What you see and what you get: combining near-infrared spectroscopy with powder diffraction

2017 ◽  
Vol 32 (S2) ◽  
pp. S3-S8
Author(s):  
Helen E. Maynard-Casely ◽  
Norman Booth ◽  
Leo Anderberg ◽  
Helen E.A. Brand ◽  
Daniel V. Cotton
Keyword(s):  
Remote Sensing ◽  
Infrared Spectroscopy ◽  
Near Infrared ◽  
Surface Composition ◽  
Planetary Surfaces ◽  
X Ray Diffraction ◽  
X Ray ◽  
Near Ir ◽  
Infra Red ◽  
Terrestrial Environments

Knowledge of the surface composition of planetary bodies comes from a number of sources; such as landers, remote sensing and meteorites. However, the bulk mapping of the composition of planetary surfaces has been undertaken by analysis of reflected sunlight and these data—principally collected in the near-infra-red (IR) region—are notoriously broad and ambiguous. Hence, if laboratory spectra could be tied to physical properties measurements, such as diffraction, this would substantially aid our understanding of processes occurring in these extra-terrestrial environments. This contribution presents the capability of collecting near-IR data at the same time as neutron and synchrotron X-ray diffraction in a range of conditions (low temperature, vacuum, and humidity variations) and highlights two examples where this capability could enhance our understanding of planetary surfaces.

X-ray diffraction and infrared characterization of Oxisols from central and southeastern Brazil

Clay Minerals ◽  
2008 ◽  
Vol 43 (4) ◽  
pp. 549-560 ◽  
Author(s):  
R. P. Nitzsche ◽  
J. B. Percival ◽  
J. K. Torrance ◽  
J. A. R. Stirling ◽  
J. T. Bowen
Keyword(s):  
Remote Sensing ◽  
Near Infrared ◽  
Microwave Remote Sensing ◽  
Short Wave ◽  
Southeastern Brazil ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sensing Applications ◽  
Remote Sensing Applications

AbstractEleven Oxisols with high clay contents, 2.6–59.7 wt.% Fe2O3, and containing hematite, goethite, magnetite and maghemite, from São Paulo, Minas Gerais and Goiás, Brazil, were studied for the purpose of microwave remote sensing applications in the 0.3 to 300 GHz range. Of special interest are: the pseudosand effect caused by Fe-oxide cementation of clusters of soil particles; the mineralogy; and whether the soil magnetic susceptibility affected by ferromagnetic magnetite and maghemite interferes with microwave propagation. Quantitative mineralogical analyses were conducted using X-ray diffraction with Rietveld refinement. Visible, near infrared and short wave infrared spectroscopic analyses were used to characterize the samples qualitatively for comparison with published spectral radiometry results. Quartz (3–88%), hematite (2–36%) and gibbsite (1–40%) occurred in all soils, whereas kaolinite (2–70%) and anatase (2–13%) occurred in nine samples. Ilmenite (1–8%) was found in eight soils and goethite (2–39%) in seven. Of the ferromagnetic minerals, maghemite occurred in seven soils (1–13%) and three contained magnetite (<2%). These results will be applied to the interpretation of the effect of Fe oxides, particularly the ferromagnetic oxides, on microwave interaction with high-Fe soils, with ultimate application to the monitoring of soil water content by microwave remote sensing.

APPLICATION OF NEAR INFRARED SPECTROSCOPY TO THE EXTRACTED WOOD OF A DIVERSE RANGE OF SPECIES

IAWA Journal ◽  
2003 ◽  
Vol 24 (4) ◽  
pp. 429-438 ◽  
Author(s):  
Laurence Schimleck ◽  
Robert Evans ◽  
Jugo Ilic
Keyword(s):  
Infrared Spectroscopy ◽  
Physical Properties ◽  
Near Infrared ◽  
Microfibril Angle ◽  
Nir Spectroscopy ◽  
X Ray Diffraction ◽  
Wood Chemistry ◽  
Diverse Range ◽  
X Ray ◽  
Longitudinal Modulus

Near infrared (NIR) spectroscopy was applied to fifty-four species (59 samples in total) representing a diverse array of taxonomic affiliations, wood chemistry and physical properties. Acetone and ethanol were used to remove extractives from the wood samples used in this study. The extracted samples were characterized in terms of collapse-free density, microfibril angle and longitudinal modulus of elasticity (estimated using the collapse-free density and X-ray diffraction data obtained from Silvi- Scan-2). NIR spectra were obtained from the radial longitudinal face of each sample and used to generate calibrations for the measured physical properties. Extraction was found to improve the calibration statistics for all properties.

