scholarly journals Chemical and isotopic characterization of the thermal fluids emerging along the North–Northeastern Greece

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
E. Dotsika ◽  
P. Dalampakis ◽  
E. Spyridonos ◽  
G. Diamantopoulos ◽  
P. Karalis ◽  
...  

AbstractHydrochemical and isotopic characteristics of fluids from major geothermal fields of middle/low temperature in N/NE Greece are examined [basins: Strymon River (SR), Nestos River Delta (ND), Xanthi–Komotini (XK), Loutros–Feres–Soufli (LFS) and Rhodope Massif]. The geodynamic context is reflected to isotopic/chemical composition of fluids, heat flow values and elevated CO2 concentrations in emitted fluids. B and Li are derived from leaching of the geothermal systems hosting rocks. δ18OH2O, δ18OSO4, δ13CCO2 values and chemical compositions of Cl, B and Li of geothermal discharges suggest two distinct source fluids. Fluids in SR exhibit high B/Cl and Li/Cl ratios, suggesting these constituents are derived from associated magmas of intermediate composition (andesitic rocks). Geothermal discharges in LFS exhibit low B/Cl and Li/Cl ratios, implying acid (rhyolitic) magmatism. δ13CCO2 and CO2/(CO2 + 105He) ratios in the west part, suggest fluids affected by addition of volatiles released from subducted marine sediments. For the eastern systems, these ratios suggest gas encountered in systems issued from mixing of crustal and mantle-derived volatiles. Isotopic geothermometers reflect, for the same direction, equilibrium processes more (LFS, XK) or less (SR) pronounced and discriminate the geothermal field from low to middle [SR, ND (Erasmio)] and middle to high enthalpy [ND (Eratino), LFS, XK].

Clay Minerals ◽  
2004 ◽  
Vol 39 (4) ◽  
pp. 501-510 ◽  
Author(s):  
S. Battaglia

AbstractPrevious attempts to use illite as a geothermometer have failed: no general relation between the mineral's chemical composition and temperature of crystallization has been found. Here, chemical compositions of 27 illite samples from five different geothermal fields (the data on four of which were drawn from the literature) were compared with their crystallization temperatures. As previously reported by Cathelineau (1988), the K content was found to be the only variable yielding a suitable correlation, but only when applied to one geothermal field; when various geothermal systems were considered, the correlation weakened considerably. Introduction of a correction algorithm to the K content of the illite has made it possible to draw a single line to fit the data from all the studied samples, yielding a good correlation coefficient (r = 0.84).


Clay Minerals ◽  
2018 ◽  
Vol 53 (2) ◽  
pp. 117-141 ◽  
Author(s):  
S.N. Maza ◽  
G. Collo ◽  
D. Morata ◽  
C. Lizana ◽  
E. Camus ◽  
...  

ABSTRACTThe occurrence of smectite-illite and smectite-chlorite minerals series was studied along a thick clay cap (~300 m) drilled in the Cerro Pabellón geothermal field (northern Andes, Chile). X-ray diffraction (XRD) and scanning electronic microscopy (SEM) were used to characterize the alteration mineralogy and clay mineral assemblages and their changes with depth. Cerro Pabellón is a high-enthalpy blind geothermal system, with a reservoir zone from ~500 m to 2000 m depth, with temperatures of 200–250°C. Three main hydrothermal alteration zones were identified: (1) argillic; (2) sub-propylitic, and (3) propylitic, with variable amounts of smectite, illite-smectite, chlorite-smectite, mixed-layer chlorite-corrensite, illite and chlorite appearing in the groundmass and filling amygdales and veinlets. Chemical and XRD data of smectites, I-S and illites show, with some exceptions, a progressive illitization with depth. The evolution of I-S with depth, shows a sigmoidal variation in the percentage of illite layers, with the conversion of smectite to R1 I-S at ~180–185°C. These temperatures are greater than those reported for other similar geothermal fields and might indicate, at least in part, the efficiency of the clay cap in terms of restricting the circulation of hydrothermal fluids in low-permeability rocks. Our results highlight the importance of a better understanding of clay-mineral evolution in active geothermal systems, not only as a direct (or indirect) way to control temperature evolution, but also as a control on permeability/porosity efficiency of the clay cap.


