Origin of Late Triassic mafic–ultramafic intrusions in the Hongqiling Ni–Cu sulfide deposit, Northeast China: evidence from trace element and Sr–Nd isotope geochemistry

There are many Late Triassic mafic–ultramafic intrusions in the Hongqiling magmatic Ni–Cu sulfide deposit, Northeast China. Research on magma evolution leading to formation of these mafic–ultramafic intrusions is of great significance for understanding the mantle beneath Northeast China and associated Ni–Cu mineralization. A trace element study of the No. 1, 3, and 7 intrusions in the Hongqiling deposit reveals that these mafic–ultramafic intrusions are characterized by enrichment of incompatible elements, which however cannot be interpreted by subduction modification. Furthermore, model of batch partial melting of depleted mantle accompanied by upper crustal contamination can simulate the trace element patterns of these mafic–ultramafic intrusions, but partial melting of depleted mantle accompanied by lower crustal contamination model cannot work. In addition, Sr–Nd isotopic compositions of the Hongqiling No. 1, 3, and 7 intrusions also indicate that crustal contamination could have occurred mainly during the magma ascent. Consequently, a possible scenario for the magma evolution is that the primary mafic–ultramafic magma was derived from batch partial melting of a depleted mantle, and then contaminated by Cambrian–Ordovician metamorphic rocks of the Hulan Group during ascent. We conclude that the mantle source contained no significant crustal component in the Late Triassic and was also independent of substantial contribution from subducted material, and therefore the Mesozoic large-scale lithospheric delamination beneath eastern China may happen after a period of time of the Late Triassic.

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Petrology, mineral chemistry, and geochemistry of Late Triassic Ni–Cu ore-bearing mafic–ultramafic intrusions, Hongqiling, northeastern China: petrogenesis and tectonic implications

Canadian Journal of Earth Sciences ◽

10.1139/cjes-2018-0014 ◽

2019 ◽

Vol 56 (2) ◽

pp. 111-128

Author(s):

Ai Li ◽

Jian Wang ◽

Yue Song

Keyword(s):

Crustal Contamination ◽

Parental Magma ◽

Mineral Chemistry ◽

Late Triassic ◽

Sulfide Deposit ◽

Chemical Compositions ◽

Tholeiitic Magma ◽

Average Value ◽

Central Asian ◽

History Of

The Hongqiling magmatic Ni–Cu sulfide deposit, situated on the southern margin of the eastern Central Asian Orogenic Belt (CAOB), is composed of over 30 mafic–ultramafic intrusions. These ore-bearing intrusions are composed mainly of harzburgite, lherzolite, websterite, orthopyroxenite, and norite (gabbro). The constituent minerals are olivine, diopside, bronzite, calcic-hornblende, plagioclase, and spinel with orthopyroxene as a dominant mineral in these intrusions. These ore-bearing intrusions are not Alaskan-type complexes. Spinel and clinopyroxene both exhibit different chemical compositions from those in the Alaskan-type complexes. The rocks that make up the intrusions have high contents of MgO (average value = 25.20 wt.%) and low TiO2 (average value = 0.58 wt.%). The high MgO contents of the minerals and the high Mg# (71) of the calculated melt in equilibrium with olivine demonstrate that the parental magma of the Hongqiling mafic–ultramafic intrusions was a high-Mg tholeiitic magma. The Hongqiling ore-bearing mafic–ultramafic intrusions and the calculated “trapped liquids” for the olivine-orthopyroxene cumulate rocks are all enriched in large-ion lithophile elements and depleted in high field strength elements. The Ce/Pb, Ta/La, Th/Yb, and (La/Sm)PM values and the depletion of Nb and Ta suggest that the magma experienced crustal contamination. The Hongqiling ore-bearing intrusions display many similarities with mafic–ultramafic intrusions that formed in a post-collisional extensional environment in the western CAOB (e.g., Huangshanxi). Common features include their whole-rock compositions and mineral chemistry. Combined with the evolutionary history of the eastern segment of the CAOB, we believe that the Late Triassic Hongqiling mafic–ultramafic intrusions formed in a post-collisional extensional environment.

