Magnetic Measurements on Some Catalytically Active Substances

1943 ◽  
Vol 65 (11) ◽  
pp. 2245-2252 ◽  
Author(s):  
Humbert Morris ◽  
P. W. Selwood
2019 ◽  
Vol 8 (1) ◽  
pp. 865-872 ◽  
Author(s):  
Zhenfeng Wang ◽  
Yanan Huang ◽  
Huijuan Luo ◽  
Zhijun Gong ◽  
Kai Zhang ◽  
...  

Abstract Rare earth tailings from the Bayan Obo mine are rich in rare earth, iron, and other catalytically active substances. In this study, Na2CO3 and Ca(OH)2 were mixed with rare earth tailings, roasted, and the tailings modified by HCl-citric acid leaching and pickling to prepare high-performance rare earth tailings-based denitrification catalysts. Denitrification performance tests show that, in the temperature range 700°C~900°C, the alkali and acid co-processed modified tailings sample gave the best catalytic denitrification performance. XRD, SEM, and H2-TPR analyses show that, compared with raw ore samples, Fe activity sites increased after alkali and acid co-treatment. Cracks and holes appeared on the surface of the sample, and the reduction temperature range was broadened. XPS analysis showed that Fe coexisted in the forms Fe2+ and Fe3+, and Ce in the forms Ce3+ and Ce4+. At a rare earth tailings microwave roasting temperature of 500°C, NO concentration of 500 ppm, CO/NO ratio 4:1, and reaction temperature of 900°C, the denitrification efficiency of the catalyst was optimal, at up to 96.2%. In this study, a relatively green and pollution-free method was used to prepare catalysts, which can provide reference for solving the problem of rare earth tailings accumulation.


2015 ◽  
Vol 820 ◽  
pp. 113-118 ◽  
Author(s):  
Joelda Dantas ◽  
Francisco Nilson da Silva ◽  
Kleberson Ricardo de Oliveira Pereira ◽  
Adriano Santana Silva ◽  
A.C.F. de M. Costa

Magnetic catalysts are easily removed from the reaction process, thereby reducing the wastewater generation. Therefore, the study proposes to evaluate the performance of the nanomagnetic catalyst Ni0.5Zn0.5Fe2O4 in the transesterification reaction of the soybean oil to produce biodiesel, varying processing conditions (temperature, molar ratio of oil:alcohol and catalyst amount) on the catalytic reaction. The catalyst was synthesized by combustion reaction and characterized by XRD, BET, magnetic measurements and gas chromatography. The results revealed the inverse spinel phase formation, type B(AB)2O4, with isotherm profile classified as type V with hysteresis loop of type 3 (H3), and surface area of ​​48.39 m2g-1. The magnetic hysteresis curve showed a characteristic behavior of soft magnetic material with saturation magnetization value of 55 emu/g. Chromatographic analysis confirmed that the magnetic nanoparticles are catalytically active and that the processing conditions directly influence the conversion into esters.


2017 ◽  
Vol 84 (1) ◽  
Author(s):  
Johannes Kiefer ◽  
Andreas Bösmann ◽  
Peter Wasserscheid

AbstractIn the past two decades, ionic liquids have found many applications as solvents for complex solutes. Prominent examples are the dissolution of biomass and carbohydrates as well as catalytically active substances. The chemical analysis of such solutions, however, is still a challenge due to the molecular complexity. In the present work, the use of infrared spectroscopy for quantifying the concentration of different solutes dissolved in an imidazolium-based ionic liquid is investigated. Binary solutions of glucose, cellubiose, and Wilkinson's catalyst in 1-ethyl-3-methylimidazolium acetate are studied as examples. For this purpose, different chemometric approaches (principal component analysis (PCA), partial least-squares regression (PLSR), and principal component regression (PCR)) for analyzing the spectra are tested. Principal component analysis was found to be suitable for classifying the different solutions. Both regression techniques were capable of deriving accurate concentration values. The performance of PLSR was slightly better than that of PCR for the same number of components.