2020 ◽  
Author(s):  
Gunnar Gunnarsson ◽  
Vignir Demusson ◽  
Ingvi Gunnarsson ◽  
Bjarni Reyr Kristjánsson ◽  
Sigrún Tómasdóttir ◽  
...  

<p><span>In 1986 a well, which was planned as a convetional production well in the Nesjavellir Field in the Hengill Area, SW Iceland, was unexpectedly drilled into a very hot formation at the depth of 2.1 km. The measured temperature in the lowest part of the well was 380°C, which was the upper range of the measuring tool used. Thus, the bottom-hole temperature was most probably higher. No one expected to hit such a hot body in this place and the well design was not appropriate to handle such high temperatures and resulting pressures. Thus, the lower parts of that well were closed off and it has since then been operated as a conventional geothermal well.</span></p><p><span>This incidence sparked the idea of drilling deeper into volcanic hydrothermal systems in Iceland in order to gain a better understanding of the roots of the geothermal systems and to be able to produce fluids with higher enthalpy. The Iceland Deep Drilling Project (IDDP) is supposed to realize that idea. The IDDP project is a consortium of domestic and international partners, both from industry and academia. The three power companies in Iceland, which operate power-production in volcanic geothermal fields (Landsvirkjun, HS-Orka, OR), committed themselves to drill one deep well each in a field of theirs. </span></p><p><span>To date two wells have been drilled in the IDDP project. The first one, IDDP-1, was drilled in the Krafla Field, N Iceland, which is operated by Landsvirkjun, and the second well, IDDP-2, was drilled in the Reykjanes Field, which is operated by HS-Orka. The original plan was to drill down to 4-5 km. However, the IDDP-1 in Krafla was drilled into magma of rhyolite composition at the depth of 2.1 km and could therefore not be drilled further. During flow tests, it was flowing superheated steam at high pressure at well head temperature of 450°C. The power capacity was estimated to be 36 MW<sub>e</sub>. However, due to hostile chemistry of the fluid and damaged casing, the well had to be abandoned and closed after the well tests. IDDP-2 was drilled down to 4,659 m. The highest temperature measured in the bottom of the well was 426°C at a pressure of 340 bar. It was also possible to obtain core samples from the bottom of the well. However, due to damaged casing it hasn't been possible to do further temperature and pressure measurements in the lower parts of IDDP-2. To date flow tests in IDDP-2 have not started.</span></p><p><span>The next well in the IDDP project is planned in the Hengill Area. The most promising target is the hot body that started it all in the Nesjavellir Field. According to experience from IDDP-1 and IDDP-2 the main techincal obstacle is the casing. Both wells have serious casing problems. The magma body unexpectedly hit by IDDP-1 illustrated that careful interdisciplinary preperations are needed when drilling into the unknown. Currently, few projects are ongoing to fill the knowledge gaps in order to minimize risk and maximize the probability of successful drilling. </span></p>


Solid Earth ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 125-159 ◽  
Author(s):  
Federico Lucci ◽  
Gerardo Carrasco-Núñez ◽  
Federico Rossetti ◽  
Thomas Theye ◽  
John Charles White ◽  
...  

Abstract. Understanding the anatomy of magma plumbing systems of active volcanoes is essential not only for unraveling magma dynamics and eruptive behaviors but also to define the geometry, depth, and temperature of the heat sources for geothermal exploration. The Pleistocene–Holocene Los Humeros volcanic complex is part of the eastern Trans-Mexican Volcanic Belt (central Mexico), and it constitutes one of the most important exploited geothermal fields in Mexico with ca. 90 MW of produced electricity. With the aim to decipher the anatomy (geometry and structure) of the magmatic plumbing system feeding the geothermal field at Los Humeros, we carried out a field-based petrological and thermobarometric study of the exposed Holocene lavas. Textural analysis, whole-rock major-element data, and mineral chemistry are integrated with a suite of mineral-liquid thermobarometric models. Our results support a scenario characterized by a heterogeneous multilayered system, comprising a deep (depth of ca. 30 km) basaltic reservoir feeding progressively shallower and smaller discrete magma stagnation layers and batches, up to shallow-crust conditions (depth of ca. 3 km). The evolution of melts in the feeding system is mainly controlled by differentiation processes through fractional crystallization (plagioclase + clinopyroxene + olivine + spinel). We demonstrate the inadequacy of the existing conceptual models, where a single voluminous melt-controlled magma chamber (or “Standard Model”) at shallow depths was proposed for the magmatic plumbing system at Los Humeros. We instead propose a magmatic plumbing system made of multiple, more or less interconnected, magma transport and storage layers within the crust, feeding small (ephemeral) magma chambers at shallow-crustal conditions. This revised scenario provides a new configuration of the heat source feeding the geothermal reservoir at Los Humeros, and it should be taken into account to drive future exploration and exploitation strategies.


