Improvements on modelling wettability alteration by Engineered water injection: Surface complexation at the oil/brine/rock contact

Fuel ◽  
2021 ◽  
Vol 284 ◽  
pp. 118991
Author(s):  
Fabio Bordeaux-Rego ◽  
Mehran Mehrabi ◽  
Alireza Sanaei ◽  
Kamy Sepehrnoori
2021 ◽  
Author(s):  
Bamikole Adeyemi ◽  
Prashant Jadhawar ◽  
Lateef Akanji

Abstract Previous studies on smart water effects have suggested wettability alteration as the most significant mechanism for additional oil recovery during smart water injection. Though many other mechanisms have been observed and proposed in several other studies, much more attention is paid to the detachment of oil films from rock surfaces. It is, however, clear from prevailing understanding that the activities at oil/brine interfaces might require as much attention as given to the brine/rock interfaces. This paper presents diffuse double layer surface complexation modelling of the adsorption of potential determining (Ca2+, Mg2+ and SO42-) ions on oil carboxylic and carbonate surfaces. Surface complexation models are developed by defining the adsorption sites, surface area and mass of the oil and carbonate surfaces. The chemical reactions involving the surface sites and five different brine solutions are also defined. The brine solutions include formation water, sea water, sea water diluted 20 and 50 times, and sea water with four times SO42- concentration. The amount of the divalent ions adsorbed at pH range of 5 to 8 are determined after the reactions had reached equilibrium. Adsorption of the ions on oil carboxylic and carbonate surfaces at elevated temperature for the sea water is also investigated. Results show that significant number of divalent ions are collected at the oil/brine interfaces just as adsorbed at the brine/rock interfaces. The results suggest that the equilibrium reactions and the dynamics at the two mathematical interfaces in any oil/brine/rock systems are equally important to reach a full understanding of the main mechanisms behind smart water effects. Therefore, the dynamics of ionic reactions at the oil/brine interface can play critical roles in defining smart water effects on residual oil mobilization.


2014 ◽  
Vol 695 ◽  
pp. 499-502 ◽  
Author(s):  
Mohamad Faizul Mat Ali ◽  
Radzuan Junin ◽  
Nor Hidayah Md Aziz ◽  
Adibah Salleh

Malaysia oilfield especially in Malay basin has currently show sign of maturity phase which involving high water-cut and also pressure declining. In recent event, Malaysia through Petroliam Nasional Berhad (PETRONAS) will be first implemented an enhanced oil recovery (EOR) project at the Tapis oilfield and is scheduled to start operations in 2014. In this project, techniques utilizing water-alternating-gas (WAG) injection which is a type of gas flooding method in EOR are expected to improve oil recovery to the field. However, application of gas flooding in EOR process has a few flaws which including poor sweep efficiency due to high mobility ratio of oil and gas that promotes an early breakthrough. Therefore, a concept of carbonated water injection (CWI) in which utilizing CO2, has ability to dissolve in water prior to injection was applied. This study is carried out to assess the suitability of CWI to be implemented in improving oil recovery in simulated sandstone reservoir. A series of displacement test to investigate the range of recovery improvement at different CO2 concentrations was carried out with different recovery mode stages. Wettability alteration properties of CWI also become one of the focuses of the study. The outcome of this study has shown a promising result in recovered residual oil by alternating the wettability characteristic of porous media becomes more water-wet.


Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1227 ◽  
Author(s):  
Muhammad Tahir ◽  
Rafael E. Hincapie ◽  
Nils Langanke ◽  
Leonhard Ganzer ◽  
Philip Jaeger

The injection of sulfonated-modified water could be an attractive application as it results in the formation of a mechanically rigid oil-water interface, and hence, possible higher oil recovery in combination with polymer. Therefore, detailed experimental investigation and fluid-flow analysis into porous media are required to understand the possible recovery mechanisms taking place. This paper evaluates the potential influence of low-salt/sulfate-modified water injection in oil recovery using a cross-analyzed approach of coupled microfluidics data and core flooding experiments. Fluid characterization was achieved by detailed rheological characterization focusing on steady shear and in-situ viscosity. Moreover, single and two-phase micromodels and core floods experiments helped to define the behavior of different fluids. Overall, coupling microfluidics, with core flooding experiments, confirmed that fluid-fluid interfacial interaction and wettability alteration are both the key recovery mechanisms for modified-water/low-salt. Finally, a combination of sulfate-modified/low-salinity water, with polymer flood can lead to ~6% extra oil, compared to the combination of polymer flood with synthetic seawater (SSW). The results present an excellent way to make use of micromodels and core experiments as a supporting tool for EOR processes evaluations, assessing fluid-fluid and rock-fluid interactions.


