Effect of Chemical Partition Behavior on Oil Recovery by Wettability Alteration in Fractured Tight Reservoirs

Author(s):  
Tesleem Lawal ◽  
Mingyuan Wang ◽  
Gayan A. Abeykoon ◽  
Francisco J. Argüelles-Vivas ◽  
Ryosuke Okuno
Author(s):  
Shuai Li ◽  
Yunhong Ding ◽  
Guangfeng Liu ◽  
Daihong Gu ◽  
Bo Cai

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Zhijie Wei ◽  
Yuyang Liu ◽  
Xiaodong Kang

Low primary recovery factor and rapid production decline necessitates the proposal of enhanced oil recovery methods to mobilize the remaining oil resource of tight reservoirs, especially for oil-wet ones, and wettability alteration by injecting a chemical agent such as a surfactant is a promising option. A discrete-fracture-network-based mathematical model is developed with consideration of the displacement mechanisms and complicated physical-chemical phenomena during EOR by wettability alteration, and this model numerically solved by the fully implicit method. Simulation cases are conducted to investigate the production performance and key factors of cyclic injection of a surfactant. Cyclic injection can significantly improve the production of oil-wet tight reservoirs, and the ultimate recovery factor can be increased by 10 percent. The reason is that a surfactant can alter the wettability of a reservoir from oil wet to medium or even water wet, which triggers spontaneous imbibition and favors oil movement from a matrix into a fracture. Better EOR results can be achieved with decreasing oil viscosity, increasing matrix permeability, or decreasing fracture spacing. Cyclic surfactant injection is applicable to reservoirs with an oil viscosity of less than 7 mPa·s, a matrix permeability bigger than 0.01 mD, or a fracture spacing smaller than 150 m. It is favorable for the wettability alteration method by maintaining capillary pressure and reducing residual oil saturation as much as possible.


Fuel ◽  
2021 ◽  
Vol 291 ◽  
pp. 119986
Author(s):  
Z. Zhang ◽  
Madhar Sahib Azad ◽  
J.J. Trivedi

2021 ◽  
Author(s):  
Xu-Guang Song ◽  
Ming-Wei Zhao ◽  
Cai-Li Dai ◽  
Xin-Ke Wang ◽  
Wen-Jiao Lv

AbstractThe ultra-low permeability reservoir is regarded as an important energy source for oil and gas resource development and is attracting more and more attention. In this work, the active silica nanofluids were prepared by modified active silica nanoparticles and surfactant BSSB-12. The dispersion stability tests showed that the hydraulic radius of nanofluids was 58.59 nm and the zeta potential was − 48.39 mV. The active nanofluids can simultaneously regulate liquid–liquid interface and solid–liquid interface. The nanofluids can reduce the oil/water interfacial tension (IFT) from 23.5 to 6.7 mN/m, and the oil/water/solid contact angle was altered from 42° to 145°. The spontaneous imbibition tests showed that the oil recovery of 0.1 wt% active nanofluids was 20.5% and 8.5% higher than that of 3 wt% NaCl solution and 0.1 wt% BSSB-12 solution. Finally, the effects of nanofluids on dynamic contact angle, dynamic interfacial tension and moduli were studied from the adsorption behavior of nanofluids at solid–liquid and liquid–liquid interface. The oil detaching and transporting are completed by synergistic effect of wettability alteration and interfacial tension reduction. The findings of this study can help in better understanding of active nanofluids for EOR in ultra-low permeability reservoirs.


Energies ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1998
Author(s):  
Haishan Luo ◽  
Kishore K. Mohanty

Unlocking oil from tight reservoirs remains a challenging task, as the existence of fractures and oil-wet rock surfaces tends to make the recovery uneconomic. Injecting a gas in the form of a foam is considered a feasible technique in such reservoirs for providing conformance control and reducing gas-oil interfacial tension (IFT) that allows the injected fluids to enter the rock matrix. This paper presents a modeling strategy that aims to understand the behavior of near-miscible foam injection and to find the optimal strategy to oil recovery depending on the reservoir pressure and gas availability. Corefloods with foam injection following gas injection into a fractured rock were simulated and history matched using a compositional commercial simulator. The simulation results agreed with the experimental data with respect to both oil recovery and pressure gradient during both injection schedules. Additional simulations were carried out by increasing the foam strength and changing the injected gas composition. It was found that increasing foam strength or the proportion of ethane could boost oil production rate significantly. When injected gas gets miscible or near miscible, the foam model would face serious challenges, as gas and oil phases could not be distinguished by the simulator, while they have essentially different effects on the presence and strength of foam in terms of modeling. We provide in-depth thoughts and discussions on potential ways to improve current foam models to account for miscible and near-miscible conditions.


