Bulk-scale synthesis of randomly stacked graphene with high crystallinity

Carbon ◽  
2021 ◽  
Author(s):  
Zizhao Xu ◽  
Shingo Nakamura ◽  
Taiki Inoue ◽  
Yuta Nishina ◽  
Yoshihiro Kobayashi
2020 ◽  
Vol 217 (14) ◽  
pp. 1900868 ◽  
Author(s):  
Shohei Teramura ◽  
Yuta Kawase ◽  
Yusuke Sakuragi ◽  
Sho Iwayama ◽  
Motoaki Iwaya ◽  
...  

2021 ◽  
Vol 127 (2) ◽  
Author(s):  
Min Il Kim ◽  
Jong Hoon Cho ◽  
Jin Ung Hwang ◽  
Byong Chol Bai ◽  
Ji Sun Im

Nanoscale ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 2685-2692
Author(s):  
Isabel S. Curtis ◽  
Ryan J. Wills ◽  
Mita Dasog

High crystallinity, low oxide content, and low sintering lead to optimally performing mesoporous Si photocatalysts for solar-driven hydrogen production.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
N. C. Angastiniotis ◽  
S. Christopoulos ◽  
K. C. Petallidou ◽  
A. M. Efstathiou ◽  
A. Othonos ◽  
...  

AbstractA bulk scale process is implemented for the production of nanostructured film composites comprising unary or multi-component metal oxide nanoparticles dispersed in a suitable polymer matrix. The as-received nanoparticles, namely Al$$_2$$ 2 O$$_3$$ 3 , SiO$$_2$$ 2 and TiO$$_2$$ 2 and binary combinations, are treated following specific chemical and mechanical processes in order to be suspended at the optimal size and composition. Subsequently, a polymer extrusion technique is employed for the fabrication of each film, while the molten polymer is mixed with the treated metal oxide nanoparticles. Transmission and reflection measurements are performed in order to map the optical properties of the fabricated, nanostructured films in the UV, VIS and IR. The results substantiate the capability of the overall methodology to regulate the optical properties of the films depending on the type of nanoparticle formation which can be adjusted both in size and composition.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2238
Author(s):  
Eng-Poh Ng ◽  
Nur Hidayahni Ahmad ◽  
Fitri Khoerunnisa ◽  
Svetlana Mintova ◽  
Tau Chuan Ling ◽  
...  

Offretite zeolite synthesis in the presence of cetyltrimethylammonium bromide (CTABr) is reported. The offretite crystals were synthesized with a high crystallinity and hexagonal prismatic shape after only 72 h of hydrothermal treatment at 180 °C. The CTABr has dual-functions during the crystallization of offretite, viz. as structure-directing agent and as mesoporogen. The resulting offretite crystals, with a Si/Al ratio of 4.1, possess more acid sites than the conventional offretite due to their high crystallinity and hierarchical structure. The synthesized offretite is also more reactive than its conventional counterpart in the acylation of 2-methylfuran for biofuel production under non-microwave instant heating condition, giving 83.5% conversion with 100% selectivity to the desired product 2-acetyl-5-methylfuran. Hence, this amphiphile synthesis approach offers another cost-effective and alternative route for crystallizing zeolite materials that require expensive organic templates.


2021 ◽  
Vol 5 (7) ◽  
pp. 2931-2949
Author(s):  
Xinle Li

sp2 carbon-conjugated COFs (sp2c-COFs) featuring an unparalleled combination of sp2 carbon linkages, extended π-conjugation, high crystallinity, permanent porosity, unique optoelectronic properties, and extraordinary chemical stability, have garnered enormous attention recently.


Nanoscale ◽  
2021 ◽  
Author(s):  
Wonbin Kim ◽  
Hong-Joon Lee ◽  
Seung Jo Yoo ◽  
Trinh Kim Cuc ◽  
Zubair Ahmad ◽  
...  

We prepare poly(pyrrole:biphenyldisulfonic acid:pyrrole (Py:BPDSA:Py)) nanocomposite of molybdenum disulfide (MoS2), P(Py:BPDSA:Py)-MoS2, with high crystallinity. The composite is synthesized by oxidative polymerization of Py:BPDSA:Py as the two-monomer-connected precursors (TMCP) linked by...


Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 462
Author(s):  
Archana R. Deokar ◽  
Ilana Perelshtein ◽  
Melissa Saibene ◽  
Nina Perkas ◽  
Paride Mantecca ◽  
...  

Simultaneous water and ethanol-based synthesis and coating of copper and zinc oxide (CuO/ZnO) nanoparticles (NPs) on bandages was carried out by ultrasound irradiation. High resolution-transmission electron microscopy demonstrated the effects of the solvent on the particle size and shape of metal oxide NPs. An antibacterial activity study of metal-oxide-coated bandages was carried out against Staphylococcus aureus (Gram-positive) and Escherichia coli (Gram-negative). CuO NP-coated bandages made from both water and ethanol demonstrated complete killing of S. aureus and E. coli bacteria within 30 min., whereas ZnO NP-coated bandages demonstrated five-log reductions in viability for both kinds of bacteria after 60 min of interaction. Further, the antibacterial mechanism of CuO/ZnO NP-coated bandages is proposed here based on electron spin resonance studies. Nanotoxicology investigations were conducted via in vivo examinations of the effect of the metal-oxide bandages on frog embryos (teratogenesis assay—Xenopus). The results show that water-based coatings resulted in lesser impacts on embryo development than the ethanol-based ones. These bandages should therefore be considered safer than the ethanol-based ones. The comparison between the toxicity of the metal oxide NPs prepared in water and ethanol is of great importance, because water will replace ethanol for bulk scale synthesis of metal oxide NPs in commercial companies to avoid further ignition problems. The novelty and importance of this manuscript is avoiding the ethanol in the typical water:ethanol mixture as the solvent for the preparation of metal oxide NPs. Ethanol is ignitable, and commercial companies are trying the evade its use. This is especially important these days, as the face mask produced by sonochemistry (SONOMASK) is being sold all over the world by SONOVIA, and it is coated with ZnO.


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