The adsorption of As(V) on poorly crystalline Fe oxyhydroxides, revisited: effect of the reaction media and the drying treatment

2021 ◽  
pp. 125863
Author(s):  
Danni Zhang ◽  
Rui Cao ◽  
Ying Wang ◽  
Shaofeng Wang ◽  
Yongfeng Jia
Keyword(s):  
Drying Treatment ◽  
Fe Oxyhydroxides ◽  
Reaction Media

Dimensionally-Controlled Hydrothermal Tm3+-doped Oxidic Nanocrystals and Their Photoluminescence Properties

2010 ◽  
Vol 1247 ◽  
Author(s):  
Rocío Calderón-Villajos ◽  
Carlos Zaldo ◽  
Concepción Cascales
Keyword(s):  
Single Crystals ◽  
Fluorescence Lifetimes ◽  
Photoluminescence Properties ◽  
Reaction Conditions ◽  
Hydrothermal Processes ◽  
Bulk Single Crystals ◽  
Template Free ◽  
Reaction Media

AbstractControlled reaction conditions in simple, template-free hydrothermal processes yield Tm-Lu2O3 and Tm-GdVO4 nanocrystals with well-defined specific morphologies and sizes. In both oxide families, nanocrystals prepared at pH 7 reaction media exhibit photoluminescence in ∼1.95 μm similar to bulk single crystals. For the lowest Tm3+ concentration (0.2 % mol) in GdVO4 measured 3H4 and 3F4 fluorescence lifetimes τ are very near to τrad.

Naturally Occurring Organic Acid-catalyzed Facile Diastereoselective Synthesis of Biologically Active (E)-3-(arylimino)indolin-2-one Derivatives in Water at Room Temperature

2019 ◽  
Vol 23 (16) ◽  
pp. 1778-1788 ◽  
Author(s):  
Gurpreet Kaur ◽  
Arvind Singh ◽  
Kiran Bala ◽  
Mamta Devi ◽  
Anjana Kumari ◽  
...  
Keyword(s):  
Room Temperature ◽  
Biologically Active ◽  
Environmentally Benign ◽  
Diastereoselective Synthesis ◽  
Substituted Anilines ◽  
Reaction Conditions ◽  
Naturally Occurring ◽  
Acid Catalyzed ◽  
Reaction Media ◽  
Column Chromatographic

A simple, straightforward and efficient method has been developed for the synthesis of (E)-3-(arylimino)indolin-2-one derivatives and (E)-2-((4-methoxyphenyl)imino)- acenaphthylen-1(2H)-one. The synthesis of these biologically-significant scaffolds was achieved from the reactions of various substituted anilines and isatins or acenaphthaquinone, respectively, using commercially available, environmentally benign and naturally occurring organic acids such as mandelic acid or itaconic acid as catalyst in aqueous medium at room temperature. Mild reaction conditions, energy efficiency, good to excellent yields, environmentally benign conditions, easy isolation of products, no need of column chromatographic separation and the reusability of reaction media are some of the significant features of the present protocol.

Synthesis, Characterization and Applications of Dicationic Ionic Liquids in Organic Synthesis

2020 ◽  
Vol 17 (4) ◽  
pp. 450-464
Author(s):  
Mohammad Javaherian ◽  
Seyyed Jafar Saghanezhad
Keyword(s):  
Ionic Liquids ◽  
Organic Synthesis ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Dicationic Ionic Liquids ◽  
Physical And Chemical ◽  
Reaction Media ◽  
And Chemical Properties

Dicationic ionic liquids are an emerging group of Ionic Liquids (ILs) that are currently receiving much attention as green reaction media and catalysts. Because of a great number of possible combinations of cations and anions, the physical and chemical properties of dicationic ionic liquids are more tunable and broader than monocationic ILs. Therefore, their unique properties have made them the target of many applied and fundamental researches. Actually, dicationic ionic liquids are more effective and rather fascinating than traditional monocationic ILs. So, due to greater versatility and diversity, their applications in organic synthesis have been extensively grown. In this review, we have focused on the synthesis, characterization and applications of dicationic ionic liquids, especially, in organic synthesis.

scholarly journals Effect of reaction media on the scavenging reaction of water-solubilized 2,2-diphenyl-1-picrylhydrazy radical by ascorbic acid

