It has been made clear that the EC-PCD composed of boron doped diamond particles improves the performance in the die sinking EDM and wire EDM in comparison with the existing standard PCD (S-PCD). However, the effect of the property improvement could not been evaluated quantitatively in the research reports in the past. Therefore, in this study, wire EDM cutting tests were conducted on the specimens of S-PCD and EC-PCD, in addition to the evaluation of cutting efficiency and cutting PCD surface, a detailed investigation of the cut surface properties of the PCD has been performed under the color 3D laser scanning microscope. In order to investigate effects of a grain size of the source diamond, EDM cutting experiments were conducted on the EC-PCD specimens of 4 different grain sizes. As a result, it was found that the cutting speed was higher in the case of EC-PCD than the case of S-PCD, e.g., by 20% and 40% respectively in the sample of 10μm and 25μm particle size. Also, in the case of the cut S-PCD surface, a groove due to the discharge is formed in the boundary of the tungsten carbide layer and the PCD layer. However, in the case of the cut EC-PCD surface, the groove did not appear in the boundary.