scholarly journals Model of kinematic waves for gas–liquid segregation with phase transition in porous media

2017 ◽  
Vol 829 ◽  
pp. 659-680
Author(s):  
Stephane Zaleski ◽  
Mikhail Panfilov

We consider the problem of gas–liquid flow with phase transition in a porous medium, governed by the buoyancy force. Free gas releases due to continuous pressure decrease. We take into account the gas expansion and the dissolution of chemical components in both phases controlled by the local phase equilibrium. We have developed an asymptotic model of flow for low pressure gradients in the form of a nonlinear hyperbolic system of first order with respect to the liquid saturation and the total flow velocity, which is the extended non-homogeneous Buckley–Leverett model. In two asymptotic cases determined by two different ratios between the characteristic times, this model is completely decoupled from pressure, i.e. the pressure enters in this model as a parameter determined through an independent formula. The segregation problem with phase transition in a bounded domain is solved for two cases of boundary conditions. The saturation behaviour is described in terms of nonlinear kinematic waves, whose evolution follows a complex segregation scenario, which includes the wave reflection and formation of shocks. The macroscopic gas–liquid interfaces are described in terms of shock waves. The comparison with numerical simulations shows satisfactory results.

2020 ◽  
Author(s):  
Tracey Jacksier ◽  
Rick Socki

<p>During liquid-vapor phase transition, CO<sub>2</sub> can undergo isotopic fractionation in both C and O.  This phase transition can occur during routine cylinder handling, such as gas expansion or while subjecting the cylinder to cold temperatures without allowing the cylinders to come to thermal equilibrium prior to use. </p><p>This work examines the isotope changes for both C and O in a series of controlled experiments on dual phase (liquid-vapor) and single-phase (vapor only) carbon dioxide contained in pressurized gas cylinders at sub-freezing, ambient and elevated temperatures.  The isotopic values were measured during the temperature equilibration from either cold or elevated temperatures to room temperature.  Isotopic values were observed to vary when the gas was at sub-freezing temperatures but not from elevated temperatures.  Stable isotope practitioners, who rely on pressurized carbon dioxide as a working IRMS laboratory reference gas, will find this work useful.</p>


1974 ◽  
Vol 14 (03) ◽  
pp. 203-215 ◽  
Author(s):  
Jerry D. Ham ◽  
James P. Brill ◽  
C. Kenneth Eilerts

Abstract Data obtained by flowing two-phase fluids through sandstone cores were used to develop empirical equations for computing the pressure gradients and liquid saturations that will occur during the recovery of gas-condensate fluids like those in the Gulf Coast area. Equilibrium saturation may be computed for a given pressure, velocity, and liquid/gas ratio of flow. For this purpose, the minimum liquid flow saturation at high pressures, S, was developed for characterizing a core and a fluid. The effects of saturation on the mobility for Darcy flow and on the coefficient for non-Darcy flow are considered in an equation with parameters in addition to the Klinkenberg and Forchheimer coefficients. All parameters for these equations may be determined parameters for these equations may be determined either by routine measurements or by correlations. Introduction Fluid properties required for computing the transient flow of gas-condensate fluids and data obtained to meet this need were discussed at the 1966 SPE-AIME Fall Meeting. In the following year Dranchuk and Kolada described a means of analyzing laboratory data for nonlinear parameters pertaining to flow of gases. Gewers and Nichol pertaining to flow of gases. Gewers and Nichol investigated the effect of liquid saturation on the non-Darcy-flow term of the pressure-gradient equation. Modine and Fields used this kind of information to simulate turbulent flow in gas wells. An equation is needed for computing a more realistic value of the pressure gradient for flowing two-phase fluids than is possible with the Darcy equation. An equation is needed to compute as a boundary condition the liquid saturation possible in the porous medium near flowing wells. This paper describes two such equations that give effect paper describes two such equations that give effect to pressure, fluid velocity, liquid/gas ratio, and saturation. Seven parameters each required for the pressure-gradient and saturation equations may be pressure-gradient and saturation equations may be calculated by means of correlation equations that utilize routinely measured core properties. Concepts and Equations The Darcy equation was modified to include the Klindenberg effect "slip flow" and the Forchheimer coefficient to represent "inertial" or "turbulent" flow of gases in dry porous media,(1) By controlling the velocity (u) and pressure (p), measuring the gradient (dp/dx) and the viscosity [mu(p)], and calculating the density [p(p)], the properties k, b, and beta were determined for properties k, b, and beta were determined for representative cores by least-squares methods. As a step in the modification of Eq. 1 to obtain an equation applicable to the flow of two-phase fluids, mobility, A, for a two-phase fluid must replace the ratio of a known permeability to a viscosity, for the gas phase(2) The quantities k and mu(p) are to have the same* significance as in Eq. 1, except that mu(p) is the viscosity of a single-phase saturated gas. Relationships of liquid- and gas-phase mobilities, lambda and lambda, to fluid mobility, lambda, have been described in Appendix C of a previous publication. Briefly, lambda = lambda + lambda = f(S, p, F, u) k/mu(p). Now mu(p) is the viscosity of the flowing fluid mu under steady-state conditions only when F = 0.


