Study of fluid circulation through the chicxulub crater using Rock-Eval pyrolysis and fluid inclusions

2022 ◽  
pp. 105194
Author(s):  
L. Hernandez-Terrones ◽  
L. Martínez ◽  
J. Szamotulski ◽  
E. González-Partida ◽  
J.V. Morgan ◽  
...  
Keyword(s):  
Fluid Inclusions ◽  
Fluid Circulation ◽  
Chicxulub Crater ◽  
Rock Eval

Past hot fluid flows in limestones detected by Δ47–(U-Pb) and not recorded by other geothermometers

Geology ◽  
2020 ◽  
Vol 48 (9) ◽  
pp. 851-856 ◽  
Author(s):  
Benjamin Brigaud ◽  
Magali Bonifacie ◽  
Maurice Pagel ◽  
Thomas Blaise ◽  
Damien Calmels ◽  
...  
Keyword(s):  
Fluid Inclusions ◽  
Thermal History ◽  
Vitrinite Reflectance ◽  
Fluid Flows ◽  
Aqueous Fluid ◽  
Rift System ◽  
History Of ◽  
Clumped Isotope ◽  
Two Stages ◽  
Rock Eval

Abstract Geothermometers are commonly used to reconstruct the diagenetic and thermal history of rocks. However, characterizing the timing, origin, and temperature of paleofluid flow remains challenging because it must be assessed indirectly through the analysis of microscopic cements that precipitate and fill intergranular spaces during fluid circulation. Here, we measure both the clumped isotope (Δ47) temperature and in situ U-Pb age of individual diagenetic calcite cements within a sedimentary section of the Paris Basin (France), whose thermal history has been previously inferred to be <60 °C. We show that cementation occurred during two stages associated with major events at the western European lithospheric scale: (1) the Bay of Biscay rifting (Late Jurassic–Early Cretaceous), and (2) north-south Pyrenean compression (Eocene) followed by east-west extension during the European Cenozoic rift system event (Oligocene). Related to both events, we report unexpectedly hot fluids, up to 110 °C, contrasting with the lower temperatures inferred from other geothermometers (e.g., fluid inclusions, clay minerals, apatite fission tracks, maturity of organic matter by Rock-Eval pyrolysis, or vitrinite reflectance). These high temperatures (>70 °C) have been measured for calcite cements containing single-phase aqueous fluid inclusions, challenging the commonly accepted assertion that the absence of nucleation of a vapor phase indicates crystallization at low temperature (∼<70 °C). We suggest that the kinetics of mineralization events prevented the recording of short-lived hot fluid flows by other geothermometers.

Chronology and orientation of N2–CH4, CO2-H2O, and H2O-rich fluid-inclusion trails in intrametamorphic quartz veins from the Cuiabá gold district, Brazil

1990 ◽  
Vol 54 (375) ◽  
pp. 245-255 ◽  
Author(s):  
C. J. S. de Alvarenga ◽  
M. Cathelineau ◽  
J. Dubessy
Keyword(s):  
Fluid Inclusion ◽  
Fluid Inclusions ◽  
Low Grade ◽  
Fluid Circulation ◽  
Raman Spectrometry ◽  
Mato Grosso ◽  
Spectrometry Analysis ◽  
Quartz Veins ◽  
Three Generations ◽  
Inclusion Trails

AbstractThe upper Proterozoic Cuiabá group of Mato Grosso, Brazil, is composed of low-grade clastic meta-sediments which have been folded by several successive tectonic events. Three generations of quartz veins are associated with the structural evolution of this area. The first veins are deformed by the main tectonic phases and show a complex deformational patterns. The second set is parallel to the cleavage and was formed syntectonically during the main folding phase, whilst the last quartz veins are related to a later stage of deformation. A systematic study of fluid inclusions in relation with a statistical study of microstructural markers (fluid inclusion trails, opened microcracks) was carried out on quartz veins from three localities. On the basis of microthermometric studies and Raman spectrometry analysis, four differents types of fluids have been distinguished, each trapped in specific fluid inclusion trails: (i) CO2-rich liquids and vapours (Lc, Vc) at Casa de Pedra, (ii) Lc and Vc inclusions with variable amounts of CO2, CH4, N2 in the vapour phase at BR-70, (iii) CH2-N2-rich vapours (Vn-m), and (iv) aqueous inclusions (L) with variable salinities representing the last fluid generations at all localities.At Casa de Pedra and BR-70, most fluids are observed within the three generations of quartz veins, indicating an important fluid circulation associated with the last phase of brittle deformation. Fluid inclusions of type (iii) and (iv) are oriented along several well defined directions. The study shows the importance of integrated microstructural and fluid-inclusion studies for understanding the geometry and chronology of fluid circulation.