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Geochemical evidence for the emplacement of the Whin Sill complex of northern England

Geological Magazine ◽

10.1017/s0016756800031836 ◽

1985 ◽

Vol 122 (4) ◽

pp. 389-396 ◽

Cited By ~ 11

Author(s):

R. S. Thorpe ◽

R. Macdonald

Keyword(s):

Trace Elements ◽

Trace Element ◽

Partial Melting ◽

Sedimentary Rocks ◽

Crustal Contamination ◽

Mantle Peridotite ◽

Chemical Characteristics ◽

Heterogeneous Mantle ◽

Magma Pulses ◽

Significant Chemical

AbstractThe Whin Sill comprises a major quartz tholeiite sill of late Carboniferous age underlying an area of c. 5000 km2 and with a volume of c. 200 km3, associated with contemporaneous dykes emplaced within Carboniferous sedimentary rocks in northeast England. New trace element analyses of chilled margins, sill interiors and dykes indicate that the Whin Sill complex magmas show significant chemical variations in terms of the relatively stable trace elements Th, Ce, Y, Zr, Nb and Ni. These data indicate that the complex was fed by a large number of compositionally distinct magma pulses, and that certain of the dykes may have formed feeder channels for the sill. The chemical characteristics of the sill and dyke samples are consistent with derivation by extensive polybaric fractional crystallization of olivine tholeiite magma derived by partial melting of compositionally heterogeneous mantle peridotite and/or crustal contamination of mantle-derived magmas.

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Mantle source characteristics of Triassic alkaline lavas within the Antalya Nappes, SW Turkey

10.5194/egusphere-egu2020-6775 ◽

2020 ◽

Author(s):

Ercan Aldanmaz ◽

Aykut Güçtekin ◽

Özlem Yıldız-Yüksekol

Keyword(s):

Trace Element ◽

Partial Melting ◽

Mantle Source ◽

Carbonate Platform ◽

Incompatible Trace Element ◽

Late Triassic ◽

Radiogenic Isotope ◽

Basaltic Rocks ◽

Sw Turkey ◽

End Members

The Late Triassic basaltic rocks that are dispersed as several lava sheets in a number of different tectonic slices within the Antalya nappes in SW Turkey represent the remnants of widespread oceanic magmatism with strong intra-plate geochemical signatures. The largest exposures are observed around the Antalya Bay, where pillow structured or massif lava flows are interlayered with Upper Triassic pelagic or carbonate platform sediments. Based on bulk-rock geochemical characteristics, the rocks mostly classify as alkaline basalts and display distinctive OIB-type trace element distributions characterized by significant enrichments in LILE and HFSE abundances, as well as LREE/HREE ratios, with respect to average N-MORB. Quantitative modeling of trace element data suggest that the primary melts that produced the alkaline lavas are largely the products of variable proportions of mixing between melts generated by variable, but generally low (<10) degrees of partial melting of more than one compositionally distinct mantle source. The samples, as a whole, display large variations in radiogenic isotope ratios with 87Sr/86Sr = 0.703021&#8211;0.70553, 143Nd/144Nd = 0.51247&#8211;0.51279, 206Pb/204Pb = 18.049&#8211;20.030, 207Pb/204Pb = 15.544&#8211;15.723 and 208Pb/204Pb = 38.546&#8211;39.530. Such variations in isotopic ratios correlate with the change in incompatible trace element relative abundances and reflect the involvement of a number of compositionally distinct mantle end-members. These include EMI and EMII type enriched mantle components both having lower 143Nd/144Nd than typical depleted MORB source with their contrasting low and high 206Pb/204Pb and 207Pb/204Pb ratios respectively, as well as a high time-integrated 238U/204Pb component with high 206Pb/204Pb at relatively low 87Sr/86Sr and &#949;Nd values. The results from trace element and radiogenic isotope data are consistent with the view that the initial melt generation was likely related to partial melting of the shallow convecting upper mantle in response to Triassic rifting events, while continued mantle upwelling resulted in progressively increased melting of mantle lithosphere that contained compositionally contrasting lithological domains with strong isotopic heterogeneities.

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Petrogenesis and tectonic implications of Late Jurassic – Early Cretaceous granitic magmatism in the Xing’an Block, Northeast China: geochronological, geochemical, and Hf isotopic evidence

Canadian Journal of Earth Sciences ◽

10.1139/cjes-2017-0226 ◽

2018 ◽

Vol 55 (6) ◽

pp. 571-588 ◽

Cited By ~ 3

Author(s):

Yue He ◽

Zhong-Hua He ◽

Wen-Chun Ge ◽

Hao Yang ◽

Zhi-Hui Wang ◽

...

