Absolute Rates of Coke Formation:  A Relative Measure for the Assessment of the Chemical Behavior of High-Temperature Steels of Different Sources

1998 ◽  
Vol 37 (11) ◽  
pp. 4302-4305 ◽  
Author(s):  
Gerhard Zimmermann ◽  
Wolfgang Zychlinski ◽  
Harry M. Woerde ◽  
Paul van den Oosterkamp
2004 ◽  
Vol 126 (1) ◽  
pp. 9-19 ◽  
Author(s):  
A. K. Gupta

Recent advances on high temperature air combustion (HiTAC) have demonstrated significant energy savings, higher and uniform thermal field, lower pollution, and smaller size of the equipment for a range of furnace applications. The HiTAC technology has evolved from the conception of excess enthalpy combustion (EEC) to high and ultra-high preheated air combustion. In the HiTAC method, combined heat regeneration and low oxygen methods are utilized to enlarge and control the flame thermal behavior. This technology has shown promise for much wider applications in various process and power industries, energy conversion, and waste to clean fuel conversion. For each application the flow, thermal, and chemical behavior of HiTAC flames must be carefully tailored to satisfy the specific needs. Qualitative and quantitative results are presented on several gas-air diffusion flames using high-temperature combustion air. A specially designed regenerative combustion test furnace facility, built by Nippon Furnace Kogyo, Japan, was used to preheat the combustion air to elevated temperatures. The flames with highly preheated combustion air were significantly more stable and homogeneous (both temporally and spatially) as compared to the flames with room-temperature combustion air. The global flame features showed the flame color to change from yellow to blue to bluish-green to green over the range of conditions examined. In some cases hybrid and purple color flame was also observed. Under certain conditions flameless or colorless oxidation of the fuel has also been demonstrated. Information on global flame features, flame spectral emission characteristics, spatial distribution of OH, CH, and C2 species and emission of pollutants has been obtained. Low levels of NOx along with negligible levels of CO and HC have been obtained using high-temperature combustion air. The thermal and chemical behavior of high-temperature air combustion flames depends on fuel property, preheat temperature, and oxygen concentration of air. Waste heat from a furnace in high-temperature air combustion technology is retrieved and introduced back into the furnace using regenerator. These features help save energy, which subsequently also reduce the emission of CO2 (greenhouse gas) to the environment. Flames with high temperature air provide significantly higher and uniform heat flux than normal air, which reduces the equipment size or increases the process material throughput for same size of the equipment. The high-temperature air combustion technology can provide significant energy savings (up to about 60%), downsizing of the equipment (about 30%), and pollution reduction (about 25%). Fuel energy savings directly translates to a reduction of CO2 and other greenhouse gases to the environment.


2020 ◽  
Vol 191 ◽  
pp. 5
Author(s):  
Jessica Uzel ◽  
Yves Lagabrielle ◽  
Serge Fourcade ◽  
Christian Chopin ◽  
Pierre Monchoux ◽  
...  

Sapphirine-bearing rocks are described in the Aulus Basin (Ariège, France) in a contact zone between the Lherz peridotitic body and Mesozoic metasediments which underwent the Pyrenean Cretaceous high-temperature, low-pressure metamorphic event (Monchoux, 1970, 1972a, 1972b). Sapphirine crystals occur in layered clastic deposits characterized by an uncommon suite of Al-Mg-rich minerals. A detailed petrographic study of sixteen samples representative of the diversity of the Lherz sapphirine-bearing rocks is presented. These rocks include breccias and microbreccias with various compositions. Some samples are composed of polymineralic clasts and isolated minerals that derive from regionally well-known protoliths such as ultramafic rocks, meta-ophites, “micaceous hornfels”, and very scarce Paleozoic basement rocks. Nevertheless, a large portion of the sapphirine-bearing clastic suite is composed of mono- and polymineralic debris that derive from unknown protolith(s). We define a "sapphirine-bearing mineral suite” (SBMS) composed of monomineralic debris including: sapphirine + enstatite + aluminous spinel + Mg-amphiboles + Ca-amphiboles + kornerupine + accessory minerals (apatite, diopside, rutile, serpentine, smectite, tourmaline, vermiculite and a white mica). We highlight the dominance of metamorphic Keuper clastic materials in the studied rocks and the presence of inclusions of anhydrite and F-, Cl-, Sr-rich apatite in minerals of the Al-Mg-rich suite. The brecciated texture and the presence of unequivocal sedimentary features suggest that the sapphirine-bearing rocks were mechanically disaggregated and then experienced winnowing in underwater conditions with poor mixing between the different sources. We measured U-Pb rutile age data in order to provide constraints on the age of (one of) the protolith(s) of those clastic deposits. The obtained age (98.6 + 1.2 Ma) is interpreted as the age of metamorphism of this protolith of the SBMS. Previous works interpreted the Lherz sapphirine-bearing rocks as crustal protoliths modified at depth along the contact with the ultramafic rocks of the Lherz body during their ascent towards shallower depths. These new data imply: (i) an Upper Triassic to Lower Jurassic origin for the main protolith of the sapphirine-bearing rocks; (ii) the metamorphism of this protolith along an active hot crust–mantle detachment during Cenomanian times with the involvement of metasomatic, brine-type fluids; and (iii) its brecciation during the exhumation of the material due to the evolution of the detachment, followed by subsequent sedimentary reworking of the metamorphic material.


