Cleavage of functionalized organic group and role of active sites for very low concentration of gaseous wet methyl iodide in the presence of Ag nanoparticles in organofunctional silica-gel network

Molybdenum oxide catalyst doped or mixed with (1 - 50) mole % Fe3+ ions were prepared. The structure of the original samples and the samples calcined at 400 °C were characterized using DTA, X-ray diffraction and IR spectra. Measurements of the electrical conductivity of calcined samples with and without isopropyl alcohol revealed that the conductance increases on increasing the content of Fe3+ ions up to 50 mole %. The activation energies of charge carriers were determined in presence and absence of the alcohol. The catalytic dehydration of isopropyl alcohol was carried out at 250 °C using a flow system. The results obtained showed that the doped or mixed catalysts are active and selective towards propene formation. However, the catalyst containing 40 mole % Fe3+ ions exhibited the highest activity and selectivity. Correlations were attempted to the catalyst composition with their electronic and catalytic properties. Probable mechanism for the dehydration process is proposed in terms of surface active sites.

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Geometric Factor in Skeletal Reactions of 2-Methylpentane on Stepped Surfaces of Platinum Catalyst

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19922012 ◽

1992 ◽

Vol 57 (10) ◽

pp. 2012-2020

Author(s):

Vladimír Hejtmánek

Keyword(s):

Active Sites ◽

Platinum Catalyst ◽

Point Of View ◽

Geometric Factor ◽

Published Data ◽

Stepped Surfaces ◽

Geometric Conditions ◽

Surface Intermediates ◽

Isomerization Mechanism

The role of geometric factor in the course of skeletal reactions (isomerization, hydrogenolysis) of 2-methylpentane on stepped (119), (557) and reconstructed R(557) surfaces of single crystals of platinum was evaluated with computer designed models. These calculations were compared with reported experimental data. It was found by analysis of geometric conditions that there are accessible active ensembles on double step of the reconstructed R(557) surface. In addition, these active sites are unsaturated in their coordination sphere and thus catalytically effective. This finding is consistent with published data, confirming higher catalytic activity of this surface. The various pathways of Bond Shift isomerization mechanism of 2-methylpentane from the point of view of steric demands of surface intermediates on differently located ensembles are discussed, too.

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Controlled synthesis of functional Ag, Ag–Au/Au–Ag nanoparticles and their Prussian blue nanocomposites for bioanalytical applications

RSC Advances ◽

10.1039/c5ra06251a ◽

2015 ◽

Vol 5 (61) ◽

pp. 49671-49679 ◽

Cited By ~ 17

Author(s):

Prem. C. Pandey ◽

Richa Singh ◽

Yashashwa Pandey

Keyword(s):

Prussian Blue ◽

Ag Nanoparticles ◽

Active Role ◽

Reducing Agents ◽

Controlled Synthesis ◽

Bioanalytical Applications

A facile method for the synthesis of functional AgNPs and bimetallic Ag–Au/Au–Ag are reported, enabling the formation of nanocomposite with prussian blue in a crystalline framework for bioanalytical applications, showing the active role of organic reducing agents and 3-aminopropyltrimethoxysilane.

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The RelA hydrolase domain acts as a molecular switch for (p)ppGpp synthesis

Communications Biology ◽

10.1038/s42003-021-01963-z ◽

2021 ◽

Vol 4 (1) ◽

Author(s):

Anurag Kumar Sinha ◽

Kristoffer Skovbo Winther

Keyword(s):

Active Sites ◽

Molecular Switch ◽

Cell Physiology ◽

Synthetase Activity ◽

Wild Type ◽

Functional Studies ◽

Loop Region ◽

A Site ◽

Trna Binding

AbstractBacteria synthesize guanosine tetra- and penta phosphate (commonly referred to as (p)ppGpp) in response to environmental stresses. (p)ppGpp reprograms cell physiology and is essential for stress survival, virulence and antibiotic tolerance. Proteins of the RSH superfamily (RelA/SpoT Homologues) are ubiquitously distributed and hydrolyze or synthesize (p)ppGpp. Structural studies have suggested that the shift between hydrolysis and synthesis is governed by conformational antagonism between the two active sites in RSHs. RelA proteins of γ-proteobacteria exclusively synthesize (p)ppGpp and encode an inactive pseudo-hydrolase domain. Escherichia coli RelA synthesizes (p)ppGpp in response to amino acid starvation with cognate uncharged tRNA at the ribosomal A-site, however, mechanistic details to the regulation of the enzymatic activity remain elusive. Here, we show a role of the enzymatically inactive hydrolase domain in modulating the activity of the synthetase domain of RelA. Using mutagenesis screening and functional studies, we identify a loop region (residues 114–130) in the hydrolase domain, which controls the synthetase activity. We show that a synthetase-inactive loop mutant of RelA is not affected for tRNA binding, but binds the ribosome less efficiently than wild type RelA. Our data support the model that the hydrolase domain acts as a molecular switch to regulate the synthetase activity.