Keyword(s):

Partial Melting ◽

Early Cretaceous ◽

Northeast China ◽

Late Jurassic ◽

Granitic Rocks ◽

Geochemical Data ◽

Magma Source ◽

Isotopic Evidence ◽

Depleted Mantle ◽

Microgranular Enclaves

This study presents new geochronological, whole-rock geochemical, and zircon Hf isotopic evidence for the age, petrogenesis, and source of Mesozoic granitic rocks of the Xing’an Block, Northeast China. This evidence reveals the Late Mesozoic tectonic evolution of the eastern section of the Central Asian Orogenic Belt. Laser-ablation inductively coupled plasma – mass spectrometryzircon U–Pb age data indicate that the syenogranite, monzogranite, and alkali feldspar granite units, as well as their associated diorite microgranular enclaves, were emplaced between 150–142 Ma, providing evidence of Late Jurassic to Early Cretaceous magmatic events within the Xing’an Block. The granites contain high concentrations of SiO2 (65.24%–75.73 wt.%) and K2O (3.94%–5.30 wt.%), low concentrations of MgO (0.10%–1.30 wt.%), and A/CNK values of 0.92–1.06. In addition, Hf isotopic analysis of zircons from the 150–142 Ma granites yields εHf(t) values of +4.54 to +12.16 and two-stage Hf model aged from 906 to 423 Ma, indicating that they formed from magmas generated by partial melting of a juvenile Neoproterozoic–Phanerozoic accreted crustal source. The basic magma source for the diorite microgranular enclaves most likely formed from partial melting of a depleted mantle that had been metasomatized by subduction-related fluids. Combining these new geochemical data with the geology of this region, Late Jurassic to Early Cretaceous magmatism in the Xing’an Block most likely occurred in an extensional environment associated with closure of the Mongol–Okhotsk Ocean.

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Crustal assimilation in the Burnt Lake metavolcanics, Grenville Province, southeastern Ontario, and its tectonic significance

Canadian Journal of Earth Sciences ◽

10.1139/e17-101 ◽

1997 ◽

Vol 34 (9) ◽

pp. 1272-1285 ◽

Cited By ~ 5

Author(s):

T. E. Smith ◽

P. E. Holm ◽

N. M. Dennison ◽

M. J. Harris

Keyword(s):

Rare Earth ◽

Trace Element ◽

Partial Melting ◽

Continental Crust ◽

Fractional Crystallization ◽

Volcanic Rocks ◽

Lake Area ◽

Depleted Mantle ◽

Mafic Magmas ◽

Back Arc

Three intimately interbedded suites of volcanic rocks are identified geochemically in the Burnt Lake area of the Belmont Domain in the Central Metasedimentary Belt, and their petrogenesis is evaluated. The Burnt Lake back-arc tholeiitic suite comprises basalts similar in trace element signature to tholeiitic basalts emplaced in back-arc basins formed in continental crust. The Burnt Lake continental tholeiitic suite comprises basalts and andésites similar in trace element composition to continental tholeiitic sequences. The Burnt Lake felsic pyroclastic suite comprises rhyolitic pyroclastics having major and trace element compositions that suggest that they were derived from crustal melts. Rare earth element models suggest that the Burnt Lake back-arc tholeiitic rocks were formed by fractional crystallization of mafic magmas derived by approximately 5% partial melting of an amphibole-bearing depleted mantle, enriched in light rare earth elements by a subduction component. The modelling also suggests that the Burnt Lake continental tholeiitic rocks were formed by contamination – fractional crystallization of mixtures of mafic magmas, derived by ~3% partial melting of the subduction-modified source, and rhyolitic crustal melts. These models are consistent with the suggestion that the Belmont Domain of the Central Metasedimentary Belt formed as a back-arc basin by attenuation of preexisting continental crust above a westerly dipping subduction zone.

