In-process assessment of clay dispersion in PLA during melt compounding: Effects of screw speed and filler content

2020 ◽  
Vol 177 ◽  
pp. 109190
Author(s):  
P.F. Teixeira ◽  
J.A. Covas ◽  
L. Hilliou
2021 ◽  
Vol 32 (3) ◽  
pp. 31-44
Author(s):  
Dylan Jia Yee Tong ◽  
◽  
Seong Chun Koay ◽  
Ming Yeng Chan ◽  
Kim Yeow Tshai ◽  
...  

Electric Discharge Machining (EDM) process uses electrodes made from graphite that wear out over time and are turned into scrap. In this research, EDM electrode scraps were recycled and turned into graphite powder (rGP). This rGP was used as a conductive filler to produce conductive polymer composite (CPC) material by combining it with polypropylene (PP) resin via melt compounding and compression moulding processes. The percolation threshold of this composite material changed when 30 wt% of rGP was added, whereby the insulative material changed became antistatic. The composite was able to achieve surface resistivity as low as 105 ohm/sq. However, the addition of higher rGP content deteriorated the tensile properties of composite, whereby the tensile strength of composite significantly decreased as compared to neat PP. The results also showed that the tensile modulus of this composite became higher, and the material became more brittle as compared to neat PP. However, the PP/rGP composite with 50 wt% filler content reduced the tensile modulus due to plasticising effect caused by the agglomeration of rGP. The addition of high filler content on PP/rGP composite also caused an increase in processing torque. This was due to the restriction of rGP particles to the melt flow of molten PP. The morphological analysis found that the PP/rGP composites with higher amounts of filler content were highly agglomerated and formed conductivity paths within the PP matrix. The increase of rGP content highly improved the thermal stability of composite. The findings of this study show that the rGP has the potential to be used as a conductive filler for producing conductive composite material.


2018 ◽  
Vol 39 (1) ◽  
pp. 25-34 ◽  
Author(s):  
Mohamed Sahnoune ◽  
Mustapha Kaci ◽  
Aurélie Taguet ◽  
Karl Delbé ◽  
Samir Mouffok ◽  
...  

AbstractThis article reports some morphological, tribological, and mechanical data on polyamide-11(PA11)/halloysite nanotube (HNT) nanocomposites prepared by melt-compounding. HNTs extracted from the Djebel Debbagh deposit in Algeria were incorporated into the polymer at 1, 3, and 5 wt%. For comparison, commercial HNTs were also used under the same processing conditions. Scanning electron microscopy showed that both HNTs were homogeneously dispersed in the PA11 matrix, despite the presence of few aggregates, in particular at higher filler contents. The tribological properties were significantly improved, resulting in a decrease in the friction coefficient and the wear rate characteristics due to the lubricating effect of HNTs. This is consistent with optical profilometry data, which evidenced the impact of both types of HNTs on the surface topography of the nanocomposite samples, in which the main wear process was plastic deformation. Furthermore, Young’s modulus and tensile strength were observed to increase with the filler content, but to the detriment of elongation at break and impact strength. Regarding the whole data, the raw Algerian halloysite led to interesting results in PA11 nanocomposites, thus revealing its potential in polymer engineering nanotechnology.


2019 ◽  
Vol 13 (3) ◽  
pp. 276-285 ◽  
Author(s):  
P. F. Teixeira ◽  
F. Sutera ◽  
R. Scaffaro ◽  
J. A. Covas ◽  
L. Hilliou

TAPPI Journal ◽  
2010 ◽  
Vol 9 (4) ◽  
pp. 31-36 ◽  
Author(s):  
YULIN DENG ◽  
PHIL JONES ◽  
LESLIE MCLAIN ◽  
ART J. RAGAUSKAS

High-filler-content paper is a growing research and development opportunity in papermaking. These new products must address traditional paper product properties while providing papermakers with distinct product platform benefits. Over the past decade, a research team involving researchers from the Institute of Paper Science and Technology at Georgia Institute of Technology and from Imerys have significantly advanced the application of starch-encapsulated papermaking fillers. This review summarizes these accomplishments from initial laboratory studies to mill trials. Laboratory results have illustrated that starch-encapsulated fillers can facilitate a near-doubling of filler content over conventional levels at equal tensile and z-direction tensile (ZDT) values. Equally important is that the use of starch-encapsulated kaolin (SEK) filler has been shown to facilitate a doubling of filler addition rate without any detrimental impact on ring crush compared with control studies with filler. Pilot-plant and mill trials have shown that SEK can function as a fiber extender, reduce steam demand for drying by 10%, and increase papermaking speeds and production rates.


2017 ◽  
Vol 32 (4) ◽  
pp. 446-454
Author(s):  
A. Mostafa ◽  
G. Pacher ◽  
T. Lucyshyn ◽  
C. Holzer ◽  
E. Krischey ◽  
...  

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