SPE Journal ◽  
2013 ◽  
Vol 18 (05) ◽  
pp. 818-828 ◽  
Author(s):  
M. Hosein Kalaei ◽  
Don W. Green ◽  
G. Paul Willhite

Summary Wettability modification of solid rocks with surfactants is an important process and has the potential to recover oil from reservoirs. When wettability is altered by use of surfactant solutions, capillary pressure, relative permeabilities, and residual oil saturations change wherever the porous rock is contacted by the surfactant. In this study, a mechanistic model is described in which wettability alteration is simulated by a new empirical correlation of the contact angle with surfactant concentration developed from experimental data. This model was tested against results from experimental tests in which oil was displaced from oil-wet cores by imbibition of surfactant solutions. Quantitative agreement between the simulation results of oil displacement and experimental data from the literature was obtained. Simulation of the imbibition of surfactant solution in laboratory-scale cores with the new model demonstrated that wettability alteration is a dynamic process, which plays a significant role in history matching and prediction of oil recovery from oil-wet porous media. In these simulations, the gravity force was the primary cause of the surfactant-solution invasion of the core that changed the rock wettability toward a less oil-wet state.


2011 ◽  
Vol 236-238 ◽  
pp. 2135-2141
Author(s):  
Qi Cheng Liu ◽  
Yong Jian Liu

Molecular film displacement is a new nanofilm EOR technique. A large number of experiments show that the mechanism of molecular film displacement is different from conventional chemical displacement (polymer, surfactant, alkali and ASP displacement etc). With water solution acting as transfer medium, molecules of the filming agent develop the force to form films through electrostatic interaction, with efficient molecules deposited on the negatively charged rock surface to form ultrathin films at nanometer scale. This change the properties of reservoir surface and the interaction condition with crude oil, making the oil easily be displaced as the pores swept by the injected fluid. Thus oil recovery is enhanced. The mechanism of molecular filming agent mainly includes absorption, wettability alteration, diffusion and capillary imbibition etc.


2014 ◽  
Vol 695 ◽  
pp. 499-502 ◽  
Author(s):  
Mohamad Faizul Mat Ali ◽  
Radzuan Junin ◽  
Nor Hidayah Md Aziz ◽  
Adibah Salleh

Malaysia oilfield especially in Malay basin has currently show sign of maturity phase which involving high water-cut and also pressure declining. In recent event, Malaysia through Petroliam Nasional Berhad (PETRONAS) will be first implemented an enhanced oil recovery (EOR) project at the Tapis oilfield and is scheduled to start operations in 2014. In this project, techniques utilizing water-alternating-gas (WAG) injection which is a type of gas flooding method in EOR are expected to improve oil recovery to the field. However, application of gas flooding in EOR process has a few flaws which including poor sweep efficiency due to high mobility ratio of oil and gas that promotes an early breakthrough. Therefore, a concept of carbonated water injection (CWI) in which utilizing CO2, has ability to dissolve in water prior to injection was applied. This study is carried out to assess the suitability of CWI to be implemented in improving oil recovery in simulated sandstone reservoir. A series of displacement test to investigate the range of recovery improvement at different CO2 concentrations was carried out with different recovery mode stages. Wettability alteration properties of CWI also become one of the focuses of the study. The outcome of this study has shown a promising result in recovered residual oil by alternating the wettability characteristic of porous media becomes more water-wet.


SPE Journal ◽  
2022 ◽  
pp. 1-13
Author(s):  
Song Qing ◽  
Hong Chen ◽  
Li-juan Han ◽  
Zhongbin Ye ◽  
Yihao Liao ◽  
...  

Summary α-Zirconium phosphate (α-ZrP) nanocrystals were synthesized by refluxing method and subsequently exfoliated into extremely thin 2D nanosheets by tetrabutylammonium hydroxide (TBAOH) solution. Dynamic light scattering, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were used to characterize the size distribution and morphology of α-ZrP nanosheets. Interfacial tension (IFT) and contact angle measurement were conducted by different concentrations of α-ZrP nanosheets solutions. The results displayed that the wettability of porous media surface was altered from oleophilic to hydrophilic and the IFT decreased with the increasing of α-ZrP nanosheets concentrations. A new method was proposed to calculate the Hamaker constant for 2D α-ZrP nanosheets. The calculated results displayed that α-ZrP nanosheets were not easy to agglomerate under experimental environment and when the interaction energy barrier increased, the transport amount of α-ZrP nanosheets also increased. Coreflooding tests were also performed with various concentrations and the oil recovery efficiency increased from 33.59 to 51.26% when α-ZrP nanosheets concentrations increased from 50 to 1,000 ppm.


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