scholarly journals Tribological and mechanical properties of polyamide-11/halloysite nanotube nanocomposites

2018 ◽  
Vol 39 (1) ◽  
pp. 25-34 ◽  
Author(s):  
Mohamed Sahnoune ◽  
Mustapha Kaci ◽  
Aurélie Taguet ◽  
Karl Delbé ◽  
Samir Mouffok ◽  
...  
Keyword(s):  
Filler Content ◽  
Processing Conditions ◽  
Optical Profilometry ◽  
Halloysite Nanotube ◽  
Elongation At Break ◽  
Polyamide 11 ◽  
Wear Process ◽  
Melt Compounding ◽  
The Impact ◽  
Scanning Electron

AbstractThis article reports some morphological, tribological, and mechanical data on polyamide-11(PA11)/halloysite nanotube (HNT) nanocomposites prepared by melt-compounding. HNTs extracted from the Djebel Debbagh deposit in Algeria were incorporated into the polymer at 1, 3, and 5 wt%. For comparison, commercial HNTs were also used under the same processing conditions. Scanning electron microscopy showed that both HNTs were homogeneously dispersed in the PA11 matrix, despite the presence of few aggregates, in particular at higher filler contents. The tribological properties were significantly improved, resulting in a decrease in the friction coefficient and the wear rate characteristics due to the lubricating effect of HNTs. This is consistent with optical profilometry data, which evidenced the impact of both types of HNTs on the surface topography of the nanocomposite samples, in which the main wear process was plastic deformation. Furthermore, Young’s modulus and tensile strength were observed to increase with the filler content, but to the detriment of elongation at break and impact strength. Regarding the whole data, the raw Algerian halloysite led to interesting results in PA11 nanocomposites, thus revealing its potential in polymer engineering nanotechnology.

Morphological, mechanical, and thermal properties of PP/SEBS/talc composites

2019 ◽  
pp. 089270571987667 ◽  
Author(s):  
Carlos Ivan Ribeiro de Oliveira ◽  
Marisa Cristina Guimarães Rocha ◽  
Joaquim Teixeira de Assis ◽  
Ana Lúcia Nazareth da Silva
Keyword(s):  
Thermal Properties ◽  
Impact Resistance ◽  
Mechanical And Thermal Properties ◽  
Processing Conditions ◽  
Screw Extruder ◽  
Crystallinity Degree ◽  
Twin Screw ◽  
The Impact ◽  
Scanning Electron ◽  
Nucleating Effect

The aim of this study is to evaluate the effect of some experimental variables such as the content of styrene–ethylene–butylene–styrene (SEBS) and talc, processing conditions and mixing protocol on the properties of polypropylene (PP). To achieve this objective, PP/SEBS blends and PP/SEBS/talc composites were processed in a corotating twin-screw extruder. A masterbatch of PP/talc was prepared before the extrusion of PP/SEBS/talc composites. The morphology of blends and composites was evaluated by scanning electron microscopy, which revealed the dispersion of small rubber droplets in the PP matrix. Moreover, the micrographs also showed that SEBS and talc particles were uniformly dispersed and distributed in the polymer matrix. Results of thermal properties showed that talc had a nucleating effect, which promoted the increase of both PP crystallization temperature and crystallinity degree. The incorporation of talc in PP/SEBS blends led to an expressive increase in the impact resistance by 70% as compared with the reference blend: PP/SEBS 80/20% (w/w). This result reveals that although the PP/SEBS/talc composites showed a separated morphology, the good dispersion and distribution of this mineral filler in the polymers contributed to avoid crack propagation and increase the impact properties. The tensile properties in the elastic region were not significantly affected.

An investigation of the impact of an amino-ended hyperbranched polymer as a new type of modifier on the compatibility of PLA/PBAT blends

2018 ◽  
Vol 38 (3) ◽  
pp. 223-229 ◽  
Author(s):  
Yujuan Jin ◽  
Shuang Men ◽  
Yunxuan Weng
Keyword(s):  
Fourier Transform ◽  
Hyperbranched Polymer ◽  
Poly Lactic Acid ◽  
Melt Mixing ◽  
Sem Images ◽  
Roller Mill ◽  
Elongation At Break ◽  
New Type ◽  
The Impact ◽  
Scanning Electron

AbstractPoly(lactic acid) (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) blends using amino-ended hyperbranched polymers (HBP) as modifiers were prepared by melt-mixing through a double-roller mill and injection molding. It was found that when the content of HBP was 2.5 phr, the elongation at break and the impact strength of PLA/PBAT blends both reached peak values. Moreover, by addition of HBP, the ΔTg of the blends was smaller. These results, together with Scanning electron microscope (SEM) images on the fractured morphology of the blends, indicate that the compatibility between PLA and PBAT is improved upon addition of HBP. The mechanism of the impact of HBP on the improvement of the compatibility between PLA and PBAT is proposed based upon Fourier transform infrared (FTIR) spectra.

