Impact of Co-Hydrothermal carbonization of animal and agricultural waste on hydrochars’ soil amendment and solid fuel properties

2022 ◽  
Vol 157 ◽  
pp. 106329
Author(s):  
Dylan Mariuzza ◽  
Jui-Chun Lin ◽  
Maurizio Volpe ◽  
Luca Fiori ◽  
Selim Ceylan ◽  
...  
Keyword(s):  
Solid Fuel ◽  
Soil Amendment ◽  
Agricultural Waste ◽  
Hydrothermal Carbonization ◽  
Fuel Properties

scholarly journals ON THE REPLACEMENT OF FOSSIL COAL IN LOCAL SOLID FUEL BOILERS

2019 ◽  
pp. 7-16
Author(s):  
V.Ya. Braverman
Keyword(s):  
Solid Fuel ◽  
Agricultural Waste ◽  
Thermochemical Treatment ◽  
Calorific Value ◽  
Hydrothermal Carbonization ◽  
Environmental Safety ◽  
Safety Standards ◽  
Fossil Coal ◽  
Best Available Technology ◽  
Available Technology

The paper substantiates the need to replace fossil coal in local solid fuel boilers by biocoal produced from various types of agricultural waste. Selection of the best available technology for biocoal production should be based on an integrated assessment including economic, environmental and social aspects. It is noted that direct combustion of agricultural waste does not meet environmental safety standards and also requires significant costs for modernization of existing boiler equipment. It is proposed to produce biocoal from agricultural waste using modern methods of thermochemical treatment — torrefaction and carbonization. End-products of biomass torrefaction — biocoal pellets or briquettes — have high calorific value, low sulfur and heavy metal contents, and low nitrogen oxide emissions. Hydrothermal carbonization is currently the most advanced biomass processing technology. It completely prevents pollution and has a number of significant advantages over other methods of biomass treatment. These advantages make it possible to consider hydrothermal carbonization to be the best available technology for the production of biochar, liquid biofuel and other products from non-food biomass. Bibl. 15, Fig. 2, Tab. 1.

scholarly journals Transformation of Sulfur during Co-Hydrothermal Carbonization of Coal Waste and Food Waste

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2271
Author(s):  
Pretom Saha ◽  
Nepu Saha ◽  
Shanta Mazumder ◽  
M. Toufiq Reza
Keyword(s):  
Food Waste ◽  
Hydrothermal Carbonization ◽  
Fuel Properties ◽  
Organic Sulfur ◽  
Coal Waste ◽  
Total Sulfur ◽  
Transformation Mechanism ◽  
Wet Chemical ◽  
The Difference ◽  
Sulfur Transformation

Co-hydrothermal carbonization (Co-HTC) is an emerging technology for processing multiple waste streams together to improve their fuel properties in the solid product, known as hydrochar, compared to the hydrothermal carbonization (HTC) of those individual streams. Sulfur is considered one of the most toxic contaminants in solid fuel and the combustion of this sulfur results in the emission of SOx. It was reported in the literature that, besides the fuel properties, Co-HTC reduced the total sulfur content in the hydrochar phase significantly. However, the transformation of different forms of sulfur has not yet been studied. Therefore, this study investigated the transformation of different forms of sulfur under the Co-HTC treatment. In the study, the Co-HTC of food waste (FW) and two types of coal wastes (middle bottom (CW1) and 4 top (CW2)) were conducted at 180 °C, 230 °C and 280 °C for 30 min. Different forms of sulfur were measured by using elemental analysis (total sulfur), and a wet chemical method (sulfate sulfur and pyritic sulfur). The organic sulfur was measured by the difference method. The results showed that a maximum of 49% and 65% decrease in total sulfur was achieved for CW1FW and CW2FW, respectively, at 230 °C. Similar to the total sulfur, the organic sulfur was also decreased about 85% and 75% for CW1FW and CW2FW, respectively. Based on these results, a sulfur transformation mechanism under Co-HTC treatment was proposed.

scholarly journals HTC of Wet Residues of the Brewing Process: Comprehensive Characterization of Produced Beer, Spent Grain and Valorized Residues

Energies ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 2058 ◽  
Author(s):  
Mateusz Jackowski ◽  
Lukasz Niedzwiecki ◽  
Magdalena Lech ◽  
Mateusz Wnukowski ◽  
Amit Arora ◽  
...  
Keyword(s):  
Main Product ◽  
Hydrothermal Carbonization ◽  
Fuel Properties ◽  
Mass Yield ◽  
Tracer Method ◽  
Brewing Process ◽  
Spent Grain ◽  
Potential Use ◽  
Comprehensive Characterization

