Correlation of sodium releasing and mineral transformation characteristics with ash composition of typical high-alkali coals

2021 ◽  
Vol 224 ◽  
pp. 107035
Author(s):  
Tai Zhang ◽  
Zishun Li ◽  
Fan Hu ◽  
Xiaohong Huang ◽  
Zhaohui Liu
Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1092
Author(s):  
Hengli Zhang ◽  
Chunjiang Yu ◽  
Zhongyang Luo ◽  
Yu’an Li

The circulating fluidized bed (CFB) boiler is a mainstream technology of biomass combustion generation in China. The high flue gas flow rate and relatively low combustion temperature of CFB make the deposition process different from that of a grate furnace. The dynamic deposition process of biomass ash needs further research, especially in industrial CFB boilers. In this study, a temperature-controlled ash deposit probe was used to sample the deposits in a 12 MW CFB boiler. Through the analysis of multiple deposit samples with different deposition times, the changes in micromorphology and chemical composition of the deposits in each deposition stage can be observed more distinctively. The initial deposits mainly consist of particles smaller than 2 μm, caused by thermophoretic deposition. The second stage is the condensation of alkali metal. Different from the condensation of KCl reported by most previous literatures, KOH is found in deposits in place of KCl. Then, it reacts with SO2, O2 and H2O to form K2SO4. In the third stage, the higher outer layer temperature of deposits reduces the condensation rate of KOH significantly. Meanwhile, the rougher surface of deposits allowed more calcium salts in fly ash to deposit through inertial impact. Thus, the elemental composition of deposits surface shows an overall trend of K decreasing and Ca increasing.


2021 ◽  
pp. 1-20
Author(s):  
Xiao-Fei Qiu ◽  
Qiong Xu ◽  
Tuo Jiang ◽  
Shan-Song Lu ◽  
Long Zhao

Abstract The South Qinling block, a segment of the Yangtze craton involved in the Qinling–Dabie orogen, is critical for understanding the tectonic evolution of eastern China. However, the tectonic setting of the South Qinling block and the northern margin of the Yangtze block during middle Neoproterozoic time has long been the subject of debate, with two distinctly different models (continental rift or volcanic arc) proposed. Here, a comprehensive study of zircon U–Pb geochronology and geochemistry has been carried out on the Chengwan granitic pluton from the Suizao terrane in the South Qinling block. The granites are monzogranite and syenogranite in lithology, and are mainly composed of potash feldspar, quartz, plagioclase and biotite. This suite has long been regarded as a Palaeozoic magmatic pluton, but zircon U–Pb ages of 809 ± 9 Ma and 816 ± 4 Ma are obtained in this study. The granites are metaluminous to strongly peraluminous with high alkali contents, and exhibit highly fractionated features, including high SiO2, low Zr/Hf ratios, rare earth element tetrad effects and enrichment of K and Rb. They show Hf–Nd isotopic decoupling, which may be genetically related to their petrogenetic process. Based on the geochemical features and the positive εHf(t) values of the zircons, it is indicated that the granites may have been derived from partial melting of juvenile tonalitic rocks by biotite breakdown under fluid-absent conditions. The Chengwan granite geochemically belongs to the A2-subtype granites, suggesting that it might have formed in a post-orogenic tectonic setting. The highly fractionated A-type granite in this study may represent extensional collapse shortly after the collisional events in the South Qinling block, and thus indicate a tectonic regime switch, from compression to extension, as early as middle Neoproterozoic time. Integrating our new data with documented magmatic, metamorphic and sedimentary events during middle Neoproterozoic time in the region may support a continental rift model, and argues against arc models.


Fuel ◽  
2013 ◽  
Vol 105 ◽  
pp. 293-300 ◽  
Author(s):  
Bo Liu ◽  
Qihui He ◽  
Zihao Jiang ◽  
Renfu Xu ◽  
Baixing Hu
Keyword(s):  
Coal Ash ◽  

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2967
Author(s):  
Seunghoon Choi ◽  
Sungjin Park ◽  
Minjoo Park ◽  
Yerin Kim ◽  
Kwang Min Lee ◽  
...  