Mechanical and thermal properties of poly(lactic acid)/sugarcane bagasse fiber green composites

2015 ◽  
Vol 30 (8) ◽  
pp. 1091-1102 ◽  
Author(s):  
RZ Khoo ◽  
WS Chow
Keyword(s):  
Lactic Acid ◽  
Sugarcane Bagasse ◽  
Mechanical Analysis ◽  
Poly Lactic Acid ◽  
Mechanical And Thermal Properties ◽  
Melt Compounding ◽  
The One ◽  
The Impact ◽  
Bagasse Fiber ◽  
Scanning Electron

Poly(lactic acid)/sugarcane bagasse fiber (PLA/SCBF) composites were prepared using melt compounding followed by compression molding. Epoxidized soybean oil (ESO) was selected as plasticizer for the PLA/SCBF composites. SCBF was alkali-treated and ground into powder form with the size of approximately 100 μm (hereafter designated as SCBFP). The properties of the PLA composites were assessed using impact tests, field-emission scanning electron microscopy, and dynamic mechanical analysis (DMA). DMA results showed that the addition of SCBF increased the storage modulus of PLA and the effect is more pronounced for the one containing SCBFP. The impact strength of PLA/SCBF composites was improved significantly by the addition of ESO.

Evaluation of the effect of processing conditions on the impact properties of polypropylene-nano-CaCO3 composites

2017 ◽  
Vol 51 (24) ◽  
pp. 3365-3372 ◽  
Author(s):  
Marisa Cristina Guimarães Rocha ◽  
Gisele Fonseca Moreira ◽  
Antonio Henrique Monteiro Fonseca Thomé da Silva
Keyword(s):  
Response Surface Methodology ◽  
Filler Content ◽  
Rotation Speed ◽  
Impact Resistance ◽  
Significant Loss ◽  
Processing Conditions ◽  
Impact Properties ◽  
Polypropylene Composites ◽  
Processing Variables ◽  
The Impact

Processing variables are known to have a decisive influence on the impact properties of polypopylene-nano-CaCO3 composites. Therefore, it becomes mandatory to evaluate the effect of extrusion conditions on composite impact resistance. In the present work, a response surface methodology was used to evaluate the effects of screw rotation speed, screw configuration, and nanoparticles content on the polypropylene impact properties. The concentration of the nano-CaCO3 particles, the screw rotation speed, and the interaction between these entrance factors were the processing variables of greater influence on the impact properties of nano-CaCO3/polypropylene composites. The increase of screw rotation speed led to a decrease in the impact resistance, while the increase of filler content promoted an increase of such property. However, the increase of nanoparticles content led to obtaining poor tensile properties. Therefore, the filler content has to be adjusted in order to improve the impact properties without significant loss of mechanical strength.

Material analysis techniques using the ion mill

1996 ◽  
Vol 54 ◽  
pp. 1034-1035
Author(s):  
J. P. Benedict ◽  
R. M. Anderson ◽  
S. J. Klepeis
Keyword(s):  
Polished Surface ◽  
Surface Material ◽  
Analysis Techniques ◽  
Material Analysis ◽  
Optical Inspection ◽  
Electron Microscopy Analysis ◽  
Microscopy Analysis ◽  
Argon Ions ◽  
The Impact ◽  
Scanning Electron

Ion mills equipped with flood guns can perform two important functions in material analysis; they can either remove material or deposit material. The ion mill holder shown in Fig. 1 is used to remove material from the polished surface of a sample for further optical inspection or SEM ( Scanning Electron Microscopy ) analysis. The sample is attached to a pohshing stud type SEM mount and placed in the ion mill holder with the polished surface of the sample pointing straight up, as shown in Fig 2. As the holder is rotating in the ion mill, Argon ions from the flood gun are directed down at the top of the sample. The impact of Argon ions against the surface of the sample causes some of the surface material to leave the sample at a material dependent, nonuniform rate. As a result, the polished surface will begin to develop topography during milling as fast sputtering materials leave behind depressions in the polished surface.

scholarly journals Integration of Stable Ionic Liquid-Based Nanofluids into Polymer Membranes. Part I: Membrane Synthesis and Characterization

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 607
Author(s):  
Carolina Hermida-Merino ◽  
Fernando Pardo ◽  
Gabriel Zarca ◽  
João M. M. Araújo ◽  
Ane Urtiaga ◽  
...  
Keyword(s):  
Polymer Membranes ◽  
Small Addition ◽  
Polymeric Membranes ◽  
Synthesis And Characterization ◽  
Complete Disappearance ◽  
Optical Profilometry ◽  
Scanning Calorimetry ◽  
Exfoliated Graphene ◽  
The Stability ◽  
Scanning Electron

In this work, polymeric membranes functionalized with ionic liquids (ILs) and exfoliated graphene nanoplatelets (xGnP) were developed and characterized. These membranes based on graphene ionanofluids (IoNFs) are promising materials for gas separation. The stability of the selected IoNFs in the polymer membranes was determined by thermogravimetric analysis (TGA). The morphology of membranes was characterized using scanning electron microscope (SEM) and interferometric optical profilometry (WLOP). SEM results evidence that upon the small addition of xGnP into the IL-dominated environment, the interaction between IL and xGnP facilitates the migration of xGnP to the surface, while suppressing the interaction between IL and Pebax®1657. Fourier transform infrared spectroscopy (FTIR) was also used to determine the polymer–IoNF interactions and the distribution of the IL in the polymer matrix. Finally, the thermodynamic properties and phase transitions (polymer–IoNF) of these functionalized membranes were studied using differential scanning calorimetry (DSC). This analysis showed a gradual decrease in the melting point of the polyamide (PA6) blocks with a decrease in the corresponding melting enthalpy and a complete disappearance of the crystallinity of the polyether (PEO) phase with increasing IL content. This evidences the high compatibility and good mixing of the polymer and the IoNF.