Author(s):  
M. M. Awad ◽  
Y. S. Muzychka

First, a detailed review of two-phase frictional pressure gradient at microgravity conditions is presented. Then, a simple semi-theoretical method for calculating two-phase frictional pressure gradient at microgravity conditions using asymptotic analysis is presented. Two-phase frictional pressure gradient is expressed in terms of the asymptotic single-phase frictional pressure gradients for liquid and gas flowing alone. In the present model, the two-phase frictional pressure gradient for x ≅ 0 is nearly identical to single-phase liquid frictional pressure gradient. Also, the two-phase frictional pressure gradient for x ≅ 1 is nearly identical to single-phase gas frictional pressure gradient. The proposed model can be transformed into either a two-phase frictional multiplier for liquid flowing alone (φl2) or two-phase frictional multiplier for gas flowing alone (φg2) as a function of the Lockhart-Martinelli parameter, X. Comparison of the asymptotic model with experimental data at microgravity conditions is presented.


1990 ◽  
Vol 25 (5) ◽  
pp. 309-319 ◽  
Author(s):  
C. Treviño ◽  
W. Stüttgen ◽  
N. Peters

Energies ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 968
Author(s):  
Yongho Seong ◽  
Changhyup Park ◽  
Jinho Choi ◽  
Ilsik Jang

This study developed a data-driven surrogate model based on a deep neural network (DNN) to evaluate gas–liquid multiphase flow occurring in horizontal pipes. It estimated the liquid holdup and pressure gradient under a slip condition and different flow patterns, i.e., slug, annular, stratified flow, etc. The inputs of the surrogate modelling were related to the fluid properties and the dynamic data, e.g., superficial velocities at the inlet, while the outputs were the liquid holdup and pressure gradient observed at the outlet. The case study determined the optimal number of hidden neurons by considering the processing time and the validation error. A total of 350 experimental data were used: 279 for supervised training, 31 for validating the training performance, and 40 unknown data, not used in training and validation, were examined to forecast the liquid holdup and pressure gradient. The liquid holdups were estimated within less than 8.08% of the mean absolute percentage error, while the error of the pressure gradient was 23.76%. The R2 values confirmed the reliability of the developed model, showing 0.89 for liquid holdups and 0.98 for pressure gradients. The DNN-based surrogate model can be applicable to estimate liquid holdup and pressure gradients in a more realistic manner with a small amount of computating resources.


Author(s):  
D. L. Callahan ◽  
Z. Ball ◽  
H. M. Phillips ◽  
R. Sauerbrey

Ultraviolet laser-irradiation can be used to induce an insulator-to-conductor phase transition on the surface of Kapton polyimide. Such structures have potential applications as resistors or conductors for VLSI applications as well as general utility electrodes. Although the percolative nature of the phase transformation has been well-established, there has been little definitive work on the mechanism or extent of transformation. In particular, there has been considerable debate about whether or not the transition is primarily photothermal in nature, as we propose, or photochemical. In this study, cross-sectional optical microscopy and transmission electron microscopy are utilized to characterize the nature of microstructural changes associated with the laser-induced pyrolysis of polyimide.Laser-modified polyimide samples initially 12 μm thick were prepared in cross-section by standard ultramicrotomy. Resulting contraction in parallel to the film surface has led to distortions in apparent magnification. The scale bars shown are calibrated for the direction normal to the film surface only.


Author(s):  
Uwe Lücken ◽  
Joachim Jäger

TEM imaging of frozen-hydrated lipid vesicles has been done by several groups Thermotrophic and lyotrophic polymorphism has been reported. By using image processing, computer simulation and tilt experiments, we tried to learn about the influence of freezing-stress and defocus artifacts on the lipid polymorphism and fine structure of the bilayer profile. We show integrated membrane proteins do modulate the bilayer structure and the morphology of the vesicles.Phase transitions of DMPC vesicles were visualized after freezing under equilibrium conditions at different temperatures in a controlled-environment vitrification system. Below the main phase transition temperature of 24°C (Fig. 1), vesicles show a facetted appearance due to the quasicrystalline areas. A gradual increase in temperature leads to melting processes with different morphology in the bilayer profile. Far above the phase transition temperature the bilayer profile is still present. In the band-pass-filtered images (Fig. 2) no significant change in the width of the bilayer profile is visible.


Author(s):  
V.A. Munoz ◽  
R.J. Mikula ◽  
C. Payette ◽  
W.W. Lam

The transformation of high molecular weight components present in heavy oils into useable liquid fuels requires their decomposition by means of a variety of processes. The low molecular weight species produced recombine under controlled conditions to generate synthetic fuels. However, an important fraction undergo further recombination into higher molecular weight components, leading to the formation of coke. The optical texture of the coke can be related to its originating components. Those with high sulfur and oxygen content tend to produce cokes with small optical texture or fine mosaic, whereas compounds with relatively high hydrogen content are likely to produce large optical texture or domains. In addition, the structure of the parent chemical components, planar or nonplanar, determines the isotropic or anisotropic character of the coke. Planar molecules have a tendency to align in an approximately parallel arrangement to initiate the formation of the nematic mesophase leading to the formation of anisotropic coke. Nonplanar highly alkylated compounds and/or those rich in polar groups form isotropic coke. The aliphatic branches produce steric hindrance to alignment, whereas the polar groups participate in cross-linking reactions.


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