A study of SnAgCu solder paste transfer efficiency and effects of optimal reflow profile on solder deposits

2011 ◽  
Vol 88 (7) ◽  
pp. 1610-1617 ◽  
Author(s):  
E.H. Amalu ◽  
W.K. Lau ◽  
N.N. Ekere ◽  
R.S. Bhatti ◽  
S. Mallik ◽  
...  
Author(s):  
Claire Ryan ◽  
Jeff M. Punch ◽  
Bryan Rodgers ◽  
Greg Heaslip ◽  
Shane O’Neill ◽  
...  

A European Union ban on lead in most electrical and electronic equipment will be imposed as of July 1st 2006. The ban, along with market pressures, means that manufacturers must transfer from a tin-lead soldering process to a lead-free process. In this paper the implications on the surface mount (SMT) soldering process are presented. A set of experiments was conducted to investigate the screen-printing and reflow steps of the SMT process using a tin-silver-copper (95.5Sn3.8Ag0.7Cu) solder and a baseline of standard tin-lead (63Sn37Pb). 10×10 arrays of micro Ball Grid Array (micro-BGA) components mounted on 8-layer FR4 printed wiring boards (PWBs) were used. The screen-printing experiment addressed the deposition of the solder paste on the board. The parameters used in the investigation were print speed, squeegee pressure, snap-off distance, separation speed and cleaning interval, with the responses being measurements of paste height and volume. Optimum screen-printer settings were determined which give adequate paste volume and height and a good print definition. The reflow experiment investigated the following parameters of the temperature profile: preheat, soak, peak and cool down temperatures, and conveyor speed. The resulting solder joints were evaluated using cross-section analysis and x-ray techniques in order to determine the presence of defects. A mechanical fatigue test was also carried out in order to compare the strength of the solder joints. The overall quality of the lead-free solder joints was determined from these tests and compared to that of tin-lead. The outcome is a set of manufacturing guidelines for transferring to lead-free solder including optimum screen-printer and reflow oven settings for use with an SnAgCu solder.


2015 ◽  
Vol 2015 (1) ◽  
pp. 000434-000442
Author(s):  
Fen Chen ◽  
Ning-Cheng Lee

The miniaturization trend is driving industry to adopting low standoff components or components in cavity. The cost reduction pressure is pushing telecommunication industry to combine assembly of components and electromagnetic shield in one single reflow process. As a result, the flux outgassing/drying is getting very difficult for devices due to poor venting channel. This resulted in insufficiently dried/burnt-off flux residue. For a properly formulated flux, the remaining flux activity posed no issue in a dried flux residue for no-clean process. However, when venting channel is blocked, not only solvents remain, but also activators could not be burnt off. The presence of solvents allows mobility of active ingredients and the associated corrosion, thus poses a major threat to the reliability. In this work, a new halogen-free no-clean SnAgCu solder paste, 33-76-1, has been developed. This solder paste exhibited SIR value above the IPC spec 100 MΩ without any dendrite formation, even with a wet flux residue on the comb pattern. The wet flux residue was caused by covering the comb pattern with 10 mm × 10 mm glass slide during reflow and SIR testing in order to mimic the poorly vented low standoff components. Paste 33-76-1 also showed very good SMT assembly performance, including voiding of QFN and HIP resistance. The wetting ability of paste 33-76-1 was very good under nitrogen. For air reflow, 33-76-1 still matched paste C which is widely accepted by industry for air reflow process. The above good performance on both non-corrosion with wet flux residue and robust SMT process can only be accomplished through a breakthrough in flux technology.


2011 ◽  
Vol 2011 (1) ◽  
pp. 000502-000508 ◽  
Author(s):  
Mark Whitmore ◽  
Clive Ashmore

As electronics assemblies continue to shrink in form factor, forcing designers towards smaller components with decreasing pitches, the Surface Mount assembly process is becoming increasingly challenged. A new “active” squeegee printing process has been developed to assist in the stencil printing of solder pastes for next generation ultra fine pitch components such as 0.3mm pitch CSP’s. Results indicate that today’s accepted stencil area ratio rules, which govern solder paste transfer efficiency can be significantly pushed to extend stencil printing process capabilities to stencil apertures having area ratios as low as 0.4. Such a breakthrough will allow the printing of ultra fine pitch components and additionally will assist with heterogeneous assembly concerns, to satisfy up and coming mixed technology demands.


Author(s):  
B. Arfaei ◽  
L. Wentlent ◽  
S. Joshi ◽  
M. Anselm ◽  
P. Borgesen

We have recently demonstrated a significantly longer life in accelerated thermal cycling for Land Grid Arrays (LGAs) assembled only with SAC305 solder paste than for the corresponding SAC305 based BGA assemblies. This superior performance was shown to be a direct effect of the solder microstructure. The final Sn solidification temperature strongly affects the initial microstructure of a SnAgCu solder joint, including the Sn grain morphology, and thus the thermomechanical behavior of the joint. Right after reflow, larger BGA joints of SnAgCu alloys, which solidify at higher temperature, reveal either a single β-Sn grain or three large grains with clearly defined boundaries formed by cyclic twinning. The orientations of the highly anisotropic Sn grains are not yet controllable in manufacturing, leading to substantial statistical scatter in the performance of the solder joints. Typical LGA solder joint dimensions, however, tend to facilitate greater undercooling and the formation of an alternative interlaced twinning microstructure. A systematic study was undertaken to identify the parameters that control the interlaced twinning microstructure. Sn grain structures were characterized by crossed polarizer microscopy and electron backscatter diffraction (EBSD). Precipitate sizes and distributions were measured using backscattered scanning electron microscopy and quantified using image analysis software. Systematic effects of solder alloy, dimensions and pad finishes were identified. Recommendations are made as to design and materials selection. The practicality of controlling the desired microstructure, as well as potential disadvantages for certain applications is discussed.


