scholarly journals Changes in surface characteristics and adsorption properties of 2,4,6-trichlorophenol following Fenton-like aging of biochar

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Liqiang Cui ◽  
Qinya Fan ◽  
Jianxiong Sun ◽  
Guixiang Quan ◽  
Jinlong Yan ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Surface Properties ◽  
Aging Process ◽  
Surface Characteristics ◽  
Natural Soil ◽  
Peanut Shell ◽  
Soil Environment ◽  
Polluted Soils ◽  
Physico Chemical

AbstractFenton-like system formed in a natural soil environment deemed to be significant in the aging process of biochar. Aged biochars have distinct physico-chemical and surface properties compared to non-aged biochar. The aged biochar proved to be useful soil amendment due to its improved elements contents and surface properties. The biochar aging process resulted in increased surface area and pore volume, as well as carbon and oxygen-containing functional groups (such as C=O, –COOH, O–C=O etc.) on its surface, which were also associated with the adsorption behavior of 2,4,6-trichlorophenol (2,4,6-TCP). The biochar aging increased the adsorption capacity of 2,4,6-TCP, which was maximum at pH 3.0. The 2,4,6-TCP adsorption capacity of aged-bush biochar (ABB) and aged-peanut shell biochar (APB) was increased by 1.0–11.0% and 7.4–38.8%, respectively compared with bush biochar (BB) and peanut shell biochar (PB) at the same initial concentration of 2,4,6-TCP. All biochars had similar 2,4,6-TCP desorption rates ranging from 33.2 to 73.3% at different sorption temperatures and times. The desorbed components were mainly 2,4,6-TCP and other degraded components, which were low in concentration with small molecule substance. The results indicated that the aged-biochar could be effective for the long-term remediation of naturally organic polluted soils.

Development and Characterization of Amine-Clay Hybrid Adsorbents for CO2 Capture

2016 ◽  
Vol 1133 ◽  
pp. 547-551 ◽  
Author(s):  
Ali E.I. Elkhalifah ◽  
Mohammad Azmi Bustam ◽  
Azmi Mohd Shariff ◽  
Sami Ullah ◽  
Nadia Riaz ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Surface Area ◽  
Surface Properties ◽  
Molar Mass ◽  
Adsorption Ability ◽  
Stepwise Increase ◽  
Inverse Effect ◽  
Bet Method ◽  
Sodium Form

The present work aims at a better understanding of the influences of the intercalated mono-, di- and triethanolamines on the characteristics and CO2 adsorption ability of sodium form of bentonite (Na-bentonite). The results revealed that the molar mass of intercalated amines significantly influenced the structural and surface properties as well as the CO2 adsorption capacity of Na-bentonite. In this respect, a stepwise increase in the d-spacing of Na-bentonite with the molar mass of amine was recorded by XRD technique. However, an inverse effect of the molar mass of amine on the surface area was confirmed by BET method. CO2 adsorption experiments on amine-bentonite hybrid adsorbents showed that the CO2 adsorption capacity inversly related to the molar mass of amine at 25 ͦC and 101 kPa. Accordingly, Na-bentonite modified by monoethanolammonium cations adsorbed as high as 0.475 mmol CO2/g compared to 0.148 and 0.087 mmol CO2/g for that one treated with di- and triethanolammonium cations, respectively.

Review of Recent Developments in Surface Nanocrystallization of Metallic Biomaterials

Nanoscale ◽  
2021 ◽  
Author(s):  
Srijan Acharya ◽  
Satyam Suwas ◽  
Kaushik Chatterjee
Keyword(s):  
Human Body ◽  
Surface Characteristics ◽  
Metallic Materials ◽  
Short Term ◽  
Surface Nanocrystallization ◽  
Metallic Biomaterials ◽  
Recent Developments

Metallic materials are widely used to prepare implants for both short-term and long-term use in the human body. The performance of these implants is greatly influenced by their surface characteristics,...

scholarly journals Evaluation of Leaf Litter Mulching and Incorporation on Skid Trails for the Recovery of Soil Physico-Chemical and Biological Properties of Mixed Broadleaved Forests

Land ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 625
Author(s):  
Meghdad Jourgholami ◽  
Azadeh Khoramizadeh ◽  
Angela Lo Monaco ◽  
Rachele Venanzi ◽  
Francesco Latterini ◽  
...  
Keyword(s):  
Soil Properties ◽  
Soil Compaction ◽  
Biological Properties ◽  
Soil Protection ◽  
Natural Soil ◽  
Compacted Soils ◽  
Beneficial Effects ◽  
Physico Chemical ◽  
Forest Logging ◽  
Soil Recovery

Engineering applications can be used to mitigate the adverse effects of soil compaction and amend compacted soils. Previous literature has highlighted the beneficial effects of interventions such as litter mulching and incorporation on skid trails. However, little is known about the effectiveness of these alternatives in restoring forest soil quality after forest logging. The objective of this study was to properly elucidate the effects of the above mentioned soil protection methods, litter incorporation before skidding (LI) and litter mulching after skidding (LM), on the recovery of compacted soil’s physico-chemical and biological properties on skid trails over a 2-year period in the Hyrcanian forests of Iran to identify the best option for restoration intervention. The litter used in both methods consisted of dried leaves of the hornbeam and maple tree in three intensities of 3, 6, and 9 Mg ha−1. The results showed that the application of both methods (LI and LM) significantly improved the soil properties when compared to the untreated skid trail. Results showed that the recovery values of soil properties in the LI treatments were significantly higher than those of the LM. The recovery values of soil properties by 6 and 9 Mg ha−1 were significantly higher than those of 3 Mg ha−1, while the differences were not significant between 6 and 9 Mg ha−1. Our findings showed that soil properties were partially recovered (70–80%) over a 2-year period from treatment, compared to untreated, but the full recovery of soil properties required more time to return to the pre-harvest value. Overall, the results of this study demonstrated that the application of soil protection methods accelerates the process of recovering soil properties much faster than natural soil recovery, which can take more than 20 years in these forests.

