scholarly journals Adsorption of heavy metals by EPS of activated sludge

2001 ◽  
Vol 43 (6) ◽  
pp. 59-66 ◽  
Author(s):  
Y. Liu ◽  
M. C. Lam ◽  
H. H. Fang
Keyword(s):  
Activated Sludge ◽  
High Speed ◽  
Suspended Solids ◽  
Extracellular Polymeric Substances ◽  
Municipal Wastewater ◽  
Freundlich Isotherm ◽  
Activated Sludge Process ◽  
Heavy Metal Concentrations ◽  
Waste Sludge ◽  
Adsorption Data

Extracellular polymeric substances (EPSs) were extracted by high-speed centrifugation at 20,000 G for 30 min from an activated sludge treating municipal wastewater. Each gram of sludge, as measured in volatile suspended solids (VSS), contained 7.3 mg of EPS, including 6.5 mg of protein (EPSp) and 0.8 mg of carbohydrate (EPSc). The EPSp had a mean MW of 2.0×105; about 18% of EPSp had MW over 5×104 and 16% below 5×103. For heavy metal concentrations ranging 10-100 mg/l, EPS on average removed 99% of Zn2+, 98% of Cu2+, 97% of Cr3+, 85% of Cd2+, 69% of Co2+, 37% of Ni2+, and 26% of CrO42-. The relative degrees of metal removals were inconsistent with those reported for the activated sludge process. Each mg of ESP had the capacity to remove up to 1.48 mg of Zn2+, 1.12 mg of Cu2+, 0.83 mg of Cr3+, 0.90 mg of Cd2+, 1.10 mg of Co2+, 0.25 mg each of Ni2+ and CrO42-. Results suggest the feasibility of recovering ESP from waste sludge for use as adsorbent. Freundlich isotherm correlated satisfactorily with the adsorption data of Ni2+,Cu2+, Cd2+, and CrO42-, (R2 ranging 0.89-0.97), whereas Langmuir isotherm correlated satisfactorily with those of Zn2+, Cr3+ and Ni2+ (R2 ranging 0.93-0.96). Both correlated poorly for those of Co2+.

scholarly journals Systematic Modeling of Municipal Wastewater Activated Sludge Process and Treatment Plant Capacity Analysis Using GPS-X

2020 ◽  
Vol 12 (19) ◽  
pp. 8182
Author(s):  
Nuhu Dalhat Mu’azu ◽  
Omar Alagha ◽  
Ismail Anil
Keyword(s):  
Activated Sludge ◽  
Suspended Solids ◽  
Systematic Approach ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Oxygen Demand ◽  
Plant Performance ◽  
Capacity Analysis ◽  
Activated Sludge Process ◽  
Effluent Quality

Mathematical modeling has become an indispensable tool for sustainable wastewater management, especially for the simulation of complex biochemical processes involved in the activated sludge process (ASP), which requires a substantial amount of data related to wastewater and sludge characteristics as well as process kinetics and stoichiometry. In this study, a systematic approach for calibration of the activated sludge model one (ASM1) model for a real municipal wastewater ASP was undertaken in GPS-X. The developed model was successfully validated while meeting the assumption of the model’s constant stoichiometry and kinetic coefficients for any plant influent compositions. The influences of vital ASP parameters on the treatment plant performance and capacity analysis for meeting local discharge limits were also investigated. Lower influent chemical oxygen demand in mgO2/L (COD) could inhibit effective nitrification and denitrification, while beyond 250 mgO2/L, there is a tendency for effluent quality to breach the regulatory limit. The plant performance can be satisfactory for handling even higher influent volumes up to 60,000 m3/d and organic loading when Total Suspended Solids/Volatile Suspended Solids (VSS/TSS) and particulate COD (XCOD)/VSS are maintained above 0.7 and 1, respectively. The wasted activated sludge (WAS) has more impact on the effluent quality compared to recycle activated sludge (RAS) with significant performance improvement when the WAS was increased from 3000 to 9000 m3/d. Hydraulic retention time (HRT) > 6 h and solids retention time (SRT) < 7 days resulted in better plant performance with the SRT having greater impact compared with HRT. The plant performance could be sustained for a quite appreciable range of COD/5-day Biochemical Oxygen Demand (BOD5 in mgO2/L) ratio, Mixed Liquor Suspended Solid (MLSS) of up to 6000 mg/L, and when BOD5/total nitrogen (TN) and COD/TN are comparatively at higher values. This work demonstrated a systematic approach for estimation of the wastewater treatment plant (WWTP) ASP parameters and the high modeling capabilities of ASM1 in GPS-X when respirometry tests data are lacking.