Stichtite: a review

Clay Minerals ◽  
2013 ◽  
Vol 48 (1) ◽  
pp. 143-148 ◽  
Author(s):  
F. L. Theiss ◽  
G. A. Ayoko ◽  
R. L. Frost
Keyword(s):  
Infrared Spectroscopy ◽  
Near Infrared ◽  
Microprobe Analysis ◽  
Electron Microprobe Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Naturally Occurring ◽  
Geological Origin ◽  
Double Hydroxide ◽  
The Ideal

AbstractStichtite is a naturally occurring layered double hydroxide (LDH) with the ideal chemical formula Mg6Cr2CO3(OH)16.4H2O. It has received less attention in the literature than other LDHs and is often described as a rare mineral; however, abundant deposits of the mineral do exist. In this article we aim to review a number of significant publications concerning the mineral stichtite, including papers covering the discovery, geological origin, synthesis and characterizsation of stichtite. Characterization techniques reviewed include powder X-ray diffraction (XRD), infrared spectroscopy (IR), near infrared spectroscopy (NIR), Raman spectroscopy (Raman), thermogravimetry (TG) and electron microprobe analysis.

Intercalation of N-methylformamide in kaolinite: In situ monitoring by near-infrared spectroscopy and X-ray diffraction

2021 ◽  
Vol 212 ◽  
pp. 106209
Author(s):  
Fevronia T. Andreou ◽  
Barbara Barylska ◽  
Zuzanna Ciesielska ◽  
Marek Szczerba ◽  
Arkadiusz Derkowski ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
In Situ Monitoring ◽  
X Ray Diffraction ◽  
X Ray

Electron Microscopy of Human Gallstones

1971 ◽  
Vol 29 ◽  
pp. 296-297
Author(s):  
C. Wolpers ◽  
R. Blaschke
Keyword(s):  
Electron Microscopy ◽  
Room Temperature ◽  
Bile Pigment ◽  
X Ray Diffraction ◽  
Triclinic Crystal System ◽  
X Ray ◽  
Follow Up Study ◽  
Infra Red ◽  
Main Components

Scanning microscopy was used to study the surface of human gallstones and the surface of fractures. The specimens were obtained by operation, washed with water, dried at room temperature and shadowcasted with carbon and aluminum. Most of the specimens belong to patients from a series of X-ray follow-up study, examined during the last twenty years. So it was possible to evaluate approximately the age of these gallstones and to get information on the intensity of growing and solving.Cholesterol, a group of bile pigment substances and different salts of calcium, are the main components of human gallstones. By X-ray diffraction technique, infra-red spectroscopy and by chemical analysis it was demonstrated that all three components can be found in any gallstone. In the presence of water cholesterol crystallizes in pane-like plates of the triclinic crystal system.

PENGGUNAAN TiO2 PARTIKEL NANO HASIL SINTESIS BERBASIS AIR MENGGUNAKAN METODA SOL-GEL PADA BAHAN KAPAS SEBAGAI APLIKASI UNTUK TEKSTIL ANTI UV

Arena Tekstil ◽  
2013 ◽  
Vol 28 (1) ◽  
Author(s):  
Maya Komalasari ◽  
Bambang Sunendar
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Sol Gel ◽  
Crosslinking Agent ◽  
X Ray Diffraction ◽  
Nano Tio2 ◽  
X Ray ◽  
Infra Red ◽  
Scanning Electron

Partikel nano TiO2 berbasis air dengan pH basa telah berhasil disintesis dengan menggunakan metode sol-gel dan diimobilisasi pada kain kapas dengan menggunakan kitosan sebagai zat pengikat silang. Sintesis dilakukan  dengan prekursor TiCl4 pada konsentrasi 0,3 M, 0,5 M dan 1 M, dan menggunakan templat kanji dengan proses kalsinasi pada suhu 500˚C selama 2 jam. Partikel nano TiO2 diaplikasikan ke kain kapas dengan metoda pad-dry-cure dan menggunakan kitosan sebagai crosslinking agent. Berdasarkan hasil Scanning Electron Microscope (SEM),diketahui bahwa morfologi partikel TiO2 berbentuk spherical dengan ukuran nano (kurang dari 100 nm). Karakterisasi X-Ray Diffraction (XRD) menunjukkan adanya tiga tipe struktur kristal utama, yaitu (100), (101) dan (102) dengan fasa kristal yang terbentuk adalah anatase dan rutile. Pada karakterisasi menggunakan SEM terhadap serbuk dari TiO2 yang telah diaplikasikan ke permukaan kain kapas, terlihat adanya imobilisasi partikel nano TiO2 melalui ikatan hidrogen silang dengan kitosan pada kain kapas. Hasil analisa tersebut kemudian dikonfirmasi dengan FTIR (Fourier Transform Infra Red) yang hasilnya memperlihatkan puncak serapan pada bilangan gelombang 3495 cm-1, 2546 cm-1, dan 511 cm-1,  yang masing-masing diasumsikan sebagai adanya vibrasi gugus fungsi O-H, N-H dan Ti-O-Ti. Hasil SEM menunjukkan pula bahwa kristal nano yang terbentuk diantaranya adalah fasa rutile , yang berdasarkan literatur terbukti dapatberfungsi sebagai anti UV.

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