2004 ◽  
Vol 19 (11) ◽  
pp. 3214-3223 ◽  
Author(s):  
T.T. Mattila ◽  
V. Vuorinen ◽  
J.K. Kivilahti

When lead-free solder alloys mix with lead-free component and board metallizations during reflow soldering, the solder interconnections become multicomponent alloy systems whose microstructures cannot be predicted on the basis of the SnPb metallurgy. To better understand the influences of these microstructures on the reliability of lead-free electronics assemblies, SnAgCu-bumped components were reflow-soldered with near-eutectic SnAgCu solder pastes on Ni(P)|m.Au- and organic solderability preservative (OSP)-coated printed wiring boards and tested under cyclic thermal shock loading conditions. The reliability performance under thermomechanical loading was found to be controlled by the kinetics of recrystallization. Because ductile fracturing of the as-soldered tin-rich colonies would require a great amount of plastic work, the formation of continuous network of grain boundaries by recrystallization is needed for cracks to nucleate and propagate intergranularly through the solder interconnections. Detailed microstructural observations revealed that cracks nucleate and grow along the grain boundaries especially between the recrystallized part and the non-recrystallized part of the interconnections. The thermal cycling test data were analyzed statistically by combining the Weibull statistics and the analysis of variance. The interconnections on Ni(P)|m.Au were found out to be more reliable than those on Cu|m.OSP. This is due to the extensive dissolution of Cu conductor, in the case of the Cu|m.OSP assemblies, into molten solder that makes the microstructure to differ noticeably from that of the Ni(P)|m.Au interconnections. Because of large primary Cu6Sn5 particles, the Cu-enriched interconnections enhance the onset of recrystallization, and cracking of the interconnections is therefore faster. The solder paste composition had no statistically significant effect on the reliability performance.


Author(s):  
Sami T. Nurmi ◽  
Janne J. Sundelin ◽  
Eero O. Ristolainen ◽  
Toivo K. Lepisto¨

As environmental issues are raising more interest and are becoming crucial factors in all parts of the world, more and more environmental-friendly electronics products are emerging. Usually this means the introduction of products with lead-free solders. However, the reliability of lead-free solders is still a serious concern despite the vast research done in this field. This paper will describe the interconnect reliability of three kinds of solder joints respectively prepared with lead-free solder paste and lead-free PBGA components, lead-free solder paste and tin-lead-silver PBGA components, and tin-lead solder paste and tin-lead-silver PBGA components. Lead-free and tin-lead solders were composed of eutectic tin-silver-copper and tin-lead, respectively. In addition, the study also presents the effect of multiple reflow times. The study focuses on the microstructures of different assemblies. The particular interest is on the assemblies soldered with lead-free solder paste and tin-lead-silver PBGA components, since the SnPbAg solder on the bumps of the PBGA components were exposed to the reflow profile meant for the lead-free SnAgCu solder. Thus, these SnPbAg solder bumps were in the molten state almost twice as long as the rest of the solders. This had a notable effect on the reliability of these solder joints as we will be showing later in this paper. The test boards were temperature-cycled for 2500 cycles between −40 and +125°C (a 30-minute cycle). PBGA solder joint failures were monitored with a real time monitoring system. Optical and scanning electron microscopy was used to inspect the broken solder joints and their microstructure. The results of tests indicate that the number of reflow times can significantly affect the lifetime of PBGA solder joints. The most notable changes can be seen in the solder joints made with tin-lead-silver PBGA components and tin-silver-copper solder paste soldered with a lead-free reflow profile. The general trend was that the reliability of the solder joints increased in proportion to the number of reflow times. Mainly two factors are believed to have the major effect on the reliability of PBGA solder joints, voids, and microstructural changes in solder.


2021 ◽  
Vol 904 ◽  
pp. 369-374
Author(s):  
Mamart Wikatsama ◽  
Nuttakrit Somdock ◽  
Chantira Boonsri ◽  
Suwan Plaipichit ◽  
Prathan Buranasiri ◽  
...  

In this research we investigated the contact angle of commercial SnAgCu solder paste mixing with some carbon allotropes such as graphite, graphene quantum dots, and fullerene of varying concentrations with melting temperature, wettability, interfacial microstructure. The wettability was assessed in terms of the contact angle. The in-line digital holography was used for determining the contact angle and morphological of samples at each temperature which the samples have been heating from room temperature until the melting temperature. In the experiment, only one beam was used as the object and reference beams which recorded by a CMOS camera. The recorded image was reconstructed by the angular spectrum digital holography numerical programing. Using the reconstructed images of our results, the shape and contact angle of solder pastes can be investigated.


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