Coordination polymer-based conductive materials: ionic conductivity vs. electronic conductivity

2019 ◽  
Vol 7 (42) ◽  
pp. 24059-24091 ◽  
Author(s):  
Hai-Ning Wang ◽  
Xing Meng ◽  
Long-Zhang Dong ◽  
Yifa Chen ◽  
Shun-Li Li ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Ionic Conductivity ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Electronic Conductivity ◽  
Structural Factors ◽  
Conductive Materials ◽  
Recent Developments

This review summarizes recent developments of coordination polymers and their derivatives for ionic and electrical conductivity with the discussion about synthetic strategies and possible mechanisms to identify the key structural factors.

scholarly journals Heavy chalcogenide-transition metal clusters as coordination polymer nodes

2020 ◽  
Vol 11 (32) ◽  
pp. 8350-8372
Author(s):  
Jiaze Xie ◽  
Lei Wang ◽  
John S. Anderson
Keyword(s):  
Coordination Polymer ◽  
Transition Metal ◽  
Coordination Polymers ◽  
Metal Clusters ◽  
Transition Metal Clusters ◽  
Chalcogenide Clusters ◽  
Challenges And Opportunities ◽  
Recent Developments

Recent developments, challenges, and opportunities in using polynuclear transition metal heavy chalcogenide clusters as nodes for coordination polymers.

Electrical Conductivity in Praseodymium-Cerium Oxide

2002 ◽  
Vol 756 ◽  
Author(s):  
Todd S. Stefanik ◽  
Harry L. Tuller
Keyword(s):  
Electrical Conductivity ◽  
Ionic Conductivity ◽  
Cerium Oxide ◽  
Electronic Conductivity ◽  
Impurity Band ◽  
Defect Model ◽  
Valence States ◽  
Partial Pressures ◽  
Wide Range ◽  
Low Levels

ABSTRACTThe electrical conductivity of PrxCe1-xO2-δ (PCO) for 0 ≤ × ≤ 0.20 was examined over a wide range of temperatures and oxygen partial pressures. A defect model based on multiple Pr valence states was found to be qualitatively consistent with the observed data. A unique pO2-dependent ionic conductivity is observed at high pO2 values in compositions containing low levels of Pr (0 ≤ × ≤ 0.01). In compositions containing higher amounts of Pr (0.05 ≤ × ≤ 0.20), formation of a Pr induced impurity band results in a significant electronic conductivity at high pO2 values.

scholarly journals Reversible formation of soft coordination polymers from liquid mixtures of photoreactive organometallic ionic liquid and bridging molecules

Soft Matter ◽  
2020 ◽  
Vol 16 (43) ◽  
pp. 9946-9954
Author(s):  
Ryo Sumitani ◽  
Tomoyuki Mochida
Keyword(s):  
Ionic Liquid ◽  
Ionic Conductivity ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Liquid Mixtures ◽  
Bridging Ligands ◽  
Reversible Formation

Liquid mixtures of a Ru-containing ionic liquid and bridging ligands were reversibly transformed into a coordination polymer or an oligomer liquid by the application of light and heat, thus enabling reversible control of their ionic conductivity.

Experimental Study on Electrical Conductivity of FexO-CaO-SiO2-Al2O3 System at Various Oxygen Potentials

2018 ◽  
Vol 37 (2) ◽  
pp. 121-125 ◽  
Author(s):  
Yan–Xiang Liu ◽  
Jun–Hao Liu ◽  
Guo–Hua Zhang ◽  
Jian–Liang Zhang ◽  
Kuo–Chih Chou
Keyword(s):  
Electrical Conductivity ◽  
Ionic Conductivity ◽  
Oxygen Potential ◽  
Electronic Conductivity ◽  
Transference Number ◽  
Free Oxygen ◽  
Total Electrical Conductivity ◽  
Oxygen Ion ◽  
Conductivity Increase ◽  
Temperature Dependences

