽  
pp. 6536
Author(s):  
Yanrong Zhao ◽  
Pengliang Sun ◽  
Ping Chen ◽  
Xiaomin Guan ◽  
Yuanhao Wang ◽  
...  
Keyword(s):  
Intermediate Phase ◽  
Raw Materials ◽  
Activity Index ◽  
Basic Oxygen Furnace ◽  
Hydration Products ◽  
Basic Oxygen ◽  
Bof Slag ◽  
Mineral Compositions ◽  
Slag Component ◽  
Basic Oxygen Furnace Slag

In this paper, a new method of basic oxygen furnace (BOF) slag component modification with a regulator was studied. The main mineral was designed as C4AF, C2S and C3S in modified BOF slag, and the batching method, mineral compositions, hydration rate, activation index and capability of resisting sulfate corrode also were studied. XRD, BEI and EDS were used to characterize the mineral formation, and SEM was used to study the morphology of hydration products. The results show that most inert phase in BOF slag can be converted into active minerals of C4AF and C2S through reasonable batching calculation and the amount of regulating agent. The formation of C4AF and C2S in modified BOF slag is better, and a small amount of MgO is embedded in the white intermediate phase, but C3S is not detected. With the increase in the CaO/SiO2 ratio in raw materials, the CaO/SiO2 ratio of calcium silicate minerals in modified BOF slag increases, the contents of f-CaO are less than 1.0%, and the activity index improves. Compared with the BOF slag, the activity index and exothermic rate of modified BOF slag improved obviously, and the activity index of 90 days is close to 100%. With the increase in modified BOF slag B cement, the flexural strength decrease; however, the capability of resisting sulfate corrode is improved due to the constant formation of a short rod-like shape ettringite in Na2SO4 solution and the improvement of the structure densification of the hydration products.

scholarly journals Effect of C-S-H Nucleating Agent on Cement Hydration

2021 ◽  
Vol 11 (14) ◽  
pp. 6638
Author(s):  
Wenhao Zhao ◽  
Xuping Ji ◽  
Yaqing Jiang ◽  
Tinghong Pan
Keyword(s):  
Fractal Dimension ◽  
Cement Hydration ◽  
Nucleating Agent ◽  
Crystal Nucleation ◽  
Enhancement Effect ◽  
Hydration Products ◽  
Hydration Degree ◽  
Hydration Kinetics ◽  
Cement Mortars ◽  
Early Strength

This work aims to study the effect of a nucleating agent on cement hydration. Firstly, the C-S-H crystal nucleation early strength agent (CNA) is prepared. Then, the effects of CNA on cement hydration mechanism, early strength enhancement effect, C-S-H content, 28-days hydration degree and 28-days fractal dimension of hydration products are studied by hydration kinetics calculation, resistivity test, BET specific surface area test and quantitative analysis of backscattered electron (BSE) images, respectively. The results show that CNA significantly improves the hydration degree of cement mixture, which is better than triethanolamine (TEA). CNA shortens the beginning time of the induction period by 49.3 min and the end time of the cement hydration acceleration period by 105.1 min than the blank sample. CNA increases the fractal dimension of hydration products, while TEA decreases the fractal dimension. CNA significantly improves the early strength of cement mortars; the 1-day and 3-days strength of cement mortars with CNA are more than the 3-days and 7-days strength of the blank sample. These results will provide a reference for the practical application of the C-S-H nucleating agent.

scholarly journals Regulating Effect of Cement Accelerator on High Content Solid-Wastes Autoclaved Aerated Concrete (HCS-AAC) Slurry Performance and Subsequent Influence

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 799
Author(s):  
Dingkun Xie ◽  
Lixiong Cai ◽  
Jie Wang
Keyword(s):  
Mechanical Properties ◽  
Mechanical Property ◽  
Solid Wastes ◽  
Hydration Products ◽  
Promoting Effect ◽  
Adverse Side Effects ◽  
Foaming Process ◽  
Carbide Slag ◽  
Negative Effect ◽  
Aerated Concrete

