Determination of total sulphur and nitrogen in crude oil products by oxidative pyrolysis with detection using a metal-plated membrane electrode

The Analyst ◽  
1988 ◽  
Vol 113 (3) ◽  
pp. 501-503 ◽  
Author(s):  
Jan Langmaier ◽  
Jaroslav Polák ◽  
František Opekar
Keyword(s):  
Crude Oil ◽  
Oil Products ◽  
Membrane Electrode ◽  
Total Sulphur ◽  
Oxidative Pyrolysis

scholarly journals Research of Soil Intrusion Depth of Crude Oil upon Emergency Spills of Oil Products

2021 ◽  
Vol 133 (2) ◽  
pp. 47-49
Author(s):  
H. M. Nasirov ◽  
Keyword(s):  
Crude Oil ◽  
Oil Products ◽  
Time Interval ◽  
Method Of Averaging ◽  
Optimum Temperature ◽  
Liquid Hydrocarbons ◽  
The Mean ◽  
Intrusion Depth

The task regarding determination of optimum temperature upon which the oil products soil intrusion depth reaches minimum is formulated and solved. It is noted that increase of temperature enhance vaporization of liquid hydrocarbons from one side which leads to decrease of intrusion depth and from another side increase speed of intrusion into soil which increase the intrusion depth. As a result the mean depth of intrusion calculated using method of averaging these factors effects has a minimum in some value of temperature. It is shown that this minimum is proportional to logarithm of time interval passed after spill event.

Energetic properties of peat saturated with petroleum products

2020 ◽  
Vol 13 (2) ◽  
pp. 105-109
Author(s):  
E. S. Dremicheva
Keyword(s):  
Crude Oil ◽  
Diesel Fuel ◽  
Energy Use ◽  
Experimental Studies ◽  
Calorific Value ◽  
Petroleum Products ◽  
Ash Content ◽  
Motor Oil ◽  
Initial Sample

This paper presents a method of sorption using peat for elimination of emergency spills of crude oil and petroleum products and the possibility of energy use of oil-saturated peat. The results of assessment of the sorbent capacity of peat are presented, with waste motor oil and diesel fuel chosen as petroleum products. Natural peat has been found to possess sorption properties in relation to petroleum products. The sorbent capacity of peat can be observed from the first minutes of contact with motor oil and diesel fuel, and significantly depends on their viscosity. For the evaluation of thermal properties of peat saturated with petroleum products, experimental studies have been conducted on determination of moisture and ash content of as-fired fuel. It is shown that adsorbed oil increases the moisture and ash content of peat in comparison with the initial sample. Therefore, when intended for energy use, peat saturated with petroleum products is to be subjected to additional drying. Simulation of net calorific value has been performed based on the calorific values of peat and petroleum products with different ratios of petroleum product content in peat and for a saturated peat sample. The obtained results are compared with those of experiments conducted in a calorimetric bomb and recalculated for net calorific value. A satisfactory discrepancy is obtained, which amounts to about 12%. Options have been considered providing for combustion of saturated peat as fuel (burnt per se and combined with a solid fuel) and processing it to produce liquid, gaseous and solid fuels. Peat can be used to solve environmental problems of elimination of emergency spills of crude oil and petroleum products and as an additional resource in solving the problem of finding affordable energy.

Determination of subnanogram amounts of sulfur dioxide and sulfites by pneumatopotentiometry

1986 ◽  
Vol 51 (10) ◽  
pp. 2077-2082 ◽  
Author(s):  
Jan Langmaier ◽  
František Opekar
Keyword(s):  
Sulfur Dioxide ◽  
Redox Potential ◽  
Sodium Hydroxide ◽  
Porous Membrane ◽  
Membrane Electrode ◽  
Iodine Monochloride ◽  
Membrane Pores ◽  
Relative Standard ◽  
Limit Of Quantitation