AbstractThe electrical conductivity of FexO-CaO-SiO2-Al2O3 slags was measured by a four terminal method. The results show that the temperature dependences of total, electronic and ionic conductivity for different compositions obey the Arrhenius law and all of them increase as increasing the temperature. For all the studied slags, as increasing CO/CO2 ratio which is used to controlled the oxygen potential, both the total electrical conductivity and electronic conductivity increase, but the ionic conductivity decreases. It was also found that the electronic transference number exhibits a strong correlation with oxygen potential, but is independent of temperature. Under the condition of constant FexO content, the higher the basicity of slags is, the higher the total electrical conductivity and ionic/electronic conductivity will be, which is resulted from the increase of free oxygen ion.

Revisiting the passivation of stainless steels and other passive CRAs

2018 ◽  
Vol 106 (1) ◽  
pp. 107 ◽  
Author(s):  
Jean- Louis Crolet
Keyword(s):  
Electrical Conductivity ◽  
Metal Ions ◽  
Base Metal ◽  
Stainless Steels ◽  
Electronic Conductivity ◽  
Transport Processes ◽  
General Knowledge ◽  
Inorganic Polymers ◽  
Faraday Cage

All that was said so far about passivity and passivation was indeed based on electrochemical prejudgments, and all based on unverified postulates. However, due the authors’ fame and for lack of anything better, the great many contradictions were carefully ignored. However, when resuming from raw experimental facts and the present general knowledge, it now appears that passivation always begins by the precipitation of a metallic hydroxide gel. Therefore, all the protectiveness mechanisms already known for porous corrosion layers apply, so that this outstanding protectiveness is indeed governed by the chemistry of transport processes throughout the entrapped water. For Al type passivation, the base metal ions only have deep and complete electronic shells, which precludes any electronic conductivity. Then protectiveness can only arise from gel thickening and densification. For Fe type passivation, an incomplete shell of superficial 3d electrons allows an early metallic or semimetallic conductivity in the gel skeleton, at the onset of the very first perfectly ordered inorganic polymers (- MII-O-MIII-O-)n. Then all depends on the acquisition, maintenance or loss of a sufficient electrical conductivity in this Faraday cage. But for both types of passive layers, all the known features can be explained by the chemistry of transport processes, with neither exception nor contradiction.

scholarly journals Pyrene Carboxylate Ligand Based Coordination Polymers for Microwave-Assisted Solvent-Free Cyanosilylation of Aldehydes

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1101
Author(s):  
Anirban Karmakar ◽  
Anup Paul ◽  
Elia Pantanetti Sabatini ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Metal Ion ◽  
Solvent Free ◽  
Lewis Acidity ◽  
Carboxylate Ligand ◽  
X Ray Diffraction ◽  
X Ray ◽  
Microwave Assisted

The new coordination polymers (CPs) [Zn(μ-1κO1:1κO2-L)(H2O)2]n·n(H2O) (1) and [Cd(μ4-1κO1O2:2κN:3,4κO3-L)(H2O)]n·n(H2O) (2) are reported, being prepared by the solvothermal reactions of 5-{(pyren-4-ylmethyl)amino}isophthalic acid (H2L) with Zn(NO3)2.6H2O or Cd(NO3)2.4H2O, respectively. They were synthesized in a basic ethanolic medium or a DMF:H2O mixture, respectively. These compounds were characterized by single-crystal X-ray diffraction, FTIR spectroscopy, thermogravimetric and elemental analysis. The single-crystal X-ray diffraction analysis revealed that compound 1 is a one dimensional linear coordination polymer, whereas 2 presents a two dimensional network. In both compounds, the coordinating ligand (L2−) is twisted due to the rotation of the pyrene ring around the CH2-NH bond. In compound 1, the Zn(II) metal ion has a tetrahedral geometry, whereas, in 2, the dinuclear [Cd2(COO)2] moiety acts as a secondary building unit and the Cd(II) ion possesses a distorted octahedral geometry. Recently, several CPs have been explored for the cyanosilylation reaction under conventional conditions, but microwave-assisted cyanosilylation of aldehydes catalyzed by CPs has not yet been well studied. Thus, we have tested the solvent-free microwave-assisted cyanosilylation reactions of different aldehydes, with trimethylsilyl cyanide, using our synthesized compounds, which behave as highly active heterogeneous catalysts. The coordination polymer 1 is more effective than 2, conceivably due to the higher Lewis acidity of the Zn(II) than the Cd(II) center and to a higher accessibility of the metal centers in the former framework. We have also checked the heterogeneity and recyclability of these coordination polymers, showing that they remain active at least after four recyclings.

