Effects of potassium peroxymonosulfate on disintegration of waste sludge and properties of extracellular polymeric substances

2016 ◽  
Vol 106 ◽  
pp. 170-177 ◽  
Author(s):  
Tianhao Niu ◽  
Zhen Zhou ◽  
Weichao Ren ◽  
Lu-Man Jiang ◽  
Bingyue Li ◽  
...  
2001 ◽  
Vol 43 (6) ◽  
pp. 59-66 ◽  
Author(s):  
Y. Liu ◽  
M. C. Lam ◽  
H. H. Fang

Extracellular polymeric substances (EPSs) were extracted by high-speed centrifugation at 20,000 G for 30 min from an activated sludge treating municipal wastewater. Each gram of sludge, as measured in volatile suspended solids (VSS), contained 7.3 mg of EPS, including 6.5 mg of protein (EPSp) and 0.8 mg of carbohydrate (EPSc). The EPSp had a mean MW of 2.0×105; about 18% of EPSp had MW over 5×104 and 16% below 5×103. For heavy metal concentrations ranging 10-100 mg/l, EPS on average removed 99% of Zn2+, 98% of Cu2+, 97% of Cr3+, 85% of Cd2+, 69% of Co2+, 37% of Ni2+, and 26% of CrO42-. The relative degrees of metal removals were inconsistent with those reported for the activated sludge process. Each mg of ESP had the capacity to remove up to 1.48 mg of Zn2+, 1.12 mg of Cu2+, 0.83 mg of Cr3+, 0.90 mg of Cd2+, 1.10 mg of Co2+, 0.25 mg each of Ni2+ and CrO42-. Results suggest the feasibility of recovering ESP from waste sludge for use as adsorbent. Freundlich isotherm correlated satisfactorily with the adsorption data of Ni2+,Cu2+, Cd2+, and CrO42-, (R2 ranging 0.89-0.97), whereas Langmuir isotherm correlated satisfactorily with those of Zn2+, Cr3+ and Ni2+ (R2 ranging 0.93-0.96). Both correlated poorly for those of Co2+.


2021 ◽  
Author(s):  
Dong Thanh Nguyen ◽  
Hoang Xuan Dinh ◽  
Trang Thi Thu Nguyen ◽  
Quy Van Tran ◽  
Phuong Minh Nguyen ◽  
...  

Abstract The aim of this study was to investigate the adsorption of three commercial reactive dyes using extracellular polymeric substances (EPS) extracted from the waste sludge of a beer wastewater treatment plant in Hanoi, Vietnam. EPS was extracted from sludge by HCHO-NaOH method and characterized by the measurement of kaolin flocculation activity, dry weight, chemical composition and functional groups. Adsorption of dyes on EPS was conducted by Jartest at different pH, reaction time and EPS dosage. The EPS was composed of 25% of sludge weight. The FTIR analysis showed the present of amine and carboxyl group in the EPS structure. The removal efficiencies of reactive dyes were high at pH below 6, the contact time was from 30 to 60 min and EPS dosage of 200 – 250 mg/L. At optimum condition, the removal efficiency of 85%, 99% and 99% were obtained for Reactive Yellow 176 (RY 176), Reactive Blue 21 (RB 21) and Reactive Red 241 (RR 241), respectively. The adsorption process could be described by both Langmuir and Fruendlich isothermal equations. The maximum dye adsorption capacity for RY 176, RB 21 and RR 241 was 0.50 g/g, 0.72 g/g and 0.95 g/g, respectively. This study revealed that the EPS in wastewater sludge can be utilized as an effective adsorbent for dyes removal, thereby, enhancing the value of sludge in wastewater treatment.


2019 ◽  
Author(s):  
Yoshihide Furuichi ◽  
Shogo Yoshimoto ◽  
Tomohiro Inaba ◽  
Nobuhiko Nomura ◽  
Katsutoshi Hori

<p></p><p>Biofilms are used in environmental biotechnologies including waste treatment and environmentally friendly chemical production. Understanding the mechanisms of biofilm formation is essential to control microbial behavior and improve environmental biotechnologies. <i>Acinetobacter </i>sp. Tol 5 autoagglutinate through the interaction of the long, peritrichate nanofiber protein AtaA, a trimeric autotransporter adhesin. Using AtaA, without cell growth or the production of extracellular polymeric substances, Tol 5 cells quickly form an unconventional biofilm. In this study, we investigated the formation process of this unconventional biofilm, which started with cell–cell interactions, proceeded to cell clumping, and led to the formation of large cell aggregates. The cell–cell interaction was described by DLVO theory based on a new concept, which considers two independent interactions between two cell bodies and between two AtaA fiber tips forming a virtual discontinuous surface. If cell bodies cannot collide owing to an energy barrier at low ionic strengths but approach within the interactive distance of AtaA fibers, cells can agglutinate through their contact. Cell clumping proceeds following the cluster–cluster aggregation model, and an unconventional biofilm containing void spaces and a fractal nature develops. Understanding its formation process would extend the utilization of various types of biofilms, enhancing environmental biotechnologies.</p><p></p>