Gold porous membrane electrode has been used for the potentiometric determination of small amounts of sulfur dioxide absorbed in the solutions of sodium tetrachloromercurate or sodium hydroxide. Sulfur dioxide is released by the reaction with an acid into a stream of nitrogen and led to the electrode immersed into the solution of iodine monochloride. Part of SO2 penetrates through the membrane pores into the solution where it is oxidized. The electrode redox potential change is a measure of the SO2 concentration in the absorption solution. In the solution of 1 . 10-5 M[ICl2]- in 0.02 M-HClO4 the limit of quantitation was found to be 0.07 ng SO2 . ml-1. The relative standard deviations of 1.4% and 2.5% were found for the determinations of 10 ng and 0.5 ng of SO2, respectively. Higher concentrations of H2S interfere only in the hydroxide solution. About 10 samples can be analyzed per one hour.

Novel palladium(II) selective membrane electrode based on 4-[(5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl]benzene-1,3-diol

2010 ◽  
Vol 75 (5) ◽  
pp. 563-575 ◽  
Author(s):  
Moslem Mohammadi ◽  
Mehdi Khodadadian ◽  
Mohammad K. Rofouei
Keyword(s):  
Limit Of Detection ◽  
Membrane Electrode ◽  
Aqueous Samples ◽  
Selective Determination ◽  
Poly Vinyl Chloride ◽  
Selective Membrane ◽  
Ph Range ◽  
Palladium Content ◽  
Methyl Benzene

A plasticized poly(vinyl chloride) membrane electrode based on 4-[(5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl]benzene-1,3-diol (L) for highly selective determination of palladium(II) (in PdCl42– form) is developed. The electrode showed a good Nernstian response (29.6 ± 0.4 mV per decade) over a wide concentration range (3.1 × 10–7 to 1.0 × 10–2 mol l–1). The limit of detection was 1.5 × 10–7 mol l–1. The electrode has a response time of about 20 s, and it can be used for at least 2 months without observing any considerable deviation from Nernstian response. The proposed electrode could be used in the pH range of 2.5–5.5. The practical utility of the electrode has been demonstrated by its use for the estimation of palladium content in aqueous samples.

scholarly journals Linkages between Energy Delivery and Economic Growth from the Point of View of Sustainable Development and Seaports

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4255
Author(s):  
Elżbieta Szaruga ◽  
Zuzanna Kłos-Adamkiewicz ◽  
Agnieszka Gozdek ◽  
Elżbieta Załoga
Keyword(s):  
Sustainable Development ◽  
Crude Oil ◽  
Cross Correlation ◽  
Point Of View ◽  
Oil Products ◽  
Modern Approach ◽  
Economic Cycles ◽  
Study Results ◽  
The One ◽  
Oil And Oil Products

This paper presents the synchronisation of economic cycles of GDP and crude oil and oil products cargo volumes in major Polish seaports. On the one hand, this issue fits into the concept of sustainable development including decoupling; on the other hand, the synchronisation may be an early warning tool. Crude oil and oil products cargo volumes are a specific barometer that predicts the next economic cycle, especially as they are primary sources of energy production. The research study applies a number of TRAMO/SEATS methods, the Hodrick–Prescott filter, spectral analysis, correlation and cross-correlation function. Noteworthy is the modern approach of using synchronisation of economic cycles as a tool, which was described in the paper. According to the study results, the cyclical components of the cargo traffic and GDP were affected by the leakage of other short-term cycles. However, based on the cross-correlation, it was proved that changes in crude oil and oil products cargo volumes preceded changes in GDP by 1–3 quarters, which may be valuable information for decision-makers and economic development planners.

scholarly journals Determination of the vaporization order of crude oils through the chemical analysis of crude oil residues burned on water

Chemosphere ◽  
2021 ◽  
pp. 131563
Author(s):  
Laurens van Gelderen ◽  
Kristoffer Gulmark Poulsen ◽  
Jan H. Christensen ◽  
Grunde Jomaas
Keyword(s):  
Chemical Analysis ◽  
Crude Oil ◽  
Crude Oils
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