2020 ◽  
Vol 10 (6) ◽  
pp. 6652-6668

Historically, smart water flooding is proved as one of the methods used to enhance oil recovery from hydrocarbon reservoirs. This method has been spread due to its low cost and ease of operation, with changing the composition and concentration of salts in the water, the smart water injection leads to more excellent compatibility with rock and fluids. However, due to a large number of sandstone reservoirs in the world and the increase of the recovery factor using this high-efficiency method, a problem occurs with the continued injection of smart water into these reservoirs a phenomenon happened in which called rock leaching. Indeed, sand production is the most common problem in these fields. Rock wettability alteration toward water wetting is considered as the main cause of sand production during the smart water injection mechanism. During this process, due to stresses on the rock surface as well as disturbance of equilibrium, the sand production in the porous media takes place. In this paper, the effect of wettability alteration of oil wetted sandstones (0.005,0.01,0.02 and 0.03 molar stearic acid in normal heptane) on sand production in the presence of smart water is fully investigated. The implementation of an effective chemical method, which is nanoparticles, have been executed to prevent sand production. By stabilizing silica nanoparticles (SiO2) at an optimum concentration of 2000 ppm in smart water (pH=8) according to the results of Zeta potential and DLS test, the effect of wettability alteration of oil wetted sandstones on sand production in the presence of smart water with nanoparticles is thoroughly reviewed. Ultimately, a comparison of the results showed that nanoparticles significantly reduced sand production.


2019 ◽  
Vol 141 (7) ◽  
Author(s):  
Yanan Ding ◽  
Sixu Zheng ◽  
Xiaoyan Meng ◽  
Daoyong Yang

In this study, a novel technique of low salinity hot water (LSHW) injection with addition of nanoparticles has been developed to examine the synergistic effects of thermal energy, low salinity water (LSW) flooding, and nanoparticles for enhancing heavy oil recovery, while optimizing the operating parameters for such a hybrid enhanced oil recovery (EOR) method. Experimentally, one-dimensional displacement experiments under different temperatures (17 °C, 45 °C, and 70 °C) and pressures (about 2000–4700 kPa) have been performed, while two types of nanoparticles (i.e., SiO2 and Al2O3) are, respectively, examined as the additive in the LSW. The performance of LSW injection with and without nanoparticles at various temperatures is evaluated, allowing optimization of the timing to initiate LSW injection. The corresponding initial oil saturation, production rate, water cut, ultimate oil recovery, and residual oil saturation profile after each flooding process are continuously monitored and measured under various operating conditions. Compared to conventional water injection, the LSW injection is found to effectively improve heavy oil recovery by 2.4–7.2% as an EOR technique in the presence of nanoparticles. Also, the addition of nanoparticles into the LSHW can promote synergistic effect of thermal energy, wettability alteration, and reduction of interfacial tension (IFT), which improves displacement efficiency and thus enhances oil recovery. It has been experimentally demonstrated that such LSHW injection with the addition of nanoparticles can be optimized to greatly improve oil recovery up to 40.2% in heavy oil reservoirs with low energy consumption. Theoretically, numerical simulation for the different flooding scenarios has been performed to capture the underlying recovery mechanisms by history matching the experimental measurements. It is observed from the tuned relative permeability curves that both LSW and the addition of nanoparticles in LSW are capable of altering the sand surface to more water wet, which confirms wettability alteration as an important EOR mechanism for the application of LSW and nanoparticles in heavy oil recovery in addition to IFT reduction.


2018 ◽  
Vol 24 (8) ◽  
pp. 40
Author(s):  
Hussain Ali Baker ◽  
Kareem A. Alwan ◽  
Saher Faris Fadhil

Smart water flooding (low salinity water flooding) was mainly invested in a sandstone reservoir. The main reasons for using low salinity water flooding are; to improve oil recovery and to give a support for the reservoir pressure. In this study, two core plugs of sandstone were used with different permeability from south of Iraq to explain the effect of water injection with different ions concentration on the oil recovery. Water types that have been used are formation water, seawater, modified low salinity water, and deionized water. The effects of water salinity, the flow rate of water injected, and the permeability of core plugs have been studied in order to summarize the best conditions of low salinity water flooding. The result of this experimental work shows that the water without any free ions (deionized water) and modified low salinity water have improved better oil recovery than the formation water and seawater as a secondary oil process. The increase in oil recovery factor related to the wettability alteration during low salinity water flooding which causes a decrease in the interfacial tension between the crude oil in porous media and the surface of reservoir rocks. As well as the dissolution of minerals such as calcite Ca+2 was observed in this work, which causes an increase in the pH value. All these factors led to change the wettability of rock to be more water-wet, so the oil recovery can be increased.  


2020 ◽  
Author(s):  
Fabio Bordeaux Rego ◽  
Mehran Mehrabi ◽  
Alireza Sanaei ◽  
Kamy Sepehrnoori

2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Alibi Kilybay ◽  
Bisweswar Ghosh ◽  
Nithin Chacko Thomas

In the oil and gas industry, Enhanced Oil Recovery (EOR) plays a major role to meet the global requirement for energy. Many types of EOR are being applied depending on the formations, fluid types, and the condition of the field. One of the latest and promising EOR techniques is application of ion-engineered water, also known as low salinity or smart water flooding. This EOR technique has been studied by researchers for different types of rocks. The mechanisms behind ion-engineered water flooding have not been confirmed yet, but there are many proposed mechanisms. Most of the authors believe that the main mechanism behind smart water flooding is the wettability alteration. However, other proposed mechanisms are interfacial tension (IFT) reduction between oil and injected brine, rock dissolution, and electrical double layer expansion. Theoretically, all the mechanisms have an effect on the oil recovery. There are some evidences of success of smart water injection on the field scale. Chemical reactions that happen with injection of smart water are different in sandstone and carbonate reservoirs. It is important to understand how these mechanisms work. In this review paper, the possible mechanisms behind smart water injection into the carbonate reservoir with brief history are discussed.


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