1992 ◽  
Vol 25 (3) ◽  
pp. 207-212 ◽  
Author(s):  
F. J. Castaldi ◽  
D. L. Ford

Slurry bioremediation testing was conducted on waste sludges from petrochemical production. The study concludes that the apparent mechanism for remediation of the waste involves an initial dissolution of the waste constituents into the aqueous phase followed by actual biodegradation. The test reactor most successful in the solubilization and dispersal of waste constituents and possibly most effective in reducing waste sludge mass during treatment is the reactor with the lowest waste sludge-to-microorganism ratio.


1985 ◽  
Vol 17 (8) ◽  
pp. 1475-1478 ◽  
Author(s):  
A P. C. Warner ◽  
G. A. Ekama ◽  
G v. R. Marais

The laboratory scale experimental investigation comprised a 6 day sludge age activated sludge process, the waste sludge of which was fed to a number of digesters operated as follows: single reactor flow through digesters at 4 or 6 days sludge age, under aerobic and anoxic-aerobic conditions (with 1,5 and 4 h cycle times) and 3-in-series flow through aerobic digesters each at 4 days sludge age; all digesters were fed draw-and-fill wise once per day. The general kinetic model for the aerobic activated sludge process set out by Dold et al., (1980) and extended to the anoxic-aerobic process by van Haandel et al., (1981) simulated accurately all the experimental data (Figs 1 to 4) without the need for adjusting the kinetic constants. Both theoretical simulations and experimental data indicate that (i) the rate of volatile solids destruction is not affected by the incorporation of anoxic cycles and (ii) the specific denitrification rate is independent of sludge age and is K4T = 0,046(l,029)(T-20) mgNO3-N/(mg active VSS. d) i.e. about 2/3 of that in the secondary anoxic of the single sludge activated sludge stystem. An important consequence of (i) and (ii) above is that denitrification can be integrated easily in the steady state digester model of Marais and Ekama (1976) and used for design (Warner et al., 1983).


1986 ◽  
Vol 18 (7-8) ◽  
pp. 413-420 ◽  
Author(s):  
P. C. Chiang ◽  
J. H. You

In this investigation it was found that the waste sludge obtained from a municipal sewage treatment plant could be reclaimed as an adsorbent for removal of organic vapours, i.e. toluene, methyl-ethyl-ketone and 1-1-2-trichloroethylene, through use of a pyrolysis technique. In order to find the optimum manufacturing process, several tests were performed under various conditions in which the addition of a catalyst, temperature control, and residence time in the furnace, were considered as the three major factors. Both the reclaimed adsorbent and commercially available activated carbon were evaluated to determine their adsorption capacity at various influent concentrations of organic vapours.


1995 ◽  
Vol 31 (12) ◽  
pp. 379-387 ◽  
Author(s):  
Henryk Melcer ◽  
Brian Evans ◽  
Stephen G. Nutt ◽  
Anthony Ho

To establish Best Available Technology Economically Achievable (BATEA) in non-urban communities which presently use conventional lagoon technology, an investigation was undertaken to evaluate alternatives which can be used to improve lagoon effluent and establish costs. Evaluated were the “Sutton” and the intermittent sand filtration or “New Hamburg” processes. The Sutton concept consists of a nitrifying extended-aeration plant followed by polishing lagoons, with waste sludge discharged into the lagoons. The New Hamburg concept consists of aerated or facultative lagoons, with the lagoon effluent sprayed intermittently over sand filters. The Sutton plants produce an improved effluent quality relative to conventional facultative lagoons in terms of BOD5 and TSS concentrations. Increases in ammonia concentration across the polishing pond occur after 5-7 years of plant operation, suggesting a need to implement a regular program of sludge removal from the lagoon. The New Hamburg process results in a significant improvement in effluent quality in terms of BOD5, TSS, TP, TKN, NH3-N and H2S concentrations. Approximate capital costs for upgrading the existing conventional lagoons in Ontario to Sutton and New Hamburg process facilities are estimated at US $221 million and US $93 million, respectively.


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