Biomineralization, a well-known natural phenomenon associated with various microbial species, is being studied to protect and strengthen building materials such as concrete. We characterized Rhodococcus erythreus S26, a novel urease-producing bacterium exhibiting CaCO3-forming activity, and investigated its ability in repairing concrete cracks for the development of environment-friendly sealants. Strain S26 grown in solid medium formed spherical and polygonal CaCO3 crystals. The S26 cells grown in a urea-containing liquid medium caused culture fluid alkalinization and increased CaCO3 levels, indicating that ureolysis was responsible for CaCO3 formation. Urease activity and CaCO3 formation increased with incubation time, reaching a maximum of 2054 U/min/mL and 3.83 g/L, respectively, at day four. The maximum CaCO3 formation was achieved when calcium lactate was used as the calcium source, followed by calcium gluconate. Although cell growth was observed after the induction period at pH 10.5, strain S26 could grow at a wide range of pH 4–10.5, showing its high alkali tolerance. FESEM showed rhombohedral crystals of 20–60 µm in size. EDX analysis indicated the presence of calcium, carbon, and oxygen in the crystals. XRD confirmed these crystals as CaCO3 containing calcite and vaterite. Furthermore, R. erythreus S26 successfully repaired the artificially induced large cracks of 0.4–0.6 mm width.


Fuel ◽  
2017 ◽  
Vol 203 ◽  
pp. 781-791 ◽  
Author(s):  
Tosin Onabanjo Somorin ◽  
Athanasios J. Kolios ◽  
Alison Parker ◽  
Ewan McAdam ◽  
Leon Williams ◽  
...  

2014 ◽  
Vol 852 ◽  
pp. 71-75 ◽  
Author(s):  
Ying Liang Tian ◽  
Jin Shu Cheng ◽  
Jing Zhang ◽  
Yan Li Shao ◽  
Xiao Li

High alkali aluminosilicate glass batches were prepared by five different raw materials, reaction heat of which in melting process was studied by means of DSC thermal analysis method. The results show that reaction heat of batches in the heating process of 25-1600°C exists a significant difference, and which is among 4396.38 J/g-5311.14 J/g, moreover the least is the batches using petalite, while the most is spodumene. In the whole heating process, 380-800°C is carbonate decomposition stage, which accounts for 42-46% of the total absorbed heat; and 800-1200°C is silicate reaction stage, 40-50%; and 1200-1600°C is glass clarify and homogenization phase , 6%-16%. Therefore, carbonate decomposition and silicate reaction is the main part of batches heat consumption, the optimization scheme for materials has a significant effect on energy saving and emission reduction.


2017 ◽  
Vol 122 ◽  
pp. 285-296 ◽  
Author(s):  
Guoliang Song ◽  
Shaobo Yang ◽  
Weijian Song ◽  
Xiaobin Qi
Keyword(s):  

Author(s):  
R. A. Batchelor ◽  
J. A. Weir

ABSTRACTThe Moffat Shale Group is a condensed, variable and partly pelagic sequence of mudrocks of Llandeilo—Llandovery age. The sequence has a five-fold lithological subdivision based mainly on the occurrence of grey mudstones within a succession otherwise dominated by fully euxinic black graptolitic mudrocks. Associated with the black mudrocks, especially in the Llandovery, are metabentonite beds which achieve a climax, both in thickness and in number, within the top quarter of the mudrock sequence. A geochemical and mineralogical study has confirmed a volcanic origin for the metabentonites. Major element data highlight a carbonate-dominated environment above the gregarius—convolutus Zones boundary. Phosphorus levels reach a peak at the same boundary, as well as at the Caradoc—Ashgill boundary where phosphorite horizons are known from Wales and Norway. Immobile trace elements have highlighted regular changes in source magma composition. Prolonged periods of crystal fractionation in magmas of intermediate composition gave rise, on eruption, to large volumes of silicic ash which had a deleterious effect on graptolite species and led to local extinctions. Regular fluctuations in ash composition from silicic to intermediate are ascribed to alternating fractionation and magma mixing cycles.


Fuel ◽  
2015 ◽  
Vol 139 ◽  
pp. 671-677 ◽  
Author(s):  
A. Konist ◽  
A. Valtsev ◽  
L. Loo ◽  
T. Pihu ◽  
M. Liira ◽  
...  

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