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Geochemistry of Cenozoic basaltic and silicic magmas in the central portion of the Loei–Phetchabun volcanic belt, Lop Buri, Thailand

Canadian Journal of Earth Sciences ◽

10.1139/e95-034 ◽

1995 ◽

Vol 32 (4) ◽

pp. 393-409 ◽

Cited By ~ 10

Author(s):

Suporn Intasopa ◽

Todd Dunn ◽

Richard StJ. Lambert

Keyword(s):

Trace Element ◽

Partial Melting ◽

Mantle Source ◽

Volcanic Rocks ◽

Volcanic Belt ◽

Central Portion ◽

Alkali Basalts ◽

Crustal Rocks ◽

Depleted Mantle ◽

Silicic Magmas

Cenozoic volcanic rocks outcrop in the central portion of the Loei–Phetchabun volcanic belt in central Thailand in the Lop Buri area. The volcanic rocks range in composition from basalt to high-silica rhyolite. In general, the volcanic rocks decrease in age from south to north. The oldest rocks studied are 55–57 Ma rhyolites that are isotopically and geochemically distinct from younger (13–24 Ma) rhyolites that occur farther north. Intermediate rocks (andesite and dacite) are less voluminous than rhyolite. Basalt occurs in the central and northern parts of the area and ranges in composition from olivine tholeiites to nepheline normative alkali basalts. The isotopic, major, and trace element compositions of the andesites, dacites, and younger rhyolites are consistent with an origin for these rocks by variable degrees of partial melting of metabasaltic crustal rocks, themselves derived from a depleted mantle source at approximately 530 ± 100 Ma. The apparent extent of partial melting of metabasalt increases from rhyolite to andesite. The isotopic and trace element systematics of the basalts are consistent with a refertilized depleted mantle source with characteristics of a mixture of normal mid-ocean ridge basalt source mantle and enriched mantle II type mantle.

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From the Finero phlogopite peridotite to the shoshonitic magmatism of the Dolomites: unveiling the evolution of the Sub-Continental Lithospheric Mantle beneath the Southern Alps (Northern Italy)

10.5194/egusphere-egu21-10137 ◽

2021 ◽

Author(s):

Federico Casetta ◽

Massimo Coltorti ◽

Ryan B. Ickert ◽

Darren F Mark ◽

Pier Paolo Giacomoni ◽

...

Keyword(s):

Partial Melting ◽

Lithospheric Mantle ◽

Planetary Science ◽

Southern Alps ◽

Late Triassic ◽

Spinel Lherzolite ◽

Depleted Mantle ◽

Significant Enrichment ◽

Continental Lithospheric Mantle ◽

Ultramafic Cumulates

The Mid-Triassic emplacement of shoshonitic magmas at the NE margin of the Adria plate in concomitance with extensional/transtensional tectonics is one of the most intriguing and peculiar aspects typifying the geodynamic evolution of the Western Tethyan realm. Although often hypothesized, the link between this magmatic event and the metasomatised Southern Alps Sub-Continental Lithospheric Mantle (SCLM) has never been constrained.Geochemical and petrological analyses of lavas, dykes and ultramafic cumulates belonging to the shoshonitic magmatism of the Dolomites, coupled with pre-existing data on peridotite massifs (i.e. Finero, Balmuccia, Baldissero), were used to reconstruct the evolution of the Southern Alps SCLM between Carboniferous and Triassic. According to our model, a metasomatised amphibole + phlogopite-bearing spinel lherzolite, similar to the Finero phlogopite peridotite and likely generated by interaction between a depleted mantle and slab-derived components during the Variscan subduction, was able to produce magmas with orogenic-like affinity during Mid-Triassic. In this context, partial melting degrees of ca. 5-7% were required for producing primitive SiO2-saturated to -undersaturated melts with shoshonitic affinity (87Sr/86Sri = 0.7032-0.7058; 143Nd/144Ndi = 0.51219-0.51235; Mg #~ 70; ~1.1 wt% H2O). As testified by the H2O content in mineral phases from the Finero phlogopite peridotite (Tommasi et al., 2017), the modelled Mid-Triassic fertile lithospheric mantle could have been able to preserve a significant enrichment and volatile content (600-800 ppm H2O) for more than 50 Ma, i.e. since the Variscan subduction-related metasomatism. During the Mid-Triassic partial melting event, the modelled Finero-like mantle exhausted the subduction-related signature inherited during the Variscan subduction. Around 20 Ma later, the same lithosphere portion was affected by an asthenospheric upwelling event related to the Late Triassic-Early Jurassic opening of the Alpine Tethys (Casetta et al., 2019).Casetta, F., Ickert, R.B., Mark, D.F., Bonadiman, C., Giacomoni, P.P., Ntaflos, T., Coltorti, M., 2019. The alkaline lamprophyres of the Dolomitic Area (Southern Alps, Italy): markers of the Late Triassic change from orogenic-like to anorogenic magmatism. Journal of Petrology 60(6), 1263-1298.Tommasi, A., Langone, A., Padr&#243;n-Navarta, J.A., Zanetti, A., Vauchez, A., 2017. Hydrous melts weaken the mantle, crystallization of pargasite and phlogopite does not: Insights from a petrostructural study of the Finero peridotites, Southern Alps. Earth and Planetary Science Letters 477, 59-72.

