scholarly journals Characterization of the Fe metalloproteome of a ubiquitous marine heterotroph, Pseudoalteromonas (BB2-AT2): multiple bacterioferritin copies enable significant Fe storage

Metallomics ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 654-667
Author(s):  
Michael G. Mazzotta ◽  
Matthew R. McIlvin ◽  
Mak A. Saito
Keyword(s):  

Despite the extreme scarcity of Fe in seawater, the marine heterotroph Pseudoalteromonas has expansive Fe storage capacity and utilization strategies.

2013 ◽  
Vol 17 (2) ◽  
pp. 817-828 ◽  
Author(s):  
M. Stoelzle ◽  
K. Stahl ◽  
M. Weiler

Abstract. Streamflow recession has been investigated by a variety of methods, often involving the fit of a model to empirical recession plots to parameterize a non-linear storage–outflow relationship based on the dQ/dt−Q method. Such recession analysis methods (RAMs) are used to estimate hydraulic conductivity, storage capacity, or aquifer thickness and to model streamflow recession curves for regionalization and prediction at the catchment scale. Numerous RAMs have been published, but little is known about how comparably the resulting recession models distinguish characteristic catchment behavior. In this study we combined three established recession extraction methods with three different parameter-fitting methods to the power-law storage–outflow model to compare the range of recession characteristics that result from the application of these different RAMs. Resulting recession characteristics including recession time and corresponding storage depletion were evaluated for 20 meso-scale catchments in Germany. We found plausible ranges for model parameterization; however, calculated recession characteristics varied over two orders of magnitude. While recession characteristics of the 20 catchments derived with the different methods correlate strongly, particularly for the RAMs that use the same extraction method, not all rank the catchments consistently, and the differences among some of the methods are larger than among the catchments. To elucidate this variability we discuss the ambiguous roles of recession extraction procedures and the parameterization of the storage–outflow model and the limitations of the presented recession plots. The results suggest strong limitations to the comparability of recession characteristics derived with different methods, not only in the model parameters but also in the relative characterization of different catchments. A multiple-methods approach to investigating streamflow recession characteristics should be considered for applications whenever possible.


RSC Advances ◽  
2016 ◽  
Vol 6 (106) ◽  
pp. 104597-104607 ◽  
Author(s):  
Monika Wilamowska-Zawlocka ◽  
Paweł Puczkarski ◽  
Zofia Grabowska ◽  
Jan Kaspar ◽  
Magdalena Graczyk-Zajac ◽  
...  

We report here on the synthesis and characterization of silicon oxycarbide (SiOC) in view of its application as a potential anode material for Li-ion batteries.


2017 ◽  
Vol 5 (2) ◽  
pp. SF109-SF126 ◽  
Author(s):  
Yuxi Yu ◽  
Xiaorong Luo ◽  
Ming Cheng ◽  
Yuhong Lei ◽  
Xiangzeng Wang ◽  
...  

Shale oil and gas have been discovered in the lacustrine Zhangjiatan Shale in the southern Ordos Basin, China. To study the distribution of extractable organic matter (EOM) in the Zhangjiatan Shale ([Formula: see text] ranges from 1.25% to 1.28%), geochemical characterization of core samples of different lithologies, scanning electron microscope observations, low-pressure [Formula: see text] and [Formula: see text] adsorption, and helium pycnometry were conducted. The content and saturation of the EOM in the pores were quantitatively characterized. The results show that the distribution of the EOM in the shale interval is heterogeneous. In general, the shale layers have a higher EOM content and saturation than siltstone layers. The total organic content and the original storage capacity control the EOM content in the shale layers. For the siltstone layers, the EOM content is mainly determined by the original storage capacity. On average, 75% of the EOM occurs in the mesopores, followed by 14% in the macropores, and 11% in the micropores. The EOM saturation in the pores decreases with the increase in pore diameter. The distribution of EOM in the shale pores is closely related to the pore type. Micropores and mesopores developed in the kerogens and pyrobitumens and the clay-mineral pores coated with organic matter are most favorable for EOM retention and charging.


Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1038 ◽  
Author(s):  
Ubaldo Marín-Comitre ◽  
Susanne Schnabel ◽  
Manuel Pulido-Fernández

Watering ponds are an important source of drinking water supply for livestock in semi-arid rangelands. Understanding the hydrological functioning of this kind of infrastructures is crucial for efficient water management in areas where water resources are often scarce. In this line, we have analyzed temporal patterns of water availability in a set of watering ponds located in Iberian rangelands and their relationship with temporal rainfall variability. In addition, the effectiveness of the ponds for conserving stored water during dry periods and some influencing factors (pond size and catchment area) have also been assessed. The results showed a high correlation between water availability and precedent rainfall, confirming, on the one hand, the capacity of storage of these infrastructures and, on the other hand, the importance of temporal rainfall patterns in their hydrological behavior. Our findings point to a minimum pond area of 2000 m2 and a catchment area/storage capacity ratio around 100 m−1 in order for watering ponds can face the dry summer period with certain guarantees, at least in regular hydrological years. Nonetheless, the vulnerability shown by the majority of the watering ponds in times of drought limits their usefulness as unique sources of water supply in many farms.


