Identification of the threshold stress and true activation energy for characterizing the deformation mechanisms during hot working

2017 ◽  
Vol 113 ◽  
pp. 27-36 ◽  
Author(s):  
S. Wang ◽  
J.R. Luo ◽  
L.G. Hou ◽  
J.S. Zhang ◽  
L.Z. Zhuang
Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 581
Author(s):  
Abdulhakim A. Almajid

This study is focused on the deformation mechanism and behavior of naturally aged 7010 aluminum alloy at elevated temperatures. The specimens were naturally aged for 60 days to reach a saturated hardness state. High-temperature tensile tests for the naturally aged sample were conducted at different temperatures of 573, 623, 673, and 723 K at various strain rates ranging from 5 × 10−5 to 10−2 s−1. The dependency of stress on the strain rate showed a stress exponent, n, of ~6.5 for the low two temperatures and ~4.5 for the high two temperatures. The apparent activation energies of 290 and 165 kJ/mol are observed at the low, and high-temperature range, respectively. These values of activation energies are greater than those of solute/solvent self-diffusion. The stress exponents, n, and activation energy observed are rather high and this indicates the presence of threshold stress. This behavior occurred as a result of the dislocation interaction with the second phase particles that are existed in the alloy at the testing temperatures. The threshold stress decreases in an exponential manner as temperature increases. The true activation energy was computed by incorporating the threshold stress in the power-law relation between the stress and the strain. The magnitude of the true activation energy, Qt dropped to 234 and 102 kJ/mol at the low and high-temperature range, respectively. These values are close to that of diffusion of Zinc in Aluminum and diffusion of Magnesium in Aluminum, respectively. The Zener–Hollomon parameter for the alloy was developed as a function of effective stress. The data in each region (low and high-temperature region) coalescence in a segment line in each region.


Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4071
Author(s):  
Yongtao Zhang ◽  
Peng Luo ◽  
Longjiang Niu ◽  
Zhanpeng Lu ◽  
Haitao Yan ◽  
...  

High-temperature plastic flow of heat-resistant 2.25Cr-1Mo-0.25V steel was investigated by hot tension (at 500–650 °C) on a Gleeble 3800 machine. The strain rate of hot tension was set as 0.001–1 s−1. The constitutive relation of the steel was modeled by the introduction of the parameters termed “true activation energy” and “threshold stress”. Then, the kinetics of high-temperature plastic flow was analyzed based on an Arrhenius equation modified by a “threshold stress”. The stress exponent of the modified equation was equal to 5. True activation energy was estimated to be 132 kJ·mol−1. According to the slip band model, the basic mechanism behind the hot deformation of the steel was considered to be dislocation climbing, which was governed by grain boundary diffusion. This model proved to be successful in its analysis of the experimental results of hot tension tests.


JOM ◽  
1968 ◽  
Vol 20 (4) ◽  
pp. 31-38 ◽  
Author(s):  
H. J. McQueen

1956 ◽  
Vol 34 (4) ◽  
pp. 489-501 ◽  
Author(s):  
M. W. Lister

The reaction between sodium hypochlorite and potassium cyanate in the presence of sodium hydroxide has been examined. The main products are chloride, and carbonate ions and nitrogen; but, especially if much hypochlorite is present, some nitrate is formed as well. The rate of reaction is proportional to the cyanate and hypochlorite concentrations, but inversely proportional to the hydroxide concentration: the rate constant is 5.45 × 10−4 min.−1 at 65 °C, at an ionic strength of 2.2. The rate constant increases somewhat as the ionic strength rises from 1.7 to 3.5. The effect of temperature makes the apparent activation energy 25 kcal./gm-molecule. The kinetics of the reaction suggest that the slow step is really a reaction of hypochlorous acid and cyanate ions, and possible intermediate products of this reaction are suggested. Allowing for the different extent of hydrolysis of hypochlorite at different temperatures, the true activation energy is found to be 15 kcal./gm-mol., which is consistent with the observed rate of reaction.


1998 ◽  
Vol 516 ◽  
Author(s):  
O. Kraft ◽  
W.D. Nix

AbstractIn this paper, we study the influence of the line width on the mechanical behavior of narrow unpassivated lines of pure Al and Al with 0.5 wt.-% Cu. The stress/temperature behavior during thermal cycling is investigated using x-ray diffractometry. Our results suggest that it is possible to distinguish between two temperature regimes in which different deformation mechanisms take place. At low temperatures, the narrowest lines sustain larger stresses than the continuous films, whereas at high temperatures the opposite behavior was found. Further, iso-thermal stress relaxation measurements on pure Al lines after various heat treatments were performed. These results indicate the existence of a threshold stress below which no deformation of the lines occurs.


Author(s):  
Bálint Boldizsár ◽  
Péter Jenei ◽  
Anwar Q. Ahmed ◽  
Maxim Yu. Murashkin ◽  
Ruslan Z. Valiev ◽  
...  

AbstractLow temperature tensile and impression creep tests were carried out on an ultrafine-grained 7xxx series Al–4.8Zn–1.2 Mg–0.14Zr (wt%) alloy, which can be deformed for maximum elongation of about 200% at 150 °C. The characteristics of the deformation process, such as the strain rate sensitivity (SRS) and activation energy (Q) were determined by considering also the effect of threshold stress. Relatively high SRS of $$\sim$$ ∼ 0.35 and low activation energy of $$\sim$$ ∼ 92 kJ/mole were obtained, confirming the super ductility of the investigated ultrafine-grained alloy in the low temperature region between 140 and 160 °C. Graphical abstract


The rate of increase in strength of absorption bands of SO has been measured in shock-heated mixtures of sulphur dioxide and argon. Arrhenius-type plots indicate a unimolecular first step of the order d [SO]/d t = k [SO 2 ] [ M ], where [SO], [SO 2 ] and [ M ] are concentrations of [SO], [SO 2 ] and total gas. The apparent activation energy at around 3500 °K is 56 kcal/mole. It is shown that on unimolecular reaction theory, if four harmonic modes of oscillation in the SO 2 molecules contribute to the energy available for transformation, the true activation energy is 74 kcal/mole. This agrees with the energy of excitation to a known triplet state of SO 2 , and on this basis it is suggested that the first steps in the decomposition are SO 2 + M = SO* 2 + M — 73.6 kcal/mole (1) and SO* 2 + SO 2 = SO 3 + SO + 25.6 kcal/mole. (2) Step (2) is spin-allowed, whereas the more direct reaction SO 2 + SO 2 = SO 3 + SO —48 kcal/ mole is spin-forbidden. This is an unusual type of decomposition mechanism and occurs because of the high dissociation energy of SO 2 , because the direct step of low-energy is spinforbidden, and because there is a favourably situated triplet state of the molecule.


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