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Evidence of crustal contamination of mafic rocks associated with rapakivi rocks: an example from the Nordingrå complex, Central Sweden

Geological Magazine ◽

10.1017/s0016756801005672 ◽

2001 ◽

Vol 138 (4) ◽

pp. 371-386 ◽

Cited By ~ 10

Author(s):

ANDERS LINDH ◽

ULF BERTIL ANDERSSON ◽

THOMAS LUNDQVIST ◽

STEFAN CLAESSON

Keyword(s):

Trace Element ◽

Crustal Contamination ◽

Incompatible Trace Element ◽

Primitive Mantle ◽

Nd Isotope ◽

East Central ◽

Enriched Mantle ◽

Depleted Mantle ◽

Two Parameters ◽

Isotope Analyses

Gabbro and leucogabbro are volumetrically important rocks in the Nordingrå rapakivi complex, East Central Sweden. Plagioclase, ortho- and clinopyroxenes, and olivine dominate the gabbro. Perthitic orthoclase and quartz are interstitial in relation to the major minerals. The present work is based on 232 major-element and a large number of trace element analyses together with 15 whole rock Sm–Nd isotope analyses of the Nordingrå gabbroic rocks. εNd(T) values are negative, −1.1 to −3.2; the most negative values come from the gabbro. Most rocks are enriched in iron, some extremely enriched; none represent primitive mantle melts. The range of Mg-numbers is the same in the gabbro and the leucogabbro. Plots of the Ni-content vs. the Mg-number are scattered, but there is a positive correlation between these two parameters. The primary mantle-normalized ratios between similar trace elements are normally strongly different from one. Values larger as well as smaller than one are found for the same ratio in different rocks. The rare earth elements are only weakly fractionated with small Eu anomalies, negative for the gabbros and positive for the leucogabbros. The primary magma of the Nordingrå gabbro-anorthosite is thought to have been derived from a mildly depleted mantle source. Variations in the degree of partial melting of a reasonably homogeneous enriched mantle do not explain the observed chemical evolution. Crystal differentiation can account for some geochemical features, especially the Fe-enrichment. Crustal contamination is required by other characteristics as, for example, the negative εNd(T) values and the irregular and sometimes high primary-mantle normalized incompatible trace-element ratios. Al-rich relic material from the formation of the rapakivi granite melt is another source of assimilation. Most probably contaminants are heterogeneous, including undepleted crust (represented, for example, by early Svecofennian and Archaean granitoids), depleted crust (restitic after rapakivi magma extraction), and to some degree the associated rapakivi magma itself. Significant parts of this crust should be Archaean in age.

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Magnetite texture and trace-element geochemistry fingerprint of pulsed mineralization in the Xinqiao Cu-Fe-Au deposit, Eastern China

American Mineralogist ◽

10.2138/am-2020-7414 ◽

2020 ◽

Vol 105 (11) ◽

pp. 1712-1723

Author(s):

Yu Zhang ◽

Pete Hollings ◽

Yongjun Shao ◽

Dengfeng Li ◽

Huayong Chen ◽

...

Keyword(s):