A novel recycled polyethylene terephthalate/polyamide 11 (rPET/PA11) thermoplastic blend

2021 ◽  
pp. 147776062110010
Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flexural Strength ◽  
Polyethylene Terephthalate ◽  
Practical Implication ◽  
Polyamide 11 ◽  
Recycled Polyethylene ◽  
Twin Screw ◽  
Electron Microscopy Analysis ◽  
The Impact

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.

Investigation of the Splat Deposition Behavior onto a Composite Coating in Cold Spray

2018 ◽  
Vol 941 ◽  
pp. 1639-1644
Author(s):  
Xin Chu ◽  
Phuong Vo ◽  
Stephen Yue
Keyword(s):  
Electron Microscope ◽  
Composite Coating ◽  
Cold Spray ◽  
Spray Deposition ◽  
Cold Spraying ◽  
Single Component ◽  
Optical Profilometry ◽  
Deposition Behavior ◽  
Polished Substrate ◽  
Scanning Electron

The splat test is usually generated by low feed rate cold spraying of particles onto an as-polished substrate and it can be considered as a monolayer coating deposition. In this study, in order to investigate cold spray deposition mechanisms, Fe splats were sprayed onto the cold-sprayed single component 316L, Fe, and a composite 90Fe coatings. Results showed that although there is only 3.6 vol.% of 316L in the composite 90Fe coating, Fe splats exhibit a much better deposition behavior onto the 90Fe as compared with the single component Fe coating. To explain this observation, Fe splat samples were characterized using the scanning electron microscope (SEM), optical profilometry, splat adhesion tests, and splat nanoindentation. Finally, a preliminary explanation towards the Fe splat deposition behavior onto the composite coating was drawn.

Production and Characterization of Porous Starch Granule and Poly(butylene adipate-co-terephthalate) Blend as a Bio-Composite

2012 ◽  
Vol 550-553 ◽  
pp. 1513-1521
Author(s):  
Sirirat Thothong ◽  
Klanarong Sriroth ◽  
Rattana Tantatherdtam ◽  
Amnat Jarerat
Keyword(s):  
Starch Granule ◽  
Rice Starch ◽  
Starch Granules ◽  
Screw Extruder ◽  
Elongation At Break ◽  
Single Screw ◽  
Single Screw Extruder ◽  
Scanning Electron ◽  
Granular Starch

To improve the miscibility of native rice starch granules and poly(butylene adipate-co-terephthalate)(PBAT), rice starch was hydrolyzed by a mixture of α-amylase and amyloglucosidase. The obtained porous rice granular starch was then mechanically blended with PBAT by single screw extruder. Many pits and holes on the surface of starch granules were observed by scanning electron microscopy (SEM). The rough surface of the rice starch granules improved the compatibility of the polymers in the blends, which consequently increased the tensile strength and the elongation at break. In addition, SEM also revealed that the porous granules were homogeneously distributed in the polymer matrix with no appearance of gaps.

Effect of inorganic nanofillers on the impact behavior and fracture probability of industrial high-density polyethylene nanocomposite

2017 ◽  
Vol 52 (18) ◽  
pp. 2431-2442 ◽  
Author(s):  
Harun Sepet ◽  
Necmettin Tarakcioglu ◽  
RDK Misra
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
High Density Polyethylene ◽  
Fracture Probability ◽  
High Density ◽  
Impact Behavior ◽  
Inorganic Filler ◽  
Melt Mixing ◽  
The Impact ◽  
Scanning Electron

The main purpose of this work is to study how the morphology of nanofillers and dispersion and distribution level of inorganic nanofiller influence the impact behavior and fracture probability of inorganic filler filled industrial high-density polyethylene nanocomposites. For this study, nanoclay and nano-CaCO3 fillers–high-density polyethylene mixings (0, 1, 3, 5 wt.% high-density polyethylene) was prepared by melt-mixing method using a compounder system. The impact behavior was examined by charpy impact test, scanning electron microscopy, and probability theory and statistics. The level of the dispersion was characterized with scanning electron microscopy energy dispersive X-ray spectroscopy analysis. The results showed rather good dispersion of both of inorganic nanofiller, with a mixture of exfoliated and confined morphology. The results indicated that the impact strength of the industrial nanocomposite decreased with the increase of inorganic particulate content. The impact reliability of the industrial nanocomposites depends on the type of nanofillers and their dispersion and distribution in the matrix.

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