Theoretical design of magnetic wires from acene and nanocorone derivatives

2016 ◽  
Vol 45 (42) ◽  
pp. 16700-16708 ◽  
Author(s):  
Joan Cano ◽  
Francesc Lloret ◽  
Miguel Julve

A theoretical design of molecular magnetic wires based on linear and cyclic oligoacene-bridged dicopper(ii) model complexes is highlighted in the present contribution.

Author(s):  
N. V. Larcher ◽  
I. G. Solorzano

It is currently well established that, for an Al-Ag alloy quenched from the α phase and aged within the metastable solvus, the aging sequence is: supersaturated α → GP zones → γ’ → γ (Ag2Al). While GP zones and plate-shaped γ’ are metastable phases, continuously distributed in the matrix, formation of the equilibrium phase γ takes place at grain boundaries by discontinuous precipitation (DP). The crystal structure of both γ’ and γ is hep with the following orientation relationship with respect to the fee α matrix: {0001}γ′,γ // {111}α, <1120>γ′,γ, // <110>α.The mechanisms and kinetics of continuous matrix precipitation (CMP) in dilute Al-Ag alloys have been studied in considerable detail. The quantitative description of DP kinetics, however, has received less attention. The present contribution reports the microstructural evolution resulting from aging an Al-Ag alloy with Ag content higher than those previously reported in the literature, focusing the observations of γ' plate-shaped metastable precipitates.


2020 ◽  
Vol 59 (1-4) ◽  
pp. 145-160
Author(s):  
Giovanbattista Galdi

SummarySupport verb constructions are documented throughout the history of Latin. These syntagms are characterized by the presence of a support verb with a more or less reduced semantic force, and a predicative (abstract or verbal) noun that often constitutes its direct object. The present contribution deals, specifically, with the use of facio as a support verb (as in bellum facere, iter facere, insidias facere etc.), focussing on the post-classical and late period. Two main questions shall be discussed: (a) whether, and if so, how facio becomes more productive in later centuries in both non-Christian and Christian sources; (b) what type of semantic evolution the verb undergoes in later Latin and whether, in this respect, continuity or rupture should be assumed with regard to the earlier period. This last point will enable us to suggest a more convincing explanation of an often-quoted passage of Cicero (Phil. 3. 22), in which the expression contumeliam facere is found.


2018 ◽  
Vol 35 (1-2) ◽  
pp. 189-223
Author(s):  
Petra Kieffer-Pülz

The present contribution suggests the common authorship of three P?li commentaries of the twelfth/thirteenth centuries CE, namely the Vinayavinicchaya??k? called Vinayas?ratthasand?pan? (less probably Vinayatthas?rasand?pan?), the Uttaravinicchaya??k? called L?natthappak?san?, and the Saccasa?khepa??k? called S?ratthas?lin?. The information collected from these three commentaries themselves and from P?li literary histories concerning these three texts leads to the second quarter of the thirteenth century CE as the period of their origination. The data from parallel texts explicitly stated to having been written by V?cissara Thera in the texts themselves render it possible to establish with a high degree of probability V?cissara Thera as their author.


2015 ◽  
Vol 7 (2) ◽  
pp. 3-20
Author(s):  
Metropolitan Hilarion of Volokolamsk

The article deals with the problem of the divine light in the mystical works of St Symeon the New Theologian (949–1022) in the context of the Eastern Christian ascetical tradition. The author focuses on the passages referring to the divine light in the works of Evagrios Pontikos, St Isaac the Syrian, St Maximus the Confessor, and in the Makarian corpus. As is shown in the present contribution, none of these authors created a fully-developed theory of the vision of the divine light. Being close to these writers in many ideas, St Symeon was generally independent of any of them in his treatment of the theme of vision of light, always basing himself primarily upon his own experience.


2020 ◽  
Author(s):  
Haoyang Yu ◽  
Alyxandra Thiessen ◽  
Md Asjad Hossain ◽  
Marc Julian Kloberg ◽  
Bernhard Rieger ◽  
...  

