Effects of the magnetic field on the polyaniline film studied by in situ conductivity measurements and X-ray diffraction

1997 ◽  
Vol 421 (1-2) ◽  
pp. 45-48 ◽  
Author(s):  
Lin-Tao Cai ◽  
Shi-Bing Yao ◽  
Shao-Min Zhou
2010 ◽  
Vol 663-665 ◽  
pp. 542-545 ◽  
Author(s):  
Bing Jie Zhu ◽  
Xin Wei Wang ◽  
Mei Fang Zhu ◽  
Qing Hong Zhang ◽  
Yao Gang Li ◽  
...  

The PANI/ITO conducting nanocomposites have been synthesized by in-situ polymerization. The obtained nanocomposites were characterized by X-ray diffraction pattern, scanning electron microscopy and Fourier transform infrared. Electrical conductivity measurements on the samples pressed into pellets showed that the maximum conductivity attained 2.0 ± 0.05 S/cm for PANI/ITO nanocomposites, at ITO doping concentration of 10 wt%. The results of the present work may provide a simple, rapid and efficient approach for preparing PANI/ITO nanocomposites.


2007 ◽  
Vol 561-565 ◽  
pp. 1565-1568 ◽  
Author(s):  
Kazuhiko Iwai ◽  
Jun Akiyama ◽  
Shigeo Asai

A high magnetic field is a useful tool to control the crystal alignment of ceramic materials. In this study, a horizontal 10T static magnetic field was imposed on slurry containing hydroxyapatite (HAp) crystals under the horizontal mold rotation during slip casting process so as to introduce uni-axial alignment for some amount of crystals in the sample, and then it was sintered in atmosphere without the magnetic field. From X-ray diffraction, it has been found that the HAp crystals in the sample treated with the mold rotation under the magnetic field were aligned its c-axis to a particular direction.


2005 ◽  
Vol 19 (01n03) ◽  
pp. 651-653
Author(s):  
W. L. WANG ◽  
L. LI ◽  
K. J. LIAO ◽  
J. ZHANG ◽  
R. J. ZHANG ◽  
...  

The Magnetothermoelectric and thermoelectric power of nano- ZnO films was investigated. The ZnO films in this study were prepared by DC reactive sputtering using a Zn target (99.99%) containing AL of 1.5%. The films obtained were characterized by SEM, x-ray diffraction, optical and electrical measurements. It was found that the sputtering ZnO films were highly orientation growth with the c-axis perpendicular to the substrate surface. The measurements showed that there was a striking seebeck effect in the ZnO films, and their thermoelectric power was linearly increased with increasing temperature. The experimental results were also demonstrated that the thermoelectric power was degraded under the magnetic field. This finding may ascribe to the magneto resistive effect.


2018 ◽  
Vol 71 (11) ◽  
pp. 914
Author(s):  
Yanfang Xia ◽  
Min Liu ◽  
Duxin Li

Co0.76Cu0.74[Fe(CN)6]·7.5H2O was prepared as a powder by a chemical co-precipitation method. The powder X-ray diffraction patterns were indexed to the typical face-centred cubic structure with the lattice parameter a 10.55(2) Å. The temperature dependence of the χ−1 curve obeys the Curie–Weiss law (χ = C/(T – θ)) in the temperature range of 180–300 K. According to Curie–Weiss law, the calculated θ value is −54.82 K. In the paramagnetic state at 300 K, the effective magnetic moment (μeff = (8χT)1/2) is 3.58 μB per formula unit. The calculated theoretical effective magnetic moment is 4.06 μB. The magnetic field cooling measurements under a 200 Oe applied magnetic field show that the saturation magnetization value at 2 K of the complex Co0.76Cu0.74[Fe(CN)6]·7.5H2O is 1.528 emu g−1.


2014 ◽  
Vol 24 (3S1) ◽  
pp. 90-94 ◽  
Author(s):  
Le Tuan Tu ◽  
Luu Van Thiem ◽  
Pham Duc Thang

The magnetic properties in Co-Ni-P nanowires arrays with diameter of 200 nm were investigated. All the samples were prepared by electrodeposition method with pH of 5.5 and at room temperature. During the deposition, a magnetic field in range of 0 - 750 Oe was applied parallel to the wires axis. The crystalline structure and morphology of the samples were characterized by X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM), respectively. The hysteresis loops were measured at room temperature using vibrating sample magnetometry (VSM). The mixture of hcp phases of the Co-Ni-P based nanowires has been indicated by the XRD pattern. The obtained results show that with 750 Oe magnetic field applied during deposition we can obtain maximum coercivity value (2180 Oe). The \(M_{r}/M_{s}\) ratio was rapid increased when the magnetic field changed from 0 Oe to 750 Oe.