Photochromism and photomagnetism in three cyano-bridged 3d-4f heterobimetallic viologen frameworks

2021 ◽  
Author(s):  
Meng-Hua Li ◽  
Ming-Hua You ◽  
Mei-Jin Lin
Keyword(s):  
Electrical Conductivity ◽  
Coordination Polymers ◽  
Porous Coordination Polymers

The incorporation of photochromic moieties into porous coordination polymers is of particular interest due to it can endow them various switchable functions in the electrical conductivity, luminescence, and magnetism. In...

Electrical Properties of Y0.06Sr0.94Ti0.6Fe0.4O3-δ-YSZ Composites as Electrode Materials

2016 ◽  
Vol 697 ◽  
pp. 327-330 ◽  
Author(s):  
Ke Shan ◽  
Xing Min Guo ◽  
Feng Rui Zhai ◽  
Zhong Zhou Yi
Keyword(s):  
Electrical Conductivity ◽  
Electrode Materials ◽  
Electronic Conductivity ◽  
Ionic Conductivities ◽  
Conductivity Measurement ◽  
Transference Numbers ◽  
Secondary Phases ◽  
Electrical Conductivity Measurement ◽  
Total Electrical Conductivity ◽  
Phase Compatibility

Y0.06Sr0.94Ti0.6Fe0.4O3-δ-YSZ composites were prepared by mixing Y, Fe co-doped SrTiO3 (Y0.06Sr0.94Ti0.6Fe0.4O3-δ known as YSTF) and 8 mol% Y2O3 stabilized ZrO2 (YSZ) in different weight fractions. The phase stability, phase compatibility, microstructure and mixed ionic-electronic conductivity of composites were investigated. Phase analysis by XRD showed no clearly detectable secondary phases. The electrical conductivity measurement on the YSTF-YSZ composites showed a drastic decrease in total electrical and ionic conductivities when more than 10 wt% of YSZ was used in the composites. The total electrical conductivity was 0.102 S/cm for Y0.06Sr0.94Ti0.6Fe0.4O3-δ and 0.043 S/cm for YSTF-20YSZ at 700 oC, respectively. The value at 700 oC is approximately 2.4 times higher than that of YSTF-20YSZ. The ionic conductivity of Y0.06Sr0.94Ti0.8Fe0.2O3-δ varies from 0.015S/cm at 700 oC to 0.02 S/cm at 800 oC, respectively. The value at 800°C is approximately 12.5 times higher than YSTF-20YSZ. The ion transference numbers of YSTF-YSZ composites vary from 0.14 to 0.28 at 800 °C.

Topological control in coordination polymers by solvent: the synthesis and structure of a novel 1D coordination polymer {[Co(μ-4,4′-bpy)(4,4′-bpy)2(NCS)2]·2DMF}n

2003 ◽  
Vol 649 (1-2) ◽  
pp. 111-115 ◽  
Author(s):  
Li-Na Zhu ◽  
Qing-Lun Wang ◽  
Wen-Zhen Wang ◽  
Dai-Zheng Liao ◽  
Zong-Hui Jiang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
1D Coordination Polymer
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