Author(s):  
A. V. Dunaev ◽  
M. N. Kostomakhin

An effective technique in the improvement of wear resistance and resource especially wornout friction is provided in the surface parts of anti-friction tribological coatings of various compositions entered in the regular lubrication maintenance of machines and equipment [1, 5, 7–10, 12–17]. Approved since 1930 [10] they during maintenance of machinery and equipment allows 2–3 times to increase their service life, 5–20 % reduced consumption of fuel and electricity, up to 30 % operating costs [7, 9, 10, 13, 14]. Introduction to oil chemically active substances, suspensions of particles of natural and artificial minerals, the oil solutions of the active organic substances, metal salts of organic acids [7, 17], the electric charge consumption less than 1 W [4, 6, 11], creating a wear-reducing coating [2, 5, 8, 12, 15–17], enhance adhesion of the lubricant is technically and economically justified, with a margin of 500–800 % or more [1, 3, 5, 7–10, 12–17]. CIP technical service as part of the overall system of technical maintenance and repair of machines, meets all the periods of their life cycle, and includes the testing, diagnosis, commissioning and preventive triboactive, the cleaning of the lubrication systems of engines, fuel, cooling, and most importantly — the restoration of worn units repair-regenerative trains [5, 7–10, 12–14, 17]. In the last intake of the mineral particles of the catalytically active open friction surface are subjected to a mechanical cold deformation, are involved in adhesion, physical and chemical processes, tribromoimidazole, catalysis of tribo-processes [2, 15–17]. As a result of the repair coating [2, 5, 12, 15–17]. The serpentine triboactive create a durable anti-friction coatings [2, 15–17]. According to research by European and American researchers [15, 16], especially in Chinese state laboratory of Tribology of Tsinghua University [17], these minerals cause the formation of diamondlike carbon fi lms (Diamond-Like carbon fi lms — DLC-fi lms). Their surface is high purity and hardness, underneath are visible traces of mechanical processing, for 90 % consist of carbon, the resistance of 10–300 Ohm/cm. The eff ect of serpentine processing is manifested through the hours and ability to operate even without triboactive [2, 10]. Below are the laboratory tribotechnical tests of triboactive and fi ling of charges in the oil, which confi rm the eff ectiveness of non-traditional tribology.


1977 ◽  
Vol 38 (03) ◽  
pp. 0640-0651 ◽  
Author(s):  
B. V Chater ◽  
A. R Williams

SummaryPlatelets were found to aggregate spontaneously when exposed to ultrasound generated by a commercial therapeutic device. At a given frequency, aggregation was found to be a dose-related phenomenon, increasing intensities of ultrasound inducing more extensive and more rapid aggregation. At any single intensity, the extent aggregation was increased as the frequency of the applied ultrasound was decreased (from 3.0 to 0.75 MHz).Ultrasound-induced platelet aggregation was found to be related to overall platelet sensitivity to adenosine diphosphate. More sensitive platelets were found to aggregate spontaneously at lower intensities of sound, and also the maximum extent of aggregation was found to be greater. Examination of ultrasound-induced platelet aggregates by electron microscopy demonstrated that the platelets had undergone the release reaction.The observation that haemoglobin was released from erythrocytes in whole blood irradiated under identical physical conditions suggests that the platelets are being distrupted by ultrasonic cavitation (violent gas/bubble oscillation).It is postulated that overall platelet aggregation is the result of two distinct effects. Firstly, the direct action of ultrasonic cavitation disrupts a small proportion of the platelet population, resulting in the liberation of active substances. These substances produce aggregation, both directly and indirectly by inducing the physiological release reaction in adjacent undamaged platelets.


2020 ◽  
pp. 3-7
Author(s):  
Vladlen Ya. Shifrin ◽  
Denis I. Belyakov ◽  
Alexander E. Shilov ◽  
Denis D. Kosenko

The results of works aimed at increasing the level of uniformity of measurements of the magnetic induction of a constant field – the basic value in the field of magnetic measurements. A set of equipment for reproducing a unit of magnetic induction of a constant field in the range of 1–25 mT was created and described. The inclusion of this complex in the State primary standard of units of magnetic induction, magnetic flux, magnetic moment and magnetic induction gradient GET 12-2011 will ensure the reproduction and direct transmission of the unit of permanent magnetic induction in the ranges of not only weak (10–3–1 mT), but medium (1–25 mT) and strong (0.025–1 T) magnetic fields. A quantum cesium magnetometer based on the resolved structure of cesium atoms was created to transmit the unit of magnetic induction to the region of medium fields. The procedure for calculating the frequency conversion coefficients to magnetic induction of the created quantum cesium magnetometer is described. The uncertainty budget for reproducing a unit of magnetic induction of a constant field using the created complex is estimated.


2020 ◽  
Vol 9 (4) ◽  
pp. 40-43
Author(s):  
N. K. Yuldasheva ◽  
S. D. Gusakova ◽  
D. Kh. Nurullaeva ◽  
N. T. Farmanova ◽  
R. P. Zakirova ◽  
...  

Introduction. Lipids are a widespread group of biologically active substances in nature, making up the bulk of the organic substances of all living organisms. They accumulate in plants in seeds, as well as in fruits and perform a number of vital functions: they are the main components of cell membranes and the energy reserve for the body.Aim. Study of neutral lipids of sown oats (Avena sativa L.).Materials and methods. The objects of the study were fruits (grains) of oats of the sown variety "Tashkent 1," harvested in the Republic of Uzbekistan. Results and discussions. Neutral lipids of oat grains have been found to contain 13 fatty acids with a predominance of the sum of oleic, linolenic and linoleic acids. The total degree of unsaturation was almost 78%. Absorption bands characteristic of these substances were observed in the IR spectrum of MEGC.Conclusion. According to the results of the NL analysis, oat grains consisted of triacylglycerides and free LCDs, which were accompanied by hydrocarbons, phytosterols, triterpenoids and tocopherols.


2016 ◽  
Vol 48 (1) ◽  
pp. 20-25 ◽  
Author(s):  
L.A. Kotyuk ◽  
◽  
D.B. Rakhmetov ◽  

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