<div><div><div><p>Covalently bonded organic monolayers play important roles in defining the solution processability, ambient stability, and electronic properties of two-dimensional (2D) materials such as Ge nanosheets (GeNSs); they also hold promise of providing avenues for the fabrication of future generation electronic and optical devices. Functionalization of GeNS normally involves surface moieties linked through covalent Ge−C bonds. In the present contribution we extend the scope of surface linkages to include Si−Ge bonding and present the first demonstration of heteronuclear dehydrocoupling of organosilanes to hydride-terminated GeNSs obtained from the deintercalation and exfoliation of CaGe2. We further exploit this new surface reactivity and demonstrated the preparation of directly bonded silicon quantum dot-Ge nanosheet hybrids.</p></div></div></div>


Author(s):  
Сергий Ким

Толкование Евсевия Кесарийского на 37-й псалом в греческом оригинале было исследовано автором настоящей статьи в рамках проекта по Александрийской и Антиохийской экзегезе при Берлинско-Бранденбургской академии наук1 в 2017-2018 гг. По итогам исследования греческих рукописей было подготовлено новое критическое издание (в печати). Данная статья является продолжением работы над этим памятником и представляет читателю первую часть древнегрузинской версии Толкования на 37-й псалом и её русского перевода. The Greek original of the Commentary on Psalm 37 by Eusebius of Caesarea was studied by the author of the present contribution in the frame of the project «Die alexandrinische und antiochenische Bibelexegese in der Spätantike» at the Berlin-Brandenburg Academy of Sciences in 2017-2018. The investigation of the Greek manuscripts led to a new critical edition of Eusebius’ text (forthcoming). We conceive the present article as a continuation of our study on this text and offer the reader a first part of the critical edition of the hitherto inedited Old Georgian version of Eusebius’ Commentary on Psalm 37 alongside its Russian translation.


Author(s):  
Adam A. Garde ◽  
Brian Chadwick ◽  
John Grocott ◽  
Cees Swager

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Garde, A. A., Chadwick, B., Grocott, J., & Swager, C. (1997). Metasedimentary rocks, intrusions and deformation history in the south-east part of the c. 1800 Ma Ketilidian orogen, South Greenland: Project SUPRASYD 1996. Geology of Greenland Survey Bulletin, 176, 60-65. https://doi.org/10.34194/ggub.v176.5063 _______________ The south-east part of the c. 1800 Ma Ketilidian orogen in South Greenland (Allaart, 1976) is dominated by strongly deformed and variably migmatised metasedimentary rocks known as the ‘Psammite and Pelite Zones’ (Chadwick & Garde, 1996); the sediments were mainly derived from the evolving Julianehåb batholith which dominates the central part of the orogen. The main purpose of the present contribution is to outline the deformational history of the Psammite Zone in the region between Lindenow Fjord and Kangerluluk (Fig. 2), investigated in 1994 and 1996 as part of the SUPRASYD project (Garde & Schønwandt, 1995 and references therein; Chadwick et al., in press). The Lindenow Fjord region has high alpine relief and extensive ice and glacier cover, and the fjords are regularly blocked by sea ice. Early studies of this part of the orogen were by boat reconnaissance (Andrews et al., 1971, 1973); extensive helicopter support in the summers of 1992 and 1994 made access to the inner fjord regions and nunataks possible for the first time.A preliminary geological map covering part of the area between Lindenow Fjord and Kangerluluk was published by Swager et al. (1995). Hamilton et al. (1996) have addressed the timing of sedimentation and deformation in the Psammite Zone by means of precise zircon U-Pb geochronology. However, major problems regarding the correlation of individual deformational events and their relationship with the evolution of the Julianehåb batholith were not resolved until the field work in 1996. The SUPRASYD field party in 1996 (Fig. 1) was based at the telestation of Prins Christian Sund some 50 km south of the working area (Fig. 2). In addition to base camp personnel, helicopter crew and the four authors, the party consisted of five geologists and M.Sc. students studying mafic igneous rocks and their mineralisation in selected areas (Stendal et al., 1997), and a geologist investigating rust zones and areas with known gold anomalies.


2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


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