Advances in activated carbon modification, surface heteroatom configuration, reactor strategies, and regeneration methods for enhanced wastewater treatment

2021 ◽  
pp. 105626
Author(s):  
Diego Ramón Lobato-Peralta ◽  
Estefanía Duque-Brito ◽  
Alejandro Ayala-Cortés ◽  
Arias Dulce María ◽  
Adriana Longoria ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Carbon Modification

New Biology for Advanced Wastewater Treatment

1999 ◽  
Vol 40 (4-5) ◽  
pp. 137-144 ◽  
Author(s):  
K. Miserez ◽  
S. Philips ◽  
W. Verstraete
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Organic Carbon ◽  
Genetically Modified Organisms ◽  
New Technologies ◽  
Chemical Oxidation ◽  
Advanced Treatment ◽  
Biological Activated Carbon ◽  
Catabolic Potential ◽  
New Biology

A number of new technologies for the advanced treatment of wastewater have recently been developed. The oxidative cometabolic transformation by methanotrophs and by nitrifiers represent new approaches in relation to organic carbon. The Biological Activated Carbon Oxidative Filters characterized by thin biofilms are also promising in that respect. Moreover, implementing genetically modified organisms with improved catabolic potential in advanced water treatment comes into perspective. For very refractory effluents chemical support techniques, like e.g. strong chemical oxidation, can be lined up with advanced biology.

scholarly journals Performance of Iron-Functionalized Activated Carbon Catalysts (Fe/AC-f) on CWPO Wastewater Treatment

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 337
Author(s):  
Sara Mesa Medina ◽  
Ana Rey ◽  
Carlos Durán-Valle ◽  
Ana Bahamonde ◽  
Marisol Faraldos
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Landfill Leachate ◽  
Surface Composition ◽  
Treatment Plant ◽  
Reaction Medium ◽  
Pollutant Removal ◽  
Operating Conditions ◽  
Water Matrix ◽  
The Stability

Two commercial activated carbon were functionalized with nitric acid, sulfuric acid, and ethylenediamine to induce the modification of their surface functional groups and facilitate the stability of corresponding AC-supported iron catalysts (Fe/AC-f). Synthetized Fe/AC-f catalysts were characterized to determine bulk and surface composition (elemental analysis, emission spectroscopy, XPS), textural (N2 isotherms), and structural characteristics (XRD). All the Fe/AC-f catalysts were evaluated in the degradation of phenol in ultrapure water matrix by catalytic wet peroxide oxidation (CWPO). Complete pollutant removal at short reaction times (30–60 min) and high TOC reduction (XTOC = 80 % at ≤ 120 min) were always achieved at the conditions tested (500 mg·L−1 catalyst loading, 100 mg·L−1 phenol concentration, stoichiometric H2O2 dose, pH 3, 50 °C and 200 rpm), improving the results found with bare activated carbon supports. The lability of the interactions of iron with functionalized carbon support jeopardizes the stability of some catalysts. This fact could be associated to modifications of the induced surface chemistry after functionalization as a consequence of the iron immobilization procedure. The reusability was demonstrated by four consecutive CWPO cycles where the activity decreased from 1st to 3rd, to become recovered in the 4th run. Fe/AC-f catalysts were applied to treat two real water matrices: the effluent of a wastewater treatment plant with a membrane biological reactor (WWTP-MBR) and a landfill leachate, opening the opportunity to extend the use of these Fe/AC-f catalysts for complex wastewater matrices remediation. The degradation of phenol spiked WWTP-MBR effluent by CWPO using Fe/AC-f catalysts revealed pH of the reaction medium as a critical parameter to obtain complete elimination of the pollutant, only reached at pH 3. On the contrary, significant TOC removal, naturally found in complex landfill leachate, was obtained at natural pH 9 and half stoichiometric H2O2 dose. This highlights the importance of the water matrix in the optimization of the CWPO operating conditions.

scholarly journals Oxytetracycline Adsorption from Aqueous Solutions on Commercial and High-Temperature Modified Activated Carbons

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3481
Author(s):  
Joanna Lach ◽  
Agnieszka Ociepa-Kubicka ◽  
Maciej Mrowiec
Keyword(s):  
Activated Carbon ◽  
Aqueous Solutions ◽  
Activated Carbons ◽  
Electricity Consumption ◽  
Solution Ph ◽  
Carbon Modification ◽  
Modification Method ◽  
Flow Through ◽  
Proposed Modification ◽  
Modified Activated Carbons

The aim of the work was to evaluate the possibility of using commercial and modified activated carbons for the removal of oxytetracycline from aqueous solutions. The kinetics and statics of adsorption as well as the effect of the activated carbon dose and solution pH on the efficiency of the oxytetracycline adsorption were analyzed. Based on the study of oxytetracycline adsorption isotherms, the activated carbons were ranked in the following order: F-300 > WG-12 > Picabiol > ROW08 > WACC 8 × 30 > F-100 > WAZ 0.6–2.4. The most effective activated carbons were characterized by large specific surfaces. The best matching results were obtained for: Redlich–Peterson, Thot and Jovanovic models, and lower for the most frequently used Freundlich and Langmuir models. The adsorption proceeded better from solutions with pH = 6 than with pH = 3 and 10. Two ways of modifying activated carbon were also assessed. A proprietary method of activated carbon modification was proposed. It uses the heating of activated carbon as a result of current flow through its bed. Both carbons modified at 400 °C in the rotary kiln and on the proprietary SEOW (Joule-heat) modification stand enabled to obtain adsorbents with higher and comparable monolayer capacities. The advantage of the proposed modification method is low electricity consumption.

Granular activated carbon (GAC) adsorption in tertiary wastewater treatment: experiments and models

2003 ◽  
Vol 47 (1) ◽  
pp. 113-120 ◽  
Author(s):  
D.S. Chaudhary ◽  
S. Vigneswaran ◽  
V. Jegatheesan ◽  
H.H. Ngo ◽  
H. Moon ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Fixed Bed ◽  
Granular Activated Carbon ◽  
Developed Countries ◽  
Synthetic Wastewater ◽  
Batch Adsorption ◽  
Model Parameters ◽  
Wide Range ◽  
Gac Adsorption

Wastewater treatment has always been a major concern in the developed countries. Over the last few decades, activated carbon adsorption has gained importance as an alternative tertiary wastewater treatment and purification process. In this study, granular activated carbon (GAC) adsorption was evaluated in terms of total organic carbon (TOC) removal from low strength synthetic wastewater. This paper provides details on adsorption experiments conducted on synthetic wastewater to develop suitable adsorption isotherms. Although the inorganics used in the synthetic wastewater solution had an overall unfavourable effect on adsorption of organics, the GAC adsorption system was found to be effective in removing TOC from the wastewater. This study showed that equation of state (EOS) theory was able to fit the adsorption isotherm results more precisely than the most commonly used Freundlich isotherm. Biodegradation of the organics with time was the most crucial and important aspect of the system and it was taken into account in determining the isotherm parameters. Initial organic concentration of the wastewater was the determining factor of the model parameters, and hence the isotherm parameters were determined covering a wide range of initial organic concentrations of the wastewater. As such, the isotherm parameters derived using the EOS theory could predict the batch adsorption and fixed bed adsorption results of the multi-component system successfully. The isotherm parameters showed a significant effect on the determination of the mass transfer coefficients in batch and fixed bed systems.

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