Comparison of Aerobic and Anoxic-Aerobic Digestion of Waste Activated Sludge

1985 ◽  
Vol 17 (8) ◽  
pp. 1475-1478 ◽  
Author(s):  
A P. C. Warner ◽  
G. A. Ekama ◽  
G v. R. Marais
Keyword(s):  
Experimental Data ◽  
Activated Sludge ◽  
Waste Activated Sludge ◽  
Activated Sludge Process ◽  
Cycle Times ◽  
Waste Sludge ◽  
Volatile Solids ◽  
In Series ◽  
Flow Through ◽  
Theoretical Simulations

The laboratory scale experimental investigation comprised a 6 day sludge age activated sludge process, the waste sludge of which was fed to a number of digesters operated as follows: single reactor flow through digesters at 4 or 6 days sludge age, under aerobic and anoxic-aerobic conditions (with 1,5 and 4 h cycle times) and 3-in-series flow through aerobic digesters each at 4 days sludge age; all digesters were fed draw-and-fill wise once per day. The general kinetic model for the aerobic activated sludge process set out by Dold et al., (1980) and extended to the anoxic-aerobic process by van Haandel et al., (1981) simulated accurately all the experimental data (Figs 1 to 4) without the need for adjusting the kinetic constants. Both theoretical simulations and experimental data indicate that (i) the rate of volatile solids destruction is not affected by the incorporation of anoxic cycles and (ii) the specific denitrification rate is independent of sludge age and is K4T = 0,046(l,029)(T-20) mgNO3-N/(mg active VSS. d) i.e. about 2/3 of that in the secondary anoxic of the single sludge activated sludge stystem. An important consequence of (i) and (ii) above is that denitrification can be integrated easily in the steady state digester model of Marais and Ekama (1976) and used for design (Warner et al., 1983).

Specific organic and nutrient loads in stabilized sludge from municipal treatment plants

1996 ◽  
Vol 33 (12) ◽  
pp. 243-250 ◽  
Author(s):  
O. Nowak ◽  
A. Franz ◽  
K. Svardal ◽  
V. Müller
Keyword(s):  
Activated Sludge ◽  
Nitrogen Removal ◽  
Single Stage ◽  
Nutrient Loads ◽  
Activated Sludge Process ◽  
Waste Sludge ◽  
Sludge Stabilization ◽  
Nitrogen Loads ◽  
Theoretical Considerations ◽  
P Removal

By means of theoretical considerations and of statistical evaluations, specific organic and nitrogen loads in separately stabilized sludge have been found to be in the range of 16 to 20g VSS/PE/d and of 1.1 to 1.5 g N/PE/d respectively. About 0.6g P/PE/d are removed from the wastewater in activated sludge plants without chemical or enhanced biological P removal. By using the single-stage activated sludge process without primary sedimentation and without separate sludge stabilization, almost complete nitrogen removal can be achieved, but specific organic and nitrogen loads in the waste sludge are up to two times higher than in separately stabilized sludge.

Dynamic modeling of nitrogen removal for a three-stage integrated fixed-film activated sludge process treating municipal wastewater

2017 ◽  
Vol 41 (2) ◽  
pp. 237-247 ◽  
Author(s):  
Paul Moretti ◽  
Jean-Marc Choubert ◽  
Jean-Pierre Canler ◽  
Pierre Buffière ◽  
Olivier Pétrimaux ◽  
...  
Keyword(s):  
Activated Sludge ◽  
Dynamic Modeling ◽  
Nitrogen Removal ◽  
Municipal Wastewater ◽  
Activated Sludge Process ◽  
Fixed Film

scholarly journals Microalgae as biological treatment for municipal wastewater – effects on the sludge handling in a treatment plant

2018 ◽  
Vol 78 (3) ◽  
pp. 644-654 ◽  
Author(s):  
J. Olsson ◽  
S. Schwede ◽  
E. Nehrenheim ◽  
E. Thorin
Keyword(s):  
Heavy Metals ◽  
Activated Sludge ◽  
Biological Treatment ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Waste Activated Sludge ◽  
Activated Sludge Process ◽  
Primary Sludge ◽  
Thermophilic Conditions ◽  
Mesophilic Conditions

Abstract A mix of microalgae and bacteria was cultivated on pre-sedimented municipal wastewater in a continuous operated microalgae-activated sludge process. The excess material from the process was co-digested with primary sludge in mesophilic and thermophilic conditions in semi-continuous mode (5 L digesters). Two reference digesters (5 L digesters) fed with waste-activated sludge (WAS) and primary sludge were operated in parallel. The methane yield was slightly reduced (≈10%) when the microalgal-bacterial substrate was used in place of the WAS in thermophilic conditions, but remained approximately similar in mesophilic conditions. The uptake of heavy metals was higher with the microalgal-bacterial substrate in comparison to the WAS, which resulted in higher levels of heavy metals in the digestates. The addition of microalgal-bacterial substrate enhanced the dewaterability in thermophilic conditions. Finally, excess heat can be recovered in both mesophilic and thermophilic conditions.