2021 ◽  
Vol 165 ◽  
pp. 55-56
Author(s):  
Ikuo Nakanishi ◽  
Yoshimi Shoji ◽  
Kei Ohkubo ◽  
Toshihiko Ozawa ◽  
Ken-ichiro Matsumoto ◽  
...  
Keyword(s):  
Ascorbic Acid ◽  
Reaction Media

Sustainable synthesis of AFe2O4 (A= Mg, Zn, Mn) catalysts: comparing the photooxidative and electrochemical properties towards organic dyes detection and degradation

2021 ◽  
Author(s):  
Jeena N. Baby ◽  
Lavanya Chandrasekar ◽  
Sea-Fue Wang ◽  
Sriram Balasubramanian ◽  
Ashwini Anantharaman ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Organic Dyes ◽  
Energy Requirements ◽  
Green Solvents ◽  
Reaction Media

By serving as alternatives to toxic and hazardous solvents, green solvents assist in implementing the idea of sustainability. The use of these neoeric reaction media dramatically reduces energy requirements and...

scholarly journals Effect of spray drying treatment on the optical properties of Mg–Al spinel ceramics

Open Ceramics ◽  
2021 ◽  
Vol 6 ◽  
pp. 100102
Author(s):  
Robin Stocky ◽  
Judith Boehmler ◽  
Sébastien Lemonnier ◽  
Pierre Gibot ◽  
Yannick Lorgouilloux ◽  
...  
Keyword(s):  
Optical Properties ◽  
Spray Drying ◽  
Drying Treatment

scholarly journals Biocatalytic Transformation of 5-Hydroxymethylfurfural into 2,5-di(hydroxymethyl)furan by a Newly Isolated Fusarium striatum Strain

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 216
Author(s):  
Alberto Millán ◽  
Núria Sala ◽  
Mercè Torres ◽  
Ramon Canela-Garayoa
Keyword(s):  
Fusarium Species ◽  
Inoculum Size ◽  
High Recovery ◽  
23 Factorial Design ◽  
Organic Solvent Extraction ◽  
Working Volume ◽  
The Media ◽  
Substrate Feeding ◽  
High Concentrations ◽  
Reaction Media

The compound 2,5-di(hydroxymethyl)furan (DHMF) is a high-value chemical block that can be synthesized from 5-hydroxymethylfurfural (HMF), a platform chemical that results from the dehydration of biomass-derived carbohydrates. In this work, the HMF biotransformation capability of different Fusarium species was evaluated, and F. striatum was selected to produce DHMF. The effects of the inoculum size, glucose concentration and pH of the media over DHMF production were evaluated by a 23 factorial design. A substrate feeding approach was found suitable to overcome the toxicity effect of HMF towards the cells when added at high concentrations (>75 mM). The process was successfully scaled-up at bioreactor scale (1.3 L working volume) with excellent DHMF production yields (95%) and selectivity (98%). DHMF was purified from the reaction media with high recovery and purity by organic solvent extraction with ethyl acetate.

scholarly journals Sprouting of Sorghum (Sorghum bicolor [L.] Moench): Effect of Drying Treatment on Protein and Starch Features

Foods ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 407 ◽  
Author(s):  
Mia Marchini ◽  
Alessandra Marti ◽  
Claudia Folli ◽  
Barbara Prandi ◽  
Tommaso Ganino ◽  
...  
Keyword(s):  
Food Production ◽  
Cost Effective ◽  
High Exposure ◽  
Effective Technology ◽  
Drying Treatment ◽  
Higher Temperature ◽  
Lower Temperature ◽  
The One ◽  
Drying Conditions ◽  
Sorghum Bicolor L

The nutritional and physicochemical properties of sorghum proteins and starch make the use of this cereal for food production challenging. Sprouting is a cost-effective technology to improve the nutritional and functional profile of grains. Two drying treatments were used after sorghum sprouting to investigate whether the drying phase could improve the protein and starch functionalities. Results showed that the drying treatment at lower temperature/longer time (40 °C for 12 h) extended the enzymatic activity that started during sprouting compared to the one performed at higher temperature/shorter time (50 °C for 6 h). An increased protein hydrolysis and water- and oil-holding capacity were found in the flour obtained by the former treatment. Higher protein matrix hydrolysis caused high exposure of starch to enzymes, thus increasing its digestibility, while worsening the technological functionality. Overall, modulating drying conditions could represent a further way, in addition to sprouting, to improve sorghum flour’s nutritional profile.

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