2011 ◽  
Vol 347-353 ◽  
pp. 3298-3301
Author(s):  
Ye Xu ◽  
Jin Qiang Ma ◽  
Yuan Feng Xu ◽  
Hui Li ◽  
He Xing Li ◽  
...  

A series of Pd catalysts supported on different materials (SiO2, γ-Al2O3, CeO2, TiO2) were synthesized through precipitation reduction of palladium ions with H2. They exhibited different activity during catalytic oxidation of CO to CO2. With the characterization of N2 physisorption experiment, X-ray diffraction, transmission electron microscopy, temperature-programmed reduction, and CO and O2 multi-pulse experiment, the correlation of catalytic activity and oxygen storage capacity (OSC) of catalyst has been investigated. It was found that the reactivity is largely controlled by the OSC of the catalysts, and thus Pd/CeO2 and Pd/TiO2 were more active than Pd/SiO2 and Pd/Al2O3 for CO oxidation.


2015 ◽  
Vol 710 ◽  
pp. 3-7 ◽  
Author(s):  
Jan Fořt ◽  
Milena Pavlíková ◽  
Anton Trník ◽  
Zbyšek Pavlík

In order to decrease the energy consumption of buildings and keep the high thermal comfort of the indoor environment, new types of plasters modified by phase change material (PCM) are developed and experimentally tested. For evaluation of the contribution of PCM admixture to plasters properties, the reference plaster is studied as well. The basic characterization of the tested plasters is done using the measurement of their bulk density, matrix density a total open porosity. For the dry plasters mixtures, the particle size distribution is accessed on laser diffraction principle. Investigation of thermal properties as main parameters affecting the thermal performance of researched materials is done by differential scanning calorimetry (DSC) and transient impulse method. The obtained results proved increased heat storage capacity of the newly developed plasters with incorporated PCM admixture.


2013 ◽  
Vol 685 ◽  
pp. 123-127 ◽  
Author(s):  
Ajin C. Sajeevan ◽  
V. Sajith

One of the methods for the reduction of harmful emissions from diesel engines such as hydrocarbon, soot and NOx is the use of fuel born catalyst Cerium oxide. The oxygen storage capacity of Cerium oxide can be improved by coating it with metal such as Zirconium. Zr – Ce-O nanoparticles were synthesized by Co-precipitation method in the present work. Dynamic Light scattering, XRD pattern and UV-Visible spectroscopy were used for characterization of the prepared samples. Thermo gravimetric studies were conducted to investigate the thermal decomposition of Zr-Ce-O nanoparticles. The oxygen storage capacity of Zr-Ce-O nanoparticles was analyzed using TPR analysis.


2020 ◽  
Vol 32 (7) ◽  
pp. 1635-1641
Author(s):  
J. William Brown ◽  
D. Geetha ◽  
P.S. Ramesh ◽  
Surekha Podili

Hexagonal zirconia doped CuS nanaocomposites were successfully synthesized through a simple mild hydrothermal synthesis. The higher dopent concentration of zirconia produces increased mesoporous homogeneous nanostructures. The structure and nature of the resulting product (Zr-CuS) were characterized by XRD, XPS, SEM/EDS and TEM techniques. The results show that zirconia is homogeneously dispersed on CuS and well separated from one another. Electrochemical studies show that the final product (Zr-CuS) possesses high specific surface area. An increase in zirconia concentration might increase the mesopore volume and a widening of microporosity. Zirconia doped CuS composite exhibits high electrochemical performance with a high capacitance of 949.47 F g-1. The presence of zirconia in CuS improves the capacitive behaviour of samples. Therefore, Zr-CuS could be promising nanocomposite for energy storage device.


2015 ◽  
Vol 7 (1-2) ◽  
pp. 55-63 ◽  
Author(s):  
T. Debnath ◽  
L. Tashmim ◽  
C. H. Ruscher ◽  
A. Hussain

Nanocrystalline cerium (IV) oxide is a technologically important material due to its high oxygen storage capacity, oxygen ionic conductivity and thermal stability. In this paper we report preparation of nanocrystalline CeO2 using glycerin nitrate method, where the precursor obtained from the mixture of cerium nitrate and glycerin were calcined at temperatures ranging from 200°C to 800°C in steps of 100°C in a muffle furnace. Attempts were also made to prepare nanocrystalline cerium (IV) oxide doped with both Mg and Zr using the same method. The calcined specimens were characterized using XRD, FTIR and SEM/EDX analyses. The influence of the calcination temperature on the cubic phase formation and its consequent effect on the crystallite size of the prepared CeO2 were studied and interpreted. The crystallite sizes calculated from XRD data using Scherrer formula reveal that the phases are nanocrystals, which was further supported by SEM photograph. The apparent activation energy for crystalline coarsening is found to be very low (26.8 kJmol-1) for this precursor compared to reported data. XRD data and also EDX analysis shows that both Mg and Zr could also be doped in CeO2 upto a certain composition,         Ce1-x-yMgxZryO2-?(x = 0.05, y = 0.05).


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