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Green Nanocoatings Based on the Deposition of Zirconium Oxide: The Role of the Substrate

Materials ◽

10.3390/ma14041043 ◽

2021 ◽

Vol 14 (4) ◽

pp. 1043

Author(s):

Vitor Bonamigo Moreira ◽

Anna Puiggalí-Jou ◽

Emilio Jiménez-Piqué ◽

Carlos Alemán ◽

Alvaro Meneguzzi ◽

...

Keyword(s):

Zirconium Oxide ◽

Active Sites ◽

Modified Electrodes ◽

Chemical Conversion ◽

Ceramic Materials ◽

Point Of View ◽

Oxide Coatings ◽

Alloying Element ◽

Substrate Nature

Herein, the influence of the substrate in the formation of zirconium oxide monolayer, from an aqueous hexafluorozirconic acid solution, by chemical conversion and by electro-assisted deposition, has been approached. The nanoscale dimensions of the ZrO2 film is affected by the substrate nature and roughness. This study evidenced that the mechanism of Zr-EAD is dependent on the potential applied and on the substrate composition, whereas conversion coating is uniquely dependent on the adsorption reaction time. The zirconium oxide based nanofilms were more homogenous in AA2024 substrates if compared to pure Al grade (AA1100). It was justified by the high content of Cu alloying element present in the grain boundaries of the latter. Such intermetallic active sites favor the obtaining of ZrO2 films, as demonstrated by XPS and AFM results. From a mechanistic point of view, the electrochemical reactions take place simultaneously with the conventional chemical conversion process driven by ions diffusion. Such findings will bring new perspectives for the generation of controlled oxide coatings in modified electrodes used, as for example, in the construction of battery cells; in automotive and in aerospace industries, to replace micrometric layers of zinc phosphate by light-weight zirconium oxide nanometric ones. This study is particularly addressed for the reduction of industrial waste by applying green bath solutions without the need of auxiliary compounds and using lightweight ceramic materials.

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On the Role of Protonic Acid Sites in Cu Loaded FAU31 Zeolite as a Catalyst for the Catalytic Transformation of Furfural to Furan

Molecules ◽

10.3390/molecules26072015 ◽

2021 ◽

Vol 26 (7) ◽

pp. 2015

Author(s):

Łukasz Kuterasiński ◽

Małgorzata Smoliło-Utrata ◽

Joanna Kaim ◽

Wojciech Rojek ◽

Jerzy Podobiński ◽

...

Keyword(s):

Active Sites ◽

Acid Sites ◽

Bronsted Acid ◽

Brønsted Acid ◽

Brønsted Acid Sites ◽

Protonic Acid ◽

Brönsted Acid ◽

Brönsted Acid Sites ◽

Bronsted Acid Sites

The aim of the present paper is to study the speciation and the role of different active site types (copper species and Brønsted acid sites) in the direct synthesis of furan from furfural catalyzed by copper-exchanged FAU31 zeolite. Four series of samples were prepared by using different conditions of post-synthesis treatment, which exhibit none, one or two types of active sites. The catalysts were characterized by XRD, low-temperature sorption of nitrogen, SEM, H2-TPR, NMR and by means of IR spectroscopy with ammonia and CO sorption as probe molecules to assess the types of active sites. All catalyst underwent catalytic tests. The performed experiments allowed to propose the relation between the kind of active centers (Cu or Brønsted acid sites) and the type of detected products (2-metylfuran and furan) obtained in the studied reaction. It was found that the production of 2-methylfuran (in trace amounts) is determined by the presence of the redox-type centers, while the protonic acid sites are mainly responsible for the furan production and catalytic activity in the whole temperature range. All studied catalysts revealed very high susceptibility to coking due to polymerization of furfural.

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Astral hydrogels mimic tissue mechanics by aster-aster interpenetration

Nature Communications ◽

10.1038/s41467-021-24663-y ◽

2021 ◽

Vol 12 (1) ◽

Author(s):

Qingqiao Xie ◽

Yuandi Zhuang ◽

Gaojun Ye ◽

Tiankuo Wang ◽

Yi Cao ◽

...

Keyword(s):

Common Core ◽

Self Assembly ◽

Master Curve ◽

Soft Tissues ◽

Tissue Mechanics ◽

Fresh Perspective ◽

Single Master Curve ◽

Unique Mechanism ◽

Gel Network

AbstractMany soft tissues are compression-stiffening and extension-softening in response to axial strains, but common hydrogels are either inert (for ideal chains) or tissue-opposite (for semiflexible polymers). Herein, we report a class of astral hydrogels that are structurally distinct from tissues but mechanically tissue-like. Specifically, hierarchical self-assembly of amphiphilic gemini molecules produces radial asters with a common core and divergently growing, semiflexible ribbons; adjacent asters moderately interpenetrate each other via interlacement of their peripheral ribbons to form a gel network. Resembling tissues, the astral gels stiffen in compression and soften in extension with all the experimental data across different gel compositions collapsing onto a single master curve. We put forward a minimal model to reproduce the master curve quantitatively, underlying the determinant role of aster-aster interpenetration. Compression significantly expands the interpenetration region, during which the number of effective crosslinks is increased and the network strengthened, while extension does the opposite. Looking forward, we expect this unique mechanism of interpenetration to provide a fresh perspective for designing and constructing mechanically tissue-like materials.

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