Trace Element ◽

Triple Junction ◽

Eastern China ◽

Black Shales ◽

Hydrothermal Fluids ◽

Oscillatory Zoning ◽

Trace Element Geochemistry ◽

Element Geochemistry ◽

Rock Interaction ◽

Multiple Pulses

Abstract The origin of stratabound deposits in the Middle-Lower Yangtze River Valley Metallogenic Belt (MLYRB), Eastern China, is the subject of considerable debate. The Xinqiao Cu-Fe-Au deposit in the Tongling ore district is a typical stratabound ore body characterized by multi-stage magnetite. A total of six generations of magnetite have been identified. Mt1 is commonly replaced by porous Mt2, and both are commonly trapped in the core of Mt3, which is characterized by both core-rim textures and oscillatory zoning. Porous Mt4 commonly truncates the oscillatory zoning of Mt3, and Mt5 is characterized by 120° triple junction texture. Mt1 to Mt5 are commonly replaced by pyrite that coexists with quartz, whereas Mt6, with a fine-grained foliated and needle-like texture, commonly cuts the early pyrite as veins and is replaced by pyrite that coexists with calcite. The geochemistry of the magnetite suggests that they are hydrothermal in origin. The microporosity of Mt2 and Mt4 magnetite, their sharp contacts with Mt1 and Mt3, and lower trace-element contents (e.g., Si, Ca, Mg, and Ti) than Mt1 and Mt3 suggest that they formed via coupled dissolution and reprecipitation of the precursor Mt1 and Mt3 magnetite, respectively. This was likely caused by high-salinity fluids derived from intensive water-rock interaction between the magmatic-hydrothermal fluids associated with the Jitou stock and Late Permian metalliferous black shales. The 120° triple junction texture of Mt5 suggests it is the result of fluid-assisted recrystallization, whereas Mt6 formed by replacement of hematite as a result of fracturing. The geochemistry of the magnetite suggests that the temperature increased from Mt2 to Mt3 and implies that there were multiple pulses of fluids from a magmatic-hydrothermal system. Therefore, we propose that the Xinqiao stratiform mineralization was genetically associated with multiple influxes of magmatic hydrothermal fluids derived from the Early Cretaceous Jitou stock. This study demonstrates that detailed texture examination and in situ trace-elements analysis under robust geological and petrographic frameworks can effectively constrain the mineralization processes and ore genesis.

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The role of sulphur on the melting of Ca-poor sediment and on trace element transfer in subduction zones: an experimental investigation

Journal of Petrology ◽

10.1093/petrology/egab005 ◽

2021 ◽

Author(s):

Anne-Aziliz Pelleter ◽

Gaëlle Prouteau ◽

Bruno Scaillet

Keyword(s):

Trace Element ◽

Partial Melting ◽

Subduction Zones ◽

Sediment Flux ◽

Arc Magmas ◽

Trace Element Contents ◽

The Stability ◽

Element Transfer ◽

High Sediment

Abstract We performed phase equilibrium experiments on a natural Ca-poor pelite at 3 GPa, 750-1000 °C, under moderately oxidizing conditions, simulating the partial melting of such lithologies in subduction zones. Experiments investigated the effect of sulphur addition on phase equilibria and compositions, with S contents of up to ∼ 2.2 wt. %. Run products were characterized for their major and trace element contents, in order to shed light on the role of sulphur on the trace element patterns of melts produced by partial melting of oceanic Ca-poor sediments. Results show that sulphur addition leads to the replacement of phengite by biotite along with the progressive consumption of garnet, which is replaced by an orthopyroxene-kyanite assemblage at the highest sulphur content investigated. All Fe-Mg silicate phases produced with sulphur, including melt, have higher MgO/(MgO+FeO) ratios (relative to S-free/poor conditions), owing to Fe being primarily locked up by sulphide in the investigated redox range. Secular infiltration of the mantle wedge by such MgO and K2O-rich melts may have contributed to the Mg and K-rich character of the modern continental crust. Addition of sulphur does not affect significantly the stability of the main accessory phases controlling the behaviour of trace elements (monazite, rutile and zircon), although our results suggest that monazite solubility is sensitive to S content at the conditions investigated. The low temperature (∼ 800 °C) S-bearing and Ca-poor sediment sourced slab melts show Th and La abundances, Th/La systematics and HFSE signatures in agreement with the characteristics of sediment-rich arc magmas. Because high S contents diminish phengite and garnet stabilities, S-rich and Ca-poor sediment sourced slab melts have higher contents of Rb, B, Li (to a lesser extent), and HREE. The highest ratios of La/Yb are observed in sulphur-poor runs (with a high proportion of garnet, which retains HREE) and beyond the monazite out curve (which retains LREE). Sulphides appear to be relatively Pb-poor and impart high Pb/Ce ratio to coexisting melts, even at high S content. Overall, our results show that Phanerozoic arc magmas from high sediment flux margins owe their geochemical signature to the subduction of terrigenous, sometimes S-rich, sediments. In contrast, subduction of such lithologies during Archean appears unlikely or unrecorded.

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