2001 ◽  
Vol 180 (3-4) ◽  
pp. 227-245 ◽  
Author(s):  
T Paulmier ◽  
M Balat-Pichelin ◽  
D Le Quéau ◽  
R Berjoan ◽  
J.F Robert

Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1284 ◽  
Author(s):  
Mohammed Al-asadi ◽  
Norbert Miskolczi

This work is dedicated to the high temperature pyrolysis of municipal plastic waste using Me/Ni/ZSM-5 catalysts. Catalysts were synthetized by wet impregnation. In addition to nickel, synthetic zeolite catalysts contain calcium, ceria, lanthanum, magnesia or manganese. Catalysts were prepared and tested using 0.1, 0.5 and 2.0 Me/Ni ratios. Catalyst morphology was investigated by SEM and surface analysis. Higher concentrations of second metals can block catalyst pore channels due to the more coke formation, which leads to smaller surface area. Furthermore, the chemicals used for the impregnation were among the catalyst grains, especially in case of 2.0 Me/Ni ratios. For pyrolysis, a horizontal tubular furnace reactor was used at 700 °C. The highest hydrogen and syngas yields were observed using ceria- and lanthanum-covered catalysts. The maximum production of syngas and hydrogen (69.8 and 49.2 mmol/g raw material) was found in the presence of Ce/Ni/ZSM-5 catalyst with a 0.5 Me/Ni ratio.


2021 ◽  
Vol 283 ◽  
pp. 119642
Author(s):  
Dhruba J. Deka ◽  
Jaesung Kim ◽  
Seval Gunduz ◽  
Deeksha Jain ◽  
Yingjie Shi ◽  
...  

2011 ◽  
Vol 50 (13) ◽  
pp. 8371-8375 ◽  
Author(s):  
Jason Millichamp ◽  
Ebrahim Ali ◽  
Nigel P. Brandon ◽  
Richard J. C. Brown ◽  
David Hodgson ◽  
...  

Author(s):  
Jinlong Du ◽  
Fengxia Zhang ◽  
Jianhang Hu ◽  
Shiliang Yang ◽  
Huili Liu ◽  
...  

2006 ◽  
Vol 514-516 ◽  
pp. 935-939
Author(s):  
M. Carmo Lança ◽  
Eugen R. Neagu ◽  
Len A. Dissado ◽  
José N. Marat-Mendes

Cross-linked polyethylene (XLPE) peelings from aged power cables from three different sources were studied using a combined procedure of isothermal and thermo-stimulated current measurements. Different parameters, such as electric field, temperature, charging/discharging times, can be selected in order to make an analysis of the space charge characteristics (such as, relaxation times and activation energies). Three different cables peelings were analyzed: A – electrically aged in the laboratory at high temperature, B – service aged for 18 years and C – thermally aged in the laboratory at high temperature. The results were compared for the different types of samples and also with previous results on laboratory aged and produced films of low-density polyethylene (LDPE) and XLPE.


2013 ◽  
Vol 750-752 ◽  
pp. 1712-1717 ◽  
Author(s):  
Ning Wang ◽  
Jin Zhou ◽  
Yu Pan ◽  
Hui Wang

Coking characteristics of China RP-3 under high temperature (above 650°C) and long-duration (20 minutes) conditions, especially the effects of temperature, pressure, and inner diameter of cooling channels on coking amount were experimentally investigated. Temperature of kerosene in experiments varied from 650°C to 730°C, pressure varied from 1.8MPa to 3.5MPa, and the mass flow rate was approximately 120g/min. Results showed that temperature has a significant influence on coking amount. Even a small increment of temperature induces remarkable coke formation. However, pressure and inner diameter of the tube has a relatively little effect on it. The coking amount increases as pressure and inner diameter increase, but the increasing rate is decreasing. It is considered that inner diameter mainly affects residence time. When residence time increases to some extent, coking amount begins to grow slowly even stop increasing. This is resulted from two reasons. Firstly, the cracking conversion percentage reaches an upper limit when residence time is adequately long; secondly, coke gradually covers the inner wall of the tube, leading to isolation of kerosene from the metal surface to form coking.


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