Effect of kinetic control, soil:solution ratio, electrolyte cation, and others, on equilibrium phosphorus concentration

Geoderma ◽  
2012 ◽  
Vol 173-174 ◽  
pp. 209-214 ◽  
Author(s):  
Jehangir H. Bhadha ◽  
Samira H. Daroub ◽  
Timothy A. Lang
1983 ◽  
Vol 23 (120) ◽  
pp. 38 ◽  
Author(s):  
PW Moody ◽  
GF Haydon ◽  
T Dickson

Grain yield response of soybean (Glycine max cv. Bragg) to applied phosphorus was measured at 19 experimental sites in the South Burnett region. The soil phosphorus supply factors of quantity, intensity, buffer capacity and rate were estimated by various soil chemical tests, and relative yield [(yield at nil applied phosphorus/maximum yield) x 100] regressed against these tests. The equilibrium phosphorus concentration-the intensity measure-accounted for the greatest percentage variation in relative yield (80%) and at 90% maximum yield was 0.014 �g P/ml. Phosphorus extracted by 0.01 M CaCl2 was highly correlated with the equilibrium phosphorus concentration (r2=0.93) and accounted for 73% of the variation in relative yield. Soil levels of calcium chloride-extractable phosphorus were interpreted as follows: < 0.044 �g P/g, response to phosphorus probable; 0.044 �g P/g to 0.058 �g P/g, response uncertain; > 0.058 �g P/g, response unlikely


2016 ◽  
Vol 5 (1) ◽  
pp. 31 ◽  
Author(s):  
Jingqiu Piao ◽  
Changyuan Tang ◽  
Toma Matsumaru ◽  
Zhiwei Han ◽  
Hiroki Sakaguchi ◽  
...  

<p>The distribution and adsorption characteristics of phosphorus were investigated in a typical headwater wetland in Ichikawa City, Chiba Prefecture, Japan. Total dissolved phosphorus (TDP) was the main phosphorus fraction in the waters, ranging from limit of quantification (0.002 mg/L) to 0.059 mg/L in spring water, from limit of quantification to 0.128 mg/L in groundwater and from 0.012 to 0.048 mg/L in river water. TDP in 33% water samples were higher than the environmental quality standard for eutrophication (0.020 mg/L). Next, phosphorus adsorption experiment was conducted to study phosphorus distribution in the aquifer where the equilibrium phosphorus concentration (C<sub>EPC</sub>) is the key to access the phosphorus in the waters. In addition, the amount of TDP releasing from the wetland through river was 20.9 g/day.</p>


1959 ◽  
Vol 39 (1) ◽  
pp. 64-75 ◽  
Author(s):  
D. A. Rennie ◽  
R. B. McKercher

The adsorption of phosphorus by four soils of differing colloid content showed close agreement with the Langmuir isotherm when final phosphorus solution concentrations were less than 20 μg. P/ml. Calculated adsorption maximum for the four soils were 79.1, 87.7, 150.4 and 164.4 μg. P per g. of soil. The average value of the constant k, related to the bounding energy of the soil for phosphorus, was 0.141.The percentage phosphorus saturation of the adsorption maximum was closely correlated with the equilibrium phosphorus concentration in the soil suspension. At an equilibrium concentration of 28.7 μg. P/ml., 100 per cent saturation of the adsorption capacity of the four soils was obtained; the total adsorbed phosphorus on the four soils was not related to the phosphorus concentration of the soil solution but varied considerably depending on the colloid content of the respective soils.Carbonated water extractable phosphorus, and 'surface' phosphorus measured by P32 equilibrium studies, were not related to the equilibrium concentration of phosphorus of the soil solution. It appears that the percentage phosphorus saturation of the adsorption maximum may prove a more reliable measure of the capacity of the soil to supply phosphorus to the soil solution than either of the 'quick' tests used.Organic matter appeared to be equally as important as the inorganic colloids in determining the phosphorus adsorption capacity of the soils. Differences in exchangeable calcium were not closely related to the adsorption maximum.


