A green and efficient route for simultaneous recovery of low valence of vanadium and chromium, titanium and iron from vanadium slag

2022 ◽  
Vol 178 ◽  
pp. 106046
Author(s):  
Zhenghao Wang ◽  
Liang Chen ◽  
Zhifeng Qin ◽  
Ke Yang ◽  
Bin Liang ◽  
...  
Keyword(s):  
Vanadium Slag ◽  
Efficient Route

Carbon Monoxide Related Reductions

INEOS OPEN ◽  
2020 ◽  
Vol 3 ◽  
Author(s):  
O. I. Afanasyev ◽  
◽  
D. Chusov ◽  
Keyword(s):  
Organic Chemistry ◽  
Carbon Monoxide ◽  
Reducing Agent ◽  
Current Development ◽  
Efficient Route ◽  
Development Prospects

Carbon monoxide is a unique reducing agent that is only gaining popularity in organic chemistry. This review highlights the main approaches to the application of CO as a reducing agent, summarizes and critically analyzes the key trends in this field, and describes the current development prospects. Potentially the most selective and efficient route for the realization of these processes is demonstrated.

Palladium Nanowire Thin Films via Template Growth

2003 ◽  
Vol 775 ◽  
Author(s):  
Donghai Wang ◽  
David T. Johnson ◽  
Byron F. McCaughey ◽  
J. Eric Hampsey ◽  
Jibao He ◽  
...  
Keyword(s):  
Thin Film ◽  
Electron Microscopy ◽  
Thin Films ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Conductive Substrate ◽  
Palladium Nanowires ◽  
Efficient Route ◽  
Silica Thin Film

AbstractPalladium nanowires have been electrodeposited into mesoporous silica thin film templates. Palladium continually grows and fills silica mesopores starting from a bottom conductive substrate, providing a ready and efficient route to fabricate a macroscopic palladium nanowire thin films for potentially use in fuel cells, electrodes, sensors, and other applications. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicate it is possible to create different nanowire morphology such as bundles and swirling mesostructure based on the template pore structure.

Efficient Route for Synthesis of Enamines from 1,3-Alkyl-2-Thioxodihydropyrimidine-4,6(1H,5H)-dione Enols

2019 ◽  
Vol 16 (7) ◽  
pp. 538-540
Author(s):  
Anamika Sharma ◽  
Zainab M. Almarhoon ◽  
Ayman El-Faham ◽  
Beatriz G. de la Torre ◽  
Fernando Albericio
Keyword(s):  
Ammonium Chloride ◽  
Thiobarbituric Acid ◽  
Acid Acid ◽  
Efficient Route ◽  
Harsh Conditions

Here we report a greener approach for the synthesis of enamines from enols of 1,3-alkyl-2- thioxodihydropyrimidine-4,6(1H,5H)-dione (thiobarbituric acid) acid using ammonium chloride and ethanol as solvents. This protocol removes the need for catalysts or harsh conditions.

Non-isothermal crystallization behavior of spinel crystals in FeO-SiO2-TiO2-V2O3-Cr2O3 slag

2018 ◽  
Vol 116 (1) ◽  
pp. 110
Author(s):  
Lixiong Shao ◽  
Jiang Diao ◽  
Wang Zhou ◽  
Tao Zhang ◽  
Bing Xie
Keyword(s):  
Cooling Rate ◽  
Crystallization Behavior ◽  
Crystal Size ◽  
Growth Mechanisms ◽  
Vanadium Slag ◽  
Growth Behaviour ◽  
Temperature Range ◽  
Chromium Spinel ◽  
Mean Diameter ◽  
The Mean

The growth behaviour of spinel crystals in vanadium slag with high Cr2O3 content was investigated and clarified by statistical analyses based on the Crystal Size Distribution (CSD) theory. The results indicate that low cooling rate and Cr2O3 content benefit the growth of spinel crystals. The chromium spinel crystals firstly precipitated and then acted as the heterogeneous nuclei of vanadium and titanium spinel crystals. The growth mechanisms of the spinel crystals at the cooling rate of 5 K/min consist two regimes: firstly, nucleation control in the temperature range of 1873 to 1773 K, in which the shapes of CSD curves are asymptotic; secondly, surface and supply control within the temperature range of 1773 to 1473 K, in which the shapes of CSD curves are lognormal. The mean diameter of spinel crystals increases from 3.97 to 52.21 µm with the decrease of temperature from 1873 to 1473 K.

scholarly journals Catalytic Antioxidant Activity of Bis-Aniline-Derived Diselenides as GPx Mimics

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4446
Author(s):  
Giancarlo V. Botteselle ◽  
Welman C. Elias ◽  
Luana Bettanin ◽  
Rômulo F. S. Canto ◽  
Drielly N. O. Salin ◽  
...  
Keyword(s):  
Antioxidant Activity ◽  
Hydrogen Bond ◽  
Electronic Properties ◽  
Partial Charge ◽  
Amino Group ◽  
Diphenyl Diselenide ◽  
Charge Delocalization ◽  
Ipso Substitution ◽  
Efficient Route ◽  
Catalytic Performances

Herein, we describe a simple and efficient route to access aniline-derived diselenides and evaluate their antioxidant/GPx-mimetic properties. The diselenides were obtained in good yields via ipso-substitution/reduction from the readily available 2-nitroaromatic halides (Cl, Br, I). These diselenides present GPx-mimetic properties, showing better antioxidant activity than the standard GPx-mimetic compounds, ebselen and diphenyl diselenide. DFT analysis demonstrated that the electronic properties of the substituents determine the charge delocalization and the partial charge on selenium, which correlate with the catalytic performances. The amino group concurs in the stabilization of the selenolate intermediate through a hydrogen bond with the selenium.

Recovery and separation of Fe and Mn from simulated chlorinated vanadium slag by molten salt electrolysis

2020 ◽  
Vol 27 (12) ◽  
pp. 1678-1686 ◽  
Author(s):  
Shi-yuan Liu ◽  
Yu-lan Zhen ◽  
Xiao-bo He ◽  
Li-jun Wang ◽  
Kuo-chih Chou
Keyword(s):  
Molten Salt ◽  
Vanadium Slag ◽  
Molten Salt Electrolysis ◽  
Fe And Mn
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