Fluid Inclusions from Anhydrite Related to the Chicxulub Crater Impact Breccias, Yucatan, Mexico: Preliminary Report

2000 ◽  
Vol 42 (3) ◽  
pp. 279-288 ◽  
Author(s):  
Eduardo Gonzalez-Partida ◽  
Alejandro Carillo-Chavez ◽  
Ricardo Martinez-Ibarra
Keyword(s):  
Fluid Inclusions ◽  
Preliminary Report ◽  
Chicxulub Crater

scholarly journals Fluid Inclusions and Rare Earth Elements (REE) analysis in calcite veins: Tectonic - diagenesis interaction in the Rosablanca formation, Mesa de los Santos sector, eastern cordillera, Colombia

2018 ◽  
Vol 8 (1) ◽  
pp. 31-43 ◽  
Author(s):  
Jairo Conde-Gómez
Keyword(s):  
Rare Earth ◽  
Fluid Inclusion ◽  
Fluid Inclusions ◽  
Early Event ◽  
Fluid Circulation ◽  
Carbonate Cement ◽  
Diagenetic Processes ◽  
Calcite Veins ◽  
Different Types ◽  
Immiscible Mixture

Studies conducted by means of petrography, cathodoluminescence, SEM, fluid inclusion and REE geochemistry in core samples from the Rosablanca Formation in the Mesa de Los  Santos sector, identified two types of material: the host rock classified as Packstones and Grainstones, and veins that texturally expose three types of filling (blocky texture, blocky elongate texture, fibrous texture). Diagenesis is characterized by dissolution, carbonate cement precipitation, compaction, fracturing and fluid circulation through fractures during at least three episodes; these diagenetic processes were contemporaneous with the distensive and compressive tectonic regimes regionally dominant during the Cretaceous, Paleogene and Neogene in the study area. The fluids that generated the different types of texture inside the veins were brines that belonged to the H2O – NaCl – CaCl2 system, with salinities between 0.03 – 12.96 % wt eq NaCl, derived from the Rosablanca Formation that was deposited under oxic conditions, retaining their marine character and implying an autochthonousorigin for the REE present in the veins. The conditions of entrapment for fluid inclusions during the early event were heterogeneous, arising from an immiscible mixture of brines andhydrocarbons, while in the second, they were homogeneous with later post-entrapment processes.later post-entrapment processes.

Determination of Chlorinity in Aqueous Fluids Using Raman Spectroscopy of the Stretching Band of Water at Room Temperature: Application to Fluid Inclusions

2002 ◽  
Vol 56 (1) ◽  
pp. 99-106 ◽  
Author(s):  
Jean Dubessy ◽  
Thérèse Lhomme ◽  
Marie-Christine Boiron ◽  
Fernando Rull
Keyword(s):  
Raman Spectroscopy ◽  
Fluid Inclusions ◽  
Pure Water ◽  
Chloride Concentration ◽  
Fluid Circulation ◽  
Synthetic Fluid Inclusions ◽  
Stretching Vibration ◽  
Temperature Application ◽  
Spectrometer Slit

A new analytical method, based on the Raman spectroscopy of the ν(OH) stretching vibration of water, has been developed for the determination of the concentration of chloride in aqueous solutions with the goal of reconstructing the bulk ion content of fluid inclusions that are relics of paleo-fluid circulation in rocks. The method involves calibrating the area of one band of the spectrum difference between pure water and solutions of appropriate composition with respect to the chloride concentration. Calibration curves were constructed for the major geological chemical salts LiCl, NaCl, KCl, CaCl2, and MgCl2, and NaCl–CaCl2 systems. The application to fluid inclusions has been confirmed using synthetic fluid inclusions. For cubic minerals such as fluorite, the calibration curve for the NaCl system correctly estimates the chlorinity. For birefringent minerals, such as quartz, the Raman spectrum of the aqueous solution depends on the orientation of the host crystal. The crystal must be oriented in such a way that one axis of the ellipse of the indicatrix projects parallel to the spectrometer slit. This method complements micro-thermometric data and allows the determination of chlorinity when ice-melting temperature cannot be used.

scholarly journals Hydrothermal fluid circulations in the western Pyrenees: new data on stable isotopes, in-situ gas analysis and fluid inclusions

2019 ◽  
Vol 98 ◽  
pp. 01001
Author(s):  
Guillaume Barré ◽  
Alexy Elias-Bahnan ◽  
Geoffrey Motte ◽  
Maxime Ducoux ◽  
Guilhem Hoareau ◽  
...  
Keyword(s):  
Fluid Inclusions ◽  
Gas Analysis ◽  
Fluid Circulation ◽  
Mantle Zone ◽  
Thermal Peak ◽  
The North ◽  
Tectonic History ◽  
Peak Event ◽  
Aquitaine Basin