2017 ◽  
Vol 909 ◽  
pp. 300-305 ◽  
Author(s):  
Takehito Ikeuchi ◽  
Akihiro Koyama ◽  
Muneyuki Imafuku ◽  
Shun Fujieda ◽  
Yusuke Onuki ◽  
...  

We carried out in situ tri-axial magnetostriction analysis for cube-oriented Fe-18%Ga single crystal by X-ray diffraction measurement under magnetic field. Periodic change in tri-axial magnetostriction with applied magnetic field direction was clearly observed. However, those values in [100] and [010] directions were not equivalent. Theoretical calculation of magnetostriction considering domain structure revealed this is caused by the non-equivalent volume fraction of initial magnetic domains.


2007 ◽  
Vol 26-28 ◽  
pp. 563-565
Author(s):  
Kazuhiko Iwai ◽  
Manabu Usui ◽  
Shigeo Asai

A static magnetic field and an alternating current are imposed on a metallic alloy during solidification for a crystal alignment of the primary phase. A Sn-10%Pb is selected as a sample because its primary phase is expected to have an anisotropic nature in magnetic susceptibility. In the x-ray diffraction pattern of the sample solidified without the magnetic field, the first and second highest peaks are (101) and (211) planes. On the other hand, those solidified with the magnetic field are (200) and (220) planes which are magnetically preferred planes. That is, the primary phase crystals in the sample solidified with the magnetic field are aligned to the specific direction.


Open Physics ◽  
2011 ◽  
Vol 9 (2) ◽  
Author(s):  
Karol Załęski ◽  
Janusz Dubowik ◽  
Iwona Gościańska ◽  
Bartłomiej Andrzejewski ◽  
Tomasz Toliński

AbstractIn this paper we report structural, magnetic and transport properties of strongly textured Ni51Mn36Sn13 thin films. The off-stoichiometric Heusler alloy films with 200 nm thickness were sputter-deposited on a MgO(100) substrate at 500 K and after annealed at 1000 K in UHV conditions. The textured growth was confirmed by x-ray diffraction in Bragg-Brentano geometry. The temperature dependence of the magnetic properties was measured by VSM and FMR methods. The electron transport measurements were carried out in function of temperature in 0 Oe and 50 kOe fields. All measurements corroborate the existence of the martensitic transformation in the film. Furthermore, transport measurements reveal an influence of the magnetic field on the transition temperature.


2013 ◽  
Vol 27 (11) ◽  
pp. 1350077
Author(s):  
J. N. WANG ◽  
W. L. LI ◽  
X. L. LI ◽  
W. D. FEI

A BiFeO 3 thin film was prepared on the (111) Pt / Ti / SiO 2/ Si substrate by the solution coating method. In order to detect the effect of an external magnetic field on the BiFeO 3 thin film, a fine scan X-ray diffraction with a scan ratio of 0.002°/s was carried out under the magnetic field parallel to the film surface. The result of the in situ analysis of X-ray diffraction for the thin film in the magnetic field indicates that the magnetic field leads to an increase of the integral intensity ratio of [Formula: see text] compared with that under no magnetic field. The increase of [Formula: see text] implies a domain switching under the magnetic field, where the domain switching comes from the decreasing residual tensile stress induced by the magnetostriction of BiFeO 3 in the magnetic field.


1998 ◽  
Vol 5 (3) ◽  
pp. 949-951
Author(s):  
J. Y. Zhao ◽  
X. W. Zhang ◽  
M. Ando

A compact environmental chamber with a furnace operating in the range from room temperature to about 900 K has been built for a high-temperature nuclear-resonant Bragg scattering study. The compact size (75 mm diameter and 70 mm depth) allows an external magnetic field to be applied from outside permanent Nd–Fe–B alloy magnets; a magnetic field up to 1000 G has been obtained. The chamber can be mounted on a precise θ–2θ goniometer so that in situ observations of X-ray diffraction from a single crystal can be carried out. The temperature is measured by two thermocouples placed at the top and back of the sample and controlled by a PID controller. The temperature fluctuation of the chamber is less than ±1 K.


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