Adverse side-effects occurred in slurry foaming and thickening process when carbide slag was substituted for quicklime in HCS-AAC. Cement accelerators were introduced to modify the slurry foaming and coagulating process during pre-curing. Meanwhile, the affiliated effects on the physical-mechanical properties and hydration products were discussed to evaluate the applicability and influence of the cement accelerator. The hydration products were characterized by mineralogical (XRD) and thermal analysis (DSC-TG). The results indicated that substituting carbide slag for quicklime retarded slurry foaming and curing progress; meanwhile, the induced mechanical property declination had a negative effect on the generation of C–S–H (I) and tobermorite. Na2SO4 and Na2O·2.0SiO2 can effectively accelerate the slurry foaming rate, but the promoting effect on slurry thickening was inconspicuous. The compressive strength of HCS-AAC obviously declined with increasing cement coagulant content, which was mainly ascribed to the decrease in bulk density caused by the accelerating effect on the slurry foaming process. Dosing Na2SO4 under 0.4% has little effect on the generation of strength contributing to hydration products while the addition of Na2O·2.0SiO2 can accelerate the generation and crystallization of C–S–H, which contributed to the high activity gelatinous SiO2 generated from the reaction between Na2O·2.0SiO2 and Ca(OH)2.

scholarly journals Action Time-Effect and Mechanism of Low-Calcium Fly Ash in Cement-Based Composites

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 681
Author(s):  
Na Yan ◽  
Qingqing Tang ◽  
Ying Zhang ◽  
Guowen Sun
Keyword(s):  
Fly Ash ◽  
Nitrogen Adsorption ◽  
Chemical Effect ◽  
Hydration Products ◽  
X Ray Diffraction ◽  
Degree Of Hydration ◽  
Surface Areas ◽  
Activity Effect ◽  
Low Calcium ◽  
Pore Size Distributions

This study was conducted in order to investigate when low-calcium fly ash plays a physical or chemical effect and what is the chemical effect proportion of low-calcium fly ash. Two types of low-calcium fly ash and quartz powder, with similar fineness as active and inert admixtures, were used as materials in this study. Under different water/binder ratios and hydration ages, the effects of the different types of admixtures and their dosages on the flexural and compressive strength of the composites were studied. X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption methods, in addition to an assessment of the degree of hydration of the fly ash, were employed to observe the hydration products at different ages, the microstructures of the hydration products, as well as their surface areas and pore size distributions. The results show that during the hydration period of 28 days, the low-calcium fly ash has a micro-aggregate filling physical effect. However, after 56 days, the hydration degree of fly ash begins to exceed 1%. This illustrates that the low-calcium fly ash has both the pozzolanic activity effect and micro-aggregate filling effect. In contrast, the low-calcium fly ash hydrated for 90 days is still dominated by the physical filling effect.

scholarly journals Enhancing carbonation and chloride resistance of autoclaved concrete by incorporating nano-CaCO3

2020 ◽  
Vol 9 (1) ◽  
pp. 998-1008
Author(s):  
Guo Li ◽  
Zheng Zhuang ◽  
Yajun Lv ◽  
Kejin Wang ◽  
David Hui
Keyword(s):  
Cement Hydration ◽  
Mercury Intrusion Porosimetry ◽  
Hardened Concrete ◽  
Optimal Dosage ◽  
Hydration Products ◽  
X Ray Diffraction ◽  
Carbonation Depth ◽  
X Ray ◽  
Chloride Resistance