The Infuence of the Depth of the Secondary Sedimentation Tanks on the Sedimentation Efficiency at Bromma Sewage Treatment Plant

1988 ◽  
Vol 20 (4-5) ◽  
pp. 143-152 ◽  
Author(s):  
M. Tendaj-Xavier ◽  
J. Hultgren
Keyword(s):  
Activated Sludge ◽  
Suspended Solids ◽  
Ferrous Sulphate ◽  
Sewage Treatment ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Design Flow ◽  
Activated Sludge Process ◽  
Solids Concentration ◽  
Rapid Flow

Bromma sewage treatment plant is the second largest plant in Stockholm with a design flow of 160,000 m3/d. The wastewater is treated mechanically, chemically by pre-precipitation with ferrous sulphate, and biologically by the activated sludge process. The requirements for the plant are 8 mg BOD7/l, 0.4 mg P/l and 2 mg NH4+-N/l. The requirement for ammonia refers to the period July-October. In order to meet those rather stringent requirements, the biological step was expanded 3 years ago with 6 new sedimentation tanks. The 6 new tanks have the same area as the 6 old ones but they have only a depth of 3.7 m compared with the depth of the old tanks, 5.7 m. Experience from the first years of operation of the new tanks is that these tanks are more sensitive and less efficient than the older ones. It seems that the effluent suspended solids concentration from the old tanks is less influenced by rapid flow variations than the concentration in the effluent from the new secondary sedimentation tanks. During the nitrification period denitrification takes place to some degree in the secondary sedimentation tanks. This may cause loss of solids and it has been observed that the deeper old tanks usually produce an effluent of better quality and seem to be less influenced by denitrification than the new ones.

Performance of membrane bioreactor combined with pre-coagulation/sedimentation

2004 ◽  
Vol 4 (1) ◽  
pp. 143-149 ◽  
Author(s):  
T. Itonaga ◽  
Y. Watanabe
Keyword(s):  
Membrane Fouling ◽  
Membrane Bioreactor ◽  
Suspended Solids ◽  
Extracellular Polymeric Substances ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Municipal Wastewater Treatment ◽  
Term Operation ◽  
Made In

This paper deals with the performance of a hybrid membrane bioreactor (MBR) combined with pre-coagulation/sedimentation. Primary clarifier effluent in a municipal wastewater treatment plant was fed into the hybrid MBR to investigate its performance during long-term operation. Pre-coagulation/sedimentation process efficiently removed the suspended solids including organic matter and phosphorus. Comparison of the hybrid MBR and conventional MBR was made in terms of the permeate quality and membrane fouling. As the organic loading to the MBR was significantly reduced by the pre-coagulation/sedimentation, production and accumulation of extracellular polymeric substances (EPS) may be limited. Therefore, the mixed liquor viscosity in the hybrid MBR was much lower than that in the conventional MBR. These effect caused by pre-coagulation/sedimentation brought a remarkable improvement in both permeate quality and membrane permeability.

Removal Efficiency of Environmental Endocrine Disrupting Chemicals Pollutants-Phthalate Esters in Northern WWTP

2013 ◽  
Vol 807-809 ◽  
pp. 694-698
Author(s):  
Rong Xin Huang ◽  
Zhen Xing Wang ◽  
Gang Liu ◽  
Qi Jin Luo
Keyword(s):  
Activated Sludge ◽  
Removal Efficiency ◽  
Municipal Wastewater ◽  
Removal Rate ◽  
Phthalate Esters ◽  
Endocrine Disrupting Chemicals ◽  
Treatment Plant ◽  
Activated Sludge Process ◽  
Wastewater Reclamation ◽  
Conventional Activated Sludge

In order to guarantee the reliability and security of reclaiming water, research on the removal efficiency of the environmental endocrine chemicals (EDCs) --the Phthalate Esters (PAEs) in conventional secondary activated sludge and wastewater reclamation and reuse process was undergoing at Harbin wastewater treatment plant (WWTP). The wastewater samples were colleted from every unit effluent of WWTP. The results showed that contamination of EDCs were presented in municipal wastewater at Harbin and the concentrations of the four PAEs were 21.01μg/L for Di-n-butyl Phthalate (DBP); 9.63μg/L for Di-n-octyl Phthalate (DnOP); 4.56μg/L for Diethyl Phthalate (DEP); 1.96μg/L for Dimethyl Phthalate (DMP) respectively in the influent. The conventional activated sludge has good removal efficiencies performance on DMP, DEP and DBP. With the increasing of molecular weight and branch chains of PAEs contaminations, the removal rate of the four PAEs in the conventional activated sludge process decreased from 99.82%(DMP)，90.60%(DEP)，90.10%(DBP) to the only 45.13% removal rate for DnOP, which was mostly removed from primary treatment but no from secondary activated sludge process; Coagulation-air flotation plus filtration process was not a feasible way to remove PAEs from reclaiming treatment units.