Geophysics ◽  
1978 ◽  
Vol 43 (7) ◽  
pp. 1485-1500 ◽  
Author(s):  
Norman Harthill

A quadripole resistivity survey of the Imperial Valley, California was carried out from the Salton Sea in the north to the Mexican border in the south. The east and west boundaries of the survey were the topographic limits of the valley. The quadripole resistivity method consists of sequentially energizing two orthogonal bipole sources with a square wave of electric current and measuring the resultant electric fields with a pair of orthogonal wire receivers. Two resultant electric fields are measured and by combining them in different proportions, their resultant can be made to rotate through 360 degrees. By performing this procedure, an ellipse of resistivity can be calculated at each measurement location. The arithmetic mean of the maximum and minimum axes of the ellipse is a tensor invariant resistivity. It was this value which was used to define the variation of electrical resistivity over the Imperial Valley. The quadripole survey of the Imperial Valley was undertaken to compare its known geothermal fields with previously unsurveyed areas. The results show that the geothermal fields of the Imperial Valley have distinctive resistivity characteristics. A large circular area south of the city of Brawley was found which has the same characteristics as the known geothermal fields. From the resistivity data, it is predicted that this south Brawley resistivity anomaly represents a geothermal field which will produce water with a temperature of approximately 200°C and with a salinity between 20,000 and 50,000 ppm. A well to test the prospect was scheduled to be drilled early in 1978.


Author(s):  
Tatiana Vasilievna Pomogaeva ◽  
Aliya Ahmetovna Aseinova ◽  
Yuriy Aleksandrovich Paritskiy ◽  
Vjacheslav Petrovich Razinkov

The article presents annual statistical data of the Caspian Research Institute of Fishery. There has been kept track of the long term dynamics of the stocks of three species of Caspian sprat (anchovy, big-eyed kilka, sprat) and investigated a process of substituting a food item of sprats Eurytemora grimmi to a small-celled copepod species Acartia tonsa Dana. According to the research results, there has been determined growth potential of stocks of each species. Ctenophoran-Mnemiopsis has an adverse effect on sprat population by eating fish eggs and larvae. Ctenophoram - Mnemiopsis is a nutritional competitor to the full-grown fishes. The article gives recommendations on reclamation of stocks of the most perspective species - common sprat, whose biological characteristics helped not to suffer during Ctenophoram outburst and to increase its population during change of the main food item. Hydroacoustic survey data prove the intensive growth of common sprat biomass in the north-west part of the Middle Caspian. According to the results of the research it may be concluded that to realize the volumes of recommended sprat catch it is necessary to organize the marine fishery of common sprat at the Russian Middle Caspian shelf.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kyosuke Okamoto ◽  
Hiroshi Asanuma ◽  
Hiro Nimiya

AbstractSubsurface structure survey based on horizontal-to-vertical (H/V) spectral ratios is widely conducted. The major merit of this survey is its convenience to obtain a stable result using a single station. Spatial variations of H/V spectral ratios are well-known phenomena, and it has been used to estimate the spatial fluctuation in subsurface structures. It is reasonable to anticipate temporal variations in H/V spectral ratios, especially in areas like geothermal fields, carbon capture and storage fields, etc., where rich fluid flows are expected, although there are few reports about the temporal changes. In Okuaizu Geothermal Field (OGF), Japan, dense seismic monitoring was deployed in 2015, and continuous monitoring has been consistent. We observed the H/V spectral ratios in OGF and found their repeated temporary drops. These drops seemed to be derived from local fluid activities according to a numerical calculation. Based on this finding, we examined a coherency between the H/V spectral ratios and fluid activities in OGF and found a significance. In conclusion, monitoring H/V spectral ratios can enable us to grasp fluid activities that sometimes could lead to a relatively large seismic event.


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