Several fluid circulation events are recorded in the Aquitaine Basin and the Chaînons Béarnais in the Pyrenean belt of southwestern France. Different fluid types are found in all locations studied. The main difference comes from the thermal peak event (rifting), which was more intense in the Chaînons Béarnais close to the exhumed mantle zone. In situ gas analysis associated of fluid inclusions and isotopic (C, O, H, S) analyses show that similar fluids are generated in both systems, although separated by deep structures, e.g. the North Pyrenean Frontal Thrust (NPFT). The Pyrenean tectonic history leads to the compartmentalization of fluid circulations.

scholarly journals Fluid evolution from quartz veins in micaschists from the thermal aureole around the Acari batholith, Northeast Brazil

2021 ◽  
Vol 21 (4) ◽  
pp. 13-30
Author(s):  
Laécio Cunha de Souza ◽  
Regina Celia de Oliveira Brasil Delgado ◽  
Heitor Neves Maia
Keyword(s):  
Fluid Inclusions ◽  
Aqueous Fluid ◽  
Fluid Circulation ◽  
Two Phase ◽  
Quartz Veins ◽  
Melting Temperatures ◽  
Three Phase ◽  
Higher Temperature ◽  
Homogenization Temperatures ◽  
Liquid Vapor

Micaschists that host the Acari batholith (Ediacaran age, 572 to 577 My) are characterized by a large number of quartz veins. The veins are more abundant in higher-temperature metamorphic zones and, together with lower metamorphic zones, form an aureole centered in the batholith. Most of the fluid inclusions are two-phase (H2O-CO2 and liquid/vapor), but three-phase varieties (liquid/vapor/salt cubes; liquid/liquid/vapor) occur locally. The analyzed veins come from the biotite + chlorite + muscovite, biotite + garnet, cordierite + andalusite, and cordierite + sillimanite metamorphic zones. CO2 melting temperatures (TmCO2) vary from -62.6 to -56.7°C, suggesting CH4 and/or N2. Eutectic temperatures (Te) in quartz veins show average values of -30.8°C in the biotite + chlorite + muscovite and biotite + garnet zones, and -38.6°C in the cordierite + andalusite and cordierite + sillimanite zones. Ice-melting temperatures (Tmice) are lower in the higher-temperature metamorphic zones. The mode values are -3.8, -5.5, -5.6, and -7.3°C, corresponding respectively to the biotite + chlorite + muscovite, biotite + garnet, cordierite + andalusite, and cordierite + sillimanite zones. A fluid characterized by the H2O-Na-Cl (KCl)-MgCl2-FeCl2-CaCl2 system is defined by: Tmice from near -1.9 to -32°C, the presence of salt cubes mainly in the cordierite + andalusite and cordierite + sillimanite zones, and recorded eutectic temperatures (Te) from -16.5 to -59.1°C. In addition, total homogenization temperatures (Tht) ranging from 117 to 388°C were obtained for primary aqueous fluid inclusions. This indicates a long period of fluid circulation under conditions of falling temperatures. Our results are consistent with an increase in the salinity of the aqueous fluid across the thermal aureole toward the granitic batholith.

Characterization of submicrometer fluid Inclusions in minerals by Analytical/Transmission Electron Microscopy and electron diffraction

1990 ◽  
Vol 48 (4) ◽  
pp. 424-424
Author(s):  
George Guthrie ◽  
David Veblen
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Electron Microscope ◽  
Electron Diffraction ◽  
Light Microscopy ◽  
Fluid Inclusions ◽  
Energy Dispersive Spectrometer ◽  
Analytical Transmission Electron Microscopy ◽  
Transmission Electron

The nature of a geologic fluid can often be inferred from fluid-filled cavities (generally <100 μm in size) that are trapped during the growth of a mineral. A variety of techniques enables the fluids and daughter crystals (any solid precipitated from the trapped fluid) to be identified from cavities greater than a few micrometers. Many minerals, however, contain fluid inclusions smaller than a micrometer. Though inclusions this small are difficult or impossible to study by conventional techniques, they are ideally suited for study by analytical/ transmission electron microscopy (A/TEM) and electron diffraction. We have used this technique to study fluid inclusions and daughter crystals in diamond and feldspar.Inclusion-rich samples of diamond and feldspar were ion-thinned to electron transparency and examined with a Philips 420T electron microscope (120 keV) equipped with an EDAX beryllium-windowed energy dispersive spectrometer. Thin edges of the sample were perforated in areas that appeared in light microscopy to be populated densely with inclusions. In a few cases, the perforations were bound polygonal sides to which crystals (structurally and compositionally different from the host mineral) were attached (Figure 1).

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