Pengambilan senyawa polisakarida ekstraseluler dari mikroorganisme dalam lumpur aktif sebagai adsorben logam berat

2018 ◽  
Vol 5 (2) ◽  
pp. 453
Author(s):  
H Haryono ◽  
Tjandra Setiadi
Keyword(s):  
Heavy Metal ◽  
Activated Sludge ◽  
Extraction Method ◽  
Extracellular Polymeric Substances ◽  
Research Result ◽  
Freundlich Isotherm ◽  
Extraction Methods ◽  
Average Maximum ◽  
Heavy Metal Adsorbent ◽  
Main Component

Extracellular polysaccaride extraction from activated sludge microorganism as heavy-metal adsorbent. Microorganisms in the form of bioagregate are the main component of activated sludge. It generally has an ability to produce EPS (extracellular polymeric substances). The important components in EPS are polysaccharides and proteins. EPS recovery from the activated sludge may be done by many extraction methods. Six of the extraction methods to extract EPS from the activated sludge have been studied in this research, such are: Middle Speed Centrifugation, Regular Centrifugation, NaOH Extraction, EDTA Extraction, Steaming Extraction and Sonication. EPS solution in the following step would be tested its performances as adsorbent of copper heavy metal. The research result shows that the best extraction method for EPS extraction was NaOH Extraction method. The amount of the polysaccharides obtained was 18,09 mg EPS/g TSS. On other hand, Steaming Extraction was the most ineffective extraction method. This method gives the polysaccharides result in the least amount, i.e., about 4,96 mg EPS/g TSS. In this research, the protein content was not detected in the all used EPS solution. In the adsorption test, the adsorption phenomena of copper metal with EPS adsorbent fitted to the Freundlich isotherm adsorption equation. The values of Freundlich's a constant (k and n) each were 2,282 and 0,963. The average maximum adsmption capaciry of EPS to metal Cu was 88,34 mg Cu/gEPS.Keywords:  Adsorption,  Heavy  Metal,  Activated  Sludge,  Extraction Methods, Polysaccharides Extracellular, Copper.AbstrakMikroorganisme dalam bentuk bioagregat adalah merupakan penyusun utama lumpur aktif, memiliki sifat  umum  yaitu  dalam  kemampuannya memproduksi  SPE (Senyawa  Polimer  Ekstraselluler). Komponen  utama dari SPE adalah polisakarida  dan protein. Pengambilan SPE dari bioagregat dapat dilakukan dengan banyak metode ekstraksi.Pada penelitian ini telah dipelajari karakteristik enam  metode  ekstraksi, yaitu: Sentrifugasi Kecepatan Sedang, Sentrifugasi Reguler, Ekstraksi dengan NaOH. Ekstraksi dengan EDTA, Ekstraksi dengan Pemanasan dan Sonikasi. Larutan SPE yang diperoleh, kemudian diuji kinerjanya sebagai adsorben logam berat tembaga. Hasil penelitian menunjukkan bahwa  metode ekstraksi terbaik adalah metode Ekstraksi dengan NaOH, dengan perolehan polisakarida sebesar 18,09 mg/g TSS. Sedangkan Ekstraksi dengan pemanasan merupakan metode ekstraksi yang paling tidak efektif dengan perolehan polisakarida paling sedikit, yaitu sekitar 4,96 mg/g TSS. Pada penelitian ini tidak dijumpai adanya protein di dalam larutan SPE dari semua  metode ekstraksi yang diterapkan. Pada uji adsorpsi, peristiwa adsorpsi logam  Cu dengan larutan SPE lebih mengikuti persamaan adsorpsi isoterm Freundlich dengan harga konstanta k dan n masing-masing sebesar 2,282 dan 0,963. Kapasitas adsorpsi maksimum rata-rata SPE terhadap logam Cu adalah sebesar 88,34 mg Cu/g SPE.Kata kunci:  Adsorpsi, Logam Berat, Lumpur Aktif, Metode Ekstraksi, Polisakarida Ekstraselluler, Tembaga.

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