A scalable synthesis of ternary nanocatalysts for a high-efficiency electrooxidation catalysis by microfluidics

Nanoscale ◽  
2020 ◽  
Vol 12 (23) ◽  
pp. 12647-12654
Author(s):  
Yingyan Zhou ◽  
Dumei Wang ◽  
Xueming Kang ◽  
Dongtang Zhang ◽  
Xiangnan Dou ◽  
...  

An array-channel continuous flow scale-up strategy based on a microchip for high dispersion of loaded PtFeCu/C nanocatalysts for nanomaterials’ synthesis is reported.

2017 ◽  
Vol 22 (5) ◽  
pp. 529-535 ◽  
Author(s):  
Minkyu Kim ◽  
Chia Min Leong ◽  
Ming Pan ◽  
Lucas R. Blauch ◽  
Sindy K. Y. Tang

This article describes an integrated platform for the on-chip exchange of the continuous phase in droplet microfluidic systems. The drops used in this work are stabilized by amphiphilic nanoparticles. For some characterizations and applications of these nanoparticle-stabilized drops, including the measurement of adsorption dynamics of nanoparticles to the droplet surface, it is necessary to change the composition of the continuous phase from that used during the droplet generation process. Thus far, no work has reported the exchange of the continuous phase for a large number (>1 million) of drops in a microfluidic system. This article describes the design and characterization of a high-efficiency and high-throughput on-chip exchanger of the continuous phase in a continuous-flow droplet microfluidic system. The efficiency of exchange was higher than 97%. The throughput was greater than 1 million drops/min, and this can be increased further by increasing the number of parallel exchangers used. Because drops are injected into the exchanger in a continuous-flow manner, the method is directly compatible with automation to further increase its reliability and potential scale-up.


RSC Advances ◽  
2019 ◽  
Vol 9 (40) ◽  
pp. 23021-23028 ◽  
Author(s):  
Nader Farahi ◽  
Christian Stiewe ◽  
D. Y. Nhi Truong ◽  
Johannes de Boor ◽  
Eckhard Müller

Considering the need for large quantities of high efficiency thermoelectric materials for industrial applications, a scalable synthesis method for high performance magnesium silicide based materials is proposed.


2019 ◽  
Author(s):  
Karolina Matuszek ◽  
R. Vijayaraghavan ◽  
Craig Forsyth ◽  
Surianarayanan Mahadevan ◽  
Mega Kar ◽  
...  

Renewable energy has the ultimate capacity to resolve the environmental and scarcity challenges of the world’s energy supplies. However, both the utility of these sources and the economics of their implementation are strongly limited by their intermittent nature; inexpensive means of energy storage therefore needs to be part of the design. Distributed thermal energy storage is surprisingly underdeveloped in this context, in part due to the lack of advanced storage materials. Here, we describe a novel family of thermal energy storage materials based on pyrazolium cation, that operate in the 100-220°C temperature range, offering safe, inexpensive capacity, opening new pathways for high efficiency collection and storage of both solar-thermal energy, as well as excess wind power. We probe the molecular origins of the high thermal energy storage capacity of these ionic materials and demonstrate extended cycling that provides a basis for further scale up and development.


1985 ◽  
Vol 50 (10) ◽  
pp. 2122-2133 ◽  
Author(s):  
Jindřich Zahradník ◽  
Marie Fialová ◽  
Jan Škoda ◽  
Helena Škodová

An experimental study was carried out aimed at establishing a data base for an optimum design of a continuous flow fixed-bed reactor for biotransformation of ammonium fumarate to L-aspartic acid catalyzed by immobilized cells of the strain Escherichia alcalescens dispar group. The experimental program included studies of the effect of reactor geometry, catalytic particle size, and packed bed arrangement on reactor hydrodynamics and on the rate of substrate conversion. An expression for the effective reaction rate was derived including the effect of mass transfer and conditions of the safe conversion-data scale-up were defined. Suggestions for the design of a pilot plant reactor (100 t/year) were formulated and decisive design parameters of such reactor were estimated for several variants of problem formulation.


Symmetry ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1325
Author(s):  
Zhongwei Gao ◽  
Changqing Pan ◽  
Chang-Ho Choi ◽  
Chih-Hung Chang

Water pollution is a growing global issue; there are many approaches to treating wastewater, including chemical coagulation, physical adsorption, and chemical oxidation. The photocatalysis process has provided a solution for removing pollutants from wastewater, where the pair of the photoelectron and hole works through an asymmetric way to degrade the contaminants under UV irradiation. This method offers an alternative route for treating the pollutant with a lower energy cost, high efficiency, and fewer byproducts. A continuous-flow microfluidic reactor has a channel size from tens to thousands of micrometers, providing uniform irradiation and short diffusion length. It can enhance the conversion efficiency of photocatalysis due to the simple spatial symmetry inside the microreactor channel and among the individual channels. In addition, the bandgap of TiO2, ZnO, or other photocatalyst nanoparticles with symmetric crystal structure can be modified through doping or embedding. In this mini-review, a review of the reported continuous-flow photocatalytic microfluidic reactor is discussed from the perspective of both microreactor design and material engineering.


2017 ◽  
Vol 13 ◽  
pp. 120-126 ◽  
Author(s):  
Christian H Hornung ◽  
Miguel Á Álvarez-Diéguez ◽  
Thomas M Kohl ◽  
John Tsanaktsidis

This work describes the Diels–Alder reaction of the naturally occurring substituted butadiene, myrcene, with a range of different naturally occurring and synthetic dienophiles. The synthesis of the Diels–Alder adduct from myrcene and acrylic acid, containing surfactant properties, was scaled-up in a plate-type continuous-flow reactor with a volume of 105 mL to a throughput of 2.79 kg of the final product per day. This continuous-flow approach provides a facile alternative scale-up route to conventional batch processing, and it helps to intensify the synthesis protocol by applying higher reaction temperatures and shorter reaction times.


Author(s):  
Jessica Orrego‐Hernández ◽  
Helen Hölzel ◽  
Maria Quant ◽  
Zhihang Wang ◽  
Kasper Moth‐Poulsen

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