Steady consumption of beer results in a steady output of residues, i.e., brewer’s spent grain (BSG). Its valorization, using hydrothermal carbonization (HTC) seems sensible. However, a significant knowledge gap regarding the variability of this residue and its influence on the valorization process and its potential use in biorefineries exists. This study attempted to fill this gap by characterization of BSG in conjunction with the main product (beer), taking into accounts details of the brewing process. Moreover, different methods to assess the performance of HTC were investigated. Overall, the differences in terms of the fuel properties of both types of spent grain were much less stark, in comparison to the differences between the respective beers. The use of HTC as a pretreatment of BSG for subsequent use as a biorefinery feedstock can be considered beneficial. HTC was helpful in uniformization and improvement of the fuel properties. A significant decrease in the oxygen content and O/C ratio and improved grindability was achieved. The Weber method proved to be feasible for HTC productivity assessment for commercial installations, giving satisfactory results for most of the cases, contrary to traditional ash tracer method, which resulted in significant overestimations of the mass yield.

scholarly journals Experimental Study on Hydrothermal Carbonization of Lignocellulosic Biomass with Magnesium Chloride for Solid Fuel Production

Processes ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 444 ◽  
Author(s):  
Samuel Carrasco ◽  
Javier Silva ◽  
Ernesto Pino-Cortés ◽  
Jaime Gómez ◽  
Fidel Vallejo ◽  
...  
Keyword(s):  
Lignocellulosic Biomass ◽  
Solid Fuel ◽  
Magnesium Chloride ◽  
Calorific Value ◽  
Hydrothermal Carbonization ◽  
Volatile Matter ◽  
Matter Content ◽  
Operating Conditions ◽  
Energy Yield ◽  
Mass Yield

The effect of magnesium chloride as an additive of hydrothermal carbonization (HTC) of lignocellulosic biomass (Pinus radiata sawdust) was studied. The HTC tests were carried out at fixed conditions of temperature and residence time of 220 °C and 1 h, respectively, and varying the dose of magnesium chloride in the range 0.0–1.0 g MgCl2/g biomass. The carbonized product (hydrochar) was tested in order to determine its calorific value (HHV) while using PARR 6100 calorimeter, mass yield by gravimetry, elemental analysis using a LECO TruSpec elemental analyzer, volatile matter content, and ash content were obtained by standardized procedures using suitable ovens for it. The results show that using a dose of 0.75 g MgCl2/g biomass results in an impact on the mass yield that was almost equal to change operating conditions from 220 to 270 °C and from 0.5 to 1 h, without additive. Likewise, the calorific value increases by 33% for this additive dose, resulting in an energy yield of 68%, thus generating a solid fuel of prominent characteristics.

scholarly journals Synthesis and characterization of rice husk biochar via hydrothermal carbonization for wastewater treatment and biofuel production

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Nazia Hossain ◽  
Sabzoi Nizamuddin ◽  
Gregory Griffin ◽  
Periasamy Selvakannan ◽  
Nabisab Mujawar Mubarak ◽  
...  
Keyword(s):  
Rice Husk ◽  
Agricultural Waste ◽  
Value Added ◽  
Hydrothermal Carbonization ◽  
Catalytic Performance ◽  
Biofuel Production ◽  
Suspension Stability ◽  
Waste Biomass ◽  
Suitable Material ◽  
Rice Husk Biochar

Abstract The recent implication of circular economy in Australia spurred the demand for waste material utilization for value-added product generations on a commercial scale. Therefore, this experimental study emphasized on agricultural waste biomass, rice husk (RH) as potential feedstock to produce valuable products. Rice husk biochar (RB) was obtained at temperature: 180 °C, pressure: 70 bar, reaction time: 20 min with water via hydrothermal carbonization (HTC), and the obtained biochar yield was 57.9%. Enhancement of zeta potential value from − 30.1 to − 10.6 mV in RB presented the higher suspension stability, and improvement of surface area and porosity in RB demonstrated the wastewater adsorption capacity. Along with that, an increase of crystallinity in RB, 60.5%, also indicates the enhancement of the catalytic performance of the material significantly more favorable to improve the adsorption efficiency of transitional compounds. In contrast, an increase of the atomic O/C ratio in RB, 0.51 delineated high breakdown of the cellulosic component, which is favorable for biofuel purpose. 13.98% SiO2 reduction in RB confirmed ash content minimization and better quality of fuel properties. Therefore, the rice husk biochar through HTC can be considered a suitable material for further application to treat wastewater and generate bioenergy.

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