Solid-State Amorphization in a Ti/B Multilayer
Thin films of pure crystalline metals, that have a negative heat of mixing, are known to amorphize. Solid-state amorphization reactions are possible to study using multilayered structures. The amorphization reaction is typically observed in multilayered structures in which one layer of the pair is crystalline and the adjacent layer or interface is amorphous, as in Ni/Zr and Cu/Y. The reaction progresses via a low temperature isothermal anneal (at several hundred degrees centigrade) in which one species preferentially diffuses into the other. Recently, in-situ observation of solid-state amorphization in a completely crystalline Ni/Ti multilayer indicates that nucleation of the amorphous phase occurs at incoherent crystalline interlayer boundaries. (The completely crystalline as-deposited structure was achieved by ensuring thermalization of the sputtered neutrals.) The progression of solidstate amorphization in Ti-B is examined using the multilayered configuration.