A scanning electron microscope study of defects in PTC materials
BaTiO3 and its solid solutions with PbTiO3 and SrTiO3 are normally insulators but, when doped with small amounts of trivalent ions, they become semiconducting. Materials in this family also possess a positive temperature coefficient of resistance (an increase in resistance with increasing temperature) over a limited temperature range and are often referred to as PTCs. The temperature where the PTC region begins is determined by the Ba/Pb/Sr ratio.The materials are generally prepared by solid state reaction of a mixture of oxides and carbonates which is subsequently sintered into a solid form. The electrical properties of such a body, in particular properties such as inrush current capability and voltage breakdown, are critically affected by microdefects in the materials which often originate during processing. The SEM is an ideal tool for studying such defects since they generally manifest themselves as localized variations in resistance.