scholarly journals Titanium oral implants: surface characteristics, interface biology and clinical outcome

2010 ◽  
Vol 7 (suppl_5) ◽  
Author(s):  
Anders Palmquist ◽  
Omar M. Omar ◽  
Marco Esposito ◽  
Jukka Lausmaa ◽  
Peter Thomsen
Keyword(s):  
Surface Properties ◽  
Cellular Response ◽  
Randomized Clinical Trials ◽  
Three Dimensional ◽  
Cell Communication ◽  
Surface Characteristics ◽  
Titanium Implants ◽  
Material Surface ◽  
Oral Implants

Bone-anchored titanium implants have revolutionized oral healthcare. Surface properties of oral titanium implants play decisive roles for molecular interactions, cellular response and bone regeneration. Nevertheless, the role of specific surface properties, such as chemical and phase composition and nanoscale features, for the biological in vivo performance remains to be established. Partly, this is due to limited transfer of state-of-the-art preparation techniques to complex three-dimensional geometries, analytical tools and access to minute, intact interfacial layers. As judged by the available results of a few randomized clinical trials, there is no evidence that any particular type of oral implant has superior long-term success. Important insights into the recruitment of mesenchymal stem cells, cell–cell communication at the interface and high-resolution imaging of the interface between the surface oxide and the biological host are prerequisites for the understanding of the mechanisms of osseointegration. Strategies for development of the next generation of material surface modifications for compromised tissue are likely to include time and functionally programmed properties, pharmacological modulation and incorporation of cellular components.

Microwave carbonization of cotton fiber for the production of carbon materials

2021 ◽  
Vol 11 ◽  
pp. 54-68
Author(s):  
E. V. Matveev ◽  
◽  
A. I. Gajdar ◽  
B. A. Lapshinov ◽  
A. V. Mamontov ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Fiber Surface ◽  
Thermal Method ◽  
Surface Layers ◽  
Cotton Lint ◽  
Microwave Exposure ◽  
Carbonization Process ◽  
Fiber Wall ◽  
Physico Chemical ◽  
Transverse Fractures

This article presents the results of comparative studies of the structural and physico-chemical features of cotton lint samples carbonized by the microwave method and the standard (thermal) method. The dependences of the temperature change of the samples during the microwave carbonization process are obtained. The heterogeneity of the morphology of the fiber surface along the cross-section of the microwave carbonized sample was revealed. It is shown that the structure of the surface layers is characterized by two mechanisms of fiber destruction: numerous brittle transverse fractures and coloring of the fibers in places of swellings (a sharp increase in their diameter) and fluffing of the surface into convoluted fibrils with a transverse size of 50 – 300 nm due to the destruction of the outer layers of the secondary fiber wall. In the central region, the destruction of fibers occurs by the formation of longitudinal interfibrillary slits and the delamination of the secondary fiber wall, which leads to the formation of pores with dimensions of 50 – 200 nm. It is established that during the microwave carbonization process, the central part of the sample is almost completely freed from impurities that are deposited on the fibers of the surface layers. It is shown that the integral adsorption capacity of the microwave carbonized sample is higher than the adsorption capacity of the sample carbonized by the thermal method (126 mg/g and 47 mg/g, respectively). It was found that during microwave exposure more than 10 minutes, regions with an adsorption capacity of ~ 350 – 450 mg/g appear in the carbonized material, that is comparable to the capacity of samples activated by the standard method.

Samples disturbance overestimates phosphorus adsorption capacity in soils under long-term application of pig slurry

2019 ◽  
Vol 65 (9) ◽  
pp. 1262-1272 ◽  
Author(s):  
Luciano Colpo Gatiboni ◽  
Djalma Eugênio Schmitt ◽  
Paulo Cezar Cassol ◽  
Jucinei José Comin ◽  
Joice Crescêncio Heidemann ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Pig Slurry ◽  
Phosphorus Adsorption

Hardening of Aged Duplex Stainless Steels by Spinodal Decomposition

2004 ◽  
Vol 10 (3) ◽  
pp. 349-354 ◽  
Author(s):  
F. Danoix ◽  
P. Auger ◽  
D. Blavette
Keyword(s):  
Mechanical Properties ◽  
Impact Toughness ◽  
Spinodal Decomposition ◽  
Stainless Steels ◽  
Aging Process ◽  
Atom Probe ◽  
Duplex Stainless Steels ◽  
Detailed Knowledge ◽  
Iron Chromium

Mechanical properties, such as hardness and impact toughness, of ferrite-containing stainless steels are greatly affected by long-term aging at intermediate temperatures. It is known that the α-α′ spinodal decomposition occurring in the iron–chromium-based ferrite is responsible for this aging susceptibility. This decomposition can be characterized unambiguously by atom probe analysis, allowing comparison both with the existing theories of spinodal decomposition and the evolution of some mechanical properties. It is then possible to predict the evolution of hardness of industrial components during service, based on the detailed knowledge of the involved aging process.

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