scholarly journals Uncovering phase transformation, morphological evolution, and nanoscale color heterogeneity in tungsten oxide electrochromic materials

2020 ◽  
Vol 8 (38) ◽  
pp. 20000-20010
Author(s):  
Anyang Hu ◽  
Zhisen Jiang ◽  
Chunguang Kuai ◽  
Scott McGuigan ◽  
Dennis Nordlund ◽  
...  

Controlling the electrochemical interfacial processes that govern the durability of electrochromic devices represents a key challenge in developing sustainable and cost-effective smart windows.

2021 ◽  
pp. 99-108
Author(s):  
P.A. Shchur ◽  
◽  
L.V. Solovyanchik ◽  
S.V. Kondrashov ◽  
◽  
...  

Paper presents the most common materials for nanostructured inorganic electrochromic coatings, describes the methods of their formation. The prospects for the use of electrochromic materials in various industries – construction, auto and aircraft construction are considered. The analysis of modern methods for the formation of nanostructured electrochromic materials used in various fields of science and technology is presented. The prospects for the use of tungsten oxide, as well as the possibility of its modification in order to improve its functional electrochromic properties, are shown.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Inti Zumeta-Dubé ◽  
José Manuel García Rangel ◽  
Jorge Roque ◽  
Issis Claudette Romero-Ibarra ◽  
Mario Fidel García Sánchez

AbstractThe strong facet-dependent performance of glass-supported CeO2 thin films in different applications (catalysis, smart windows, etc.) has been the target of diverse fundamental and technological approaches. However, the design of accurate, cost-effective and scalable methods with the potential for large-area coverage that produce highly textured glass-supported CeO2 thin films remains a technological challenge. In the present work, it is demonstrated that under proper tuning conditions, the ultrasonic spray pyrolysis technique enables one to obtain glass-supported polycrystalline CeO2 films with noticeable texture along both the (100) and (111) directions, as well as with randomly oriented crystallites (no texture). The influence of flow rates, solution molarity, and substrate temperature on the texture and morphological characteristics, as well as optical absorption and Raman response of the deposited films, is evaluated. The obtained results are discussed on the basis of the combined dependence of the CeO2-exposed surfaces on the thermodynamic stability of the corresponding facets and the reaction kinetics, which modulate the crystallite growth direction.


2021 ◽  
Vol 335 ◽  
pp. 03008
Author(s):  
Khizar Mushtaq ◽  
Pui May Chou ◽  
Chin Wei Lai

Tungsten being a transition element, forms oxide compounds of various oxidation states that enables it to form nanocolloids of tungsten oxide dihydrate. Multiple methods have been used in recent years to synthesize nano tungsten oxide dihydrate, including sol-gel synthesis, electrochemical deposition, hydrothermal synthesis and anodization. However, a universally accepted synthesis method for this material is not offered. The most appropriate method and its corresponding processing parameters for the synthesis of nano tungsten oxide dihydrate colloids were presented in the present study. The objective of the present study was to investigate the effect of processing parameters, i.e. applied voltage, temperature and anodizing duration on the particle size of nanocolloids. It is found that anodization is the easiest, efficient, and cost-effective method to synthesize the colloidal solution of nano tungsten oxide dihydrate. Conducting the synthesis at room temperature at a voltage of 50 V for 60 minutes yields the product with particle size of 40 – 60 nm, which can be used in wide array of applications. This paper also highlights the research gaps for future work and gives recommendations to extend this study particularly for the industrial application of tungsten oxide.


2019 ◽  
Vol 1 (6) ◽  
pp. 1038-1045 ◽  
Author(s):  
Kai Rong ◽  
Hui Zhang ◽  
He Zhang ◽  
Yan-Yan Hu ◽  
Youxing Fang ◽  
...  

2017 ◽  
Vol 5 (36) ◽  
pp. 18919-18932 ◽  
Author(s):  
Andrea Paolella ◽  
Cyril Faure ◽  
Vladimir Timoshevskii ◽  
Sergio Marras ◽  
Giovanni Bertoni ◽  
...  

Well-known since the 18th century,hexacyanoferrate, or “Prussian blue”, is currently getting its “second life” as a promising material for Li-ion batteries and electrochromic devices.


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