Glass-fiber reinforced polymer (GFRP) composite rods with epoxy matrix filled with electrically nonconducting particles find widespread use in high-voltage electrical insulator applications. The service loads require a range of different, minimum material property values, e.g. toughness, tensile, or compressive strength, but also component-specific performance, e.g. pull-out friction of surface crimped metal fittings or electric breakdown strength. The contribution discusses selected examples of the effects of different particle filler types on the properties of filled epoxy resin as well as on the behavior of GFRP rods with such a matrix. In all investigated systems CaCO3 was used as micron-sized filler, complemented by different amounts of either nanosilica or core-shell rubber (binary filler), or by both, nanosilica and core-shell rubber (ternary filler). With ternary filler combinations at a content of 36 wt%, fracture toughness GIC was improved in nanocomposite epoxy plates and in GFRP rods by 60% and 100%, respectively compared to a matrix with 20 wt% CaCO3 (used as reference system). The glass transition temperature Tg for some ternary systems dropped from 160 °C (for neat epoxy), to approximately 140 °C, the maximum allowed drop in Tg in view of requirements from further processing steps of the electrically insulating components. The ternary fillers yield transfer of the improvements of fracture properties from epoxy nanocomposite plates into the GFRP rods beyond that of the system with CaCO3 filler only. Compressive strength of the GFRP rods was improved by about 20% only for the binary nanosilica and CaCO3 filler, and was not significantly enhanced with the ternary systems. That combination, however, did not yield improvements in toughness beyond the CaCO3-filled nanocomposite plates and rods. With the range of filler types and contents investigated here, it was hence not possible to simultaneously optimize both, fracture toughness and compressive strength of the GFRP insulator rods.
High modulus polyimide particle-reinforcement of epoxy composites