AbstractThree nano-CaCO3 (NC) replacement levels of 1, 2, and 3% (by weight of cement) were utilized in autoclaved concrete. The accelerated carbonation depth and Coulomb electric fluxes of the hardened concrete were tested periodically at the ages of 28, 90, 180, and 300 days. In addition, X-ray diffraction, thermogravimetry, and mercury intrusion porosimetry were also performed to study changes in the hydration products of cement and microscopic pore structure of concrete under autoclave curing. Results indicated that a suitable level of NC replacement exerts filling and accelerating effects, promotes the generation of cement hydration products, reduces porosity, and refines the micropores of autoclaved concrete. These effects substantially enhanced the carbonation and chloride resistance of the autoclaved concrete and endowed the material with resistances approaching or exceeding that of standard cured concrete. Among the three NC replacement ratios, the 3% NC replacement was the optimal dosage for improving the long-term carbonation and chloride resistance of concrete.

scholarly journals Performance and Microstructure of Cold Recycled Mixes Using Asphalt Emulsion with Different Contents of Cement

Materials ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 2548 ◽  
Author(s):  
Yanhai Yang ◽  
Ye Yang ◽  
Baitong Qian
Keyword(s):  
Low Temperature ◽  
Temperature Stability ◽  
Hydration Products ◽  
High Temperature Stability ◽  
Asphalt Emulsion ◽  
Moisture Susceptibility ◽  
Pavement Maintenance ◽  
Maintenance And Rehabilitation ◽  
Low Temperature Cracking ◽  
Temperature Crack

Cold recycled mixes using asphalt emulsion (CRME) is an economical and environmentally-friendly technology for asphalt pavement maintenance and rehabilitation. In order to determine the optimum range of cement contents, the complex interaction between cement and asphalt emulsion and the effects of cement on performance of CRME were investigated with different contents of cement. The microstructure and chemical composition of the fracture surface of CRME with different contents of cement were analyzed in this paper as well. Results show that the high-temperature stability and moisture susceptibility of CRME increased with the contents of cement increasing. The low-temperature crack resistance ability gradually increased when the content of cement is increased from 0% to 1.5%. However, it gradually decreased when the content of cement is increased from 1.5% to 4%. Cold recycled mixes had better low-temperature cracking resistance when the contents of cement were in the range from 1% to 2%. The results of microstructure and energy spectrum analysis show that the composite structure is formed by hydration products and asphalt emulsion. The study will be significant to better know the effects of cement and promote the development of CRME.

scholarly journals Using of Microsilica for Strength Improvement of Fiber Reinforced Cementitious Surface Compounds

2013 ◽  
Vol 2013 ◽  
pp. 1-7
Author(s):  
S. S. Shebl ◽  
Ibrahim S. Khalil ◽  
H. Shoukry
Keyword(s):  
Date Palm ◽  
Fine Sand ◽  
Structural Performance ◽  
Polypropylene Fibers ◽  
Hydration Products ◽  
Fiber Reinforced ◽  
Surface Compounds ◽  
Extension Work ◽  
Strength Improvement

This study represents an extension work to investigate the role of ultra fine sand (UFS) in enhancing the mechanical properties of fiber reinforced cementitious compounds. The micro-structural origins were identified by scanning electron microscope (SEM). About 50% of UFS had a diameter of less than 20 μm. Ordinary Portland Cement (OPC) was partially substituted by UFS at 3, 5, 7 and 10% by weight of binder. It was found that as UFS loadings increase, the flexural, compressive, and tensile strengths increased up to about 5% UFS loading by 12.9, 15.7 and 30.1%, respectively, thereafter, a decrease in these properties was observed. This can be attributed to the pozzolanic effect besides the filling effect of UFS resulting in enhancing the interfacial bonds between the sand grains and hydration products that makes the paste more homogeneous and dense. The effect of both short natural and artificial fiber loadings on the structural performance of compounds was also studied. Loadings of 2%, by weight, of short natural date palm leaves’ midribs fibers (DP) and artificial polypropylene fibers (PP) were added to the 5% UFS blended mix. An increase in both flexural and tensile strength was achieved, while a decrease in the compressive strength was observed.

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