Author(s):  
Valeriy G. Yakubenko ◽  
Anna L. Chultsova

Identification of water masses in areas with complex water dynamics is a complex task, which is usually solved by the method of expert assessments. In this paper, it is proposed to use a formal procedure based on the application of the method of optimal multiparametric analysis (OMP analysis). The data of field measurements obtained in the 68th cruise of the R/V “Academician Mstislav Keldysh” in the summer of 2017 in the Barents Sea on the distribution of temperature, salinity, oxygen, silicates, nitrogen, and phosphorus concentration are used as a data for research. A comparison of the results with data on the distribution of water masses in literature based on expert assessments (Oziel et al., 2017), allows us to conclude about their close structural similarity. Some differences are related to spatial and temporal shifts of measurements. This indicates the feasibility of using the OMP analysis technique in oceanological studies to obtain quantitative data on the spatial distribution of different water masses.


1992 ◽  
Vol 27 (2) ◽  
pp. 271-286 ◽  
Author(s):  
Sonia Paulino Mattos ◽  
Irene Guimarães Altafin ◽  
Hélio José de Freitas ◽  
Cristine Gobbato Brandão Cavalcanti ◽  
Vera Regina Estuqui Alves

Abstract Built in 1959, Lake Paranoá, in Brasilia, Brazil, has been undergoing an accelerated process of nutrient enrichment, due to inputs of inadequately treated raw sewage, generated by a population of 600,000 inhabitants. Consequently, it shows high nutrient content (40 µg/L of total phosphorus and 1800 µg/L of total nitrogen), low transparency (0.65 m) and high levels of chlorophyll a (65 µg/L), represented mainly by Cylindrospermopsis raciborskii and sporadic bloom of Microcystis aeruginosa, which is being combatted with copper sulphate. With the absence of seasonality and a vertical distribution which is not very evident, the horizontal pattern assumes great importance in this reservoir, in which five compartments stand out. Based on this segmentation and on the identification of the total phosphorus parameter as the limiting factor for algal growth, mathematical models were developed which demonstrate the need for advanced treatment of all the sewage produced in its drainage basin. With this, it is expected that a process of restoration will be initiated, with a decline in total phosphorus concentration to readings below 25 µg/L. Additional measures are proposed to accelerate this process.


1994 ◽  
Vol 30 (5) ◽  
pp. 177-186 ◽  
Author(s):  
Karin Sundblad ◽  
Andrzej Tonderski ◽  
Jacek Rulewski

Nitrogen and phosphorus concentration data representing samples collected once a month for nine months at 13 locations along the Vistula River are considered in a preliminary discussion of the sources of the nutrients transported to the Baltic Sea. Concentrations in relation to flow data indicated substantial differences between subbasins. Based on those differences, on the area-specific nutrient loss for a six-month period and on the wastewater discharge in each subbasin, four regions could be recognized in the river basin: i) the southern region with a large impact of point sources, ii) the south central region, where diffuse sources seemed to be of major importance, iii) the north central region with a combined effect of point and diffuse sources, and retention in two reservoirs, iv) the northern region where point sources seemed to be the dominating source, at least for phosphorus. Our results illustrate the importance of differences in phosphorus retention between the basins. Long-term retention along the course of the river, particularly in the two reservoirs, must be estimated to allow proper source apportionment in the Vistula basin. Concentration decreases in the Wloclawek Reservoir varied between 44 and 68% for P, and 11 to 37% for N, in the months with significant retention. In some months, however, concentrations increased, indicating a release of nutrients.


1993 ◽  
Vol 28 (3-5) ◽  
pp. 441-449 ◽  
Author(s):  
Paul J. Garrison ◽  
Timothy R. Asplund

Nonpoint source controls were installed in a 1215 ha agricultural watershed in northeastern Wisconsin in the late 1970. Changes were made in handling of animal wastes and cropping practices to reduce runoff of sediment and nutrients. Modelling results predicted a reduction in phosphorus runoff of 30 percent. The water quality of White Clay Lake has worsened since the installation of NPS controls. The lake's phosphorus concentration has increased from a mean of 29 µg L−1 in the late 1970s to 44 µg L−1 in recent years. Water clarity has declined from 2.7 to 2.1 m and the mean summer chlorophyll levels have increased from 9 to 13 µg L−1 with peak values exceeding 40 µg L−1. Increased phosphorus loading is not the result of elevated precipitation but instead the failure of the control measures to sufficiently reduce P loading. Most of the effort was placed on structural changes while most of the P loading comes from cropland runoff. Further, soil phosphorus concentrations have increased because of artificial fertilizers and manure spreading. The White Clay Lake experience is discouraging since the majority of the polluters in this watershed utilized some NPS control practices, including 76 percent of the farms which installed waste management control facilities.


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