scholarly journals Interaction of borohydride stabilized silver nanoparticles with sulfur-containing organophosphates

RSC Advances ◽  
2021 ◽  
Vol 11 (51) ◽  
pp. 32286-32294
Author(s):  
Shalini Shikha ◽  
Samit Dureja ◽  
Rachit Sapra ◽  
Jisha Babu ◽  
V. Haridas ◽  
...  

Understanding the interaction between borohydride ion stabilized Ag nanoparticles and sulfur bearing organophosphates is the key to developing cost-effective colorimetric pesticide detection technology.

2020 ◽  
Vol 11 (2) ◽  
pp. 8875-8883

The unrivaled features and prospective applications promote graphene as a potent contender for next-generation nanodevices. But the realization of a tunable bandgap structure for zero-bandgap graphene at all times persists as a dilemma. In this work, a green approach is adopted for the bandgap modulation of graphene oxide (GO). The biosynthesized silver nanoparticles (AgNPs) were introduced into the graphene matrix, and hence the bandgap was tailored for the formation of a semiconductor composite. The bare GO that has got a bandgap of 3.41 eV was tuned to 2.33 eV on the addition of AgNPs. The preparation of AgNPs using fruit extract of cyanococcus make the process greener, safer, and cost-effective. This paper intends to open a new venture towards the environment safe synthesis of semiconductor nanocomposite necessitate for optoelectronic and photovoltaic technologies.


2021 ◽  
Vol 9 (2) ◽  
pp. 214-230
Author(s):  
Surindra Negi ◽  
◽  
Vir Singh ◽  
Jyoti Rawat ◽  
◽  
...  

Heavy metal pollution is of great concern and cannot be ignored as heavy metals are highly mobile in soil and are recalcitrant. Nanotechnology provides a novel sustainable approach for synthesizing materials of desired properties, composition, and structure, it is however expected to adsorb heavy metals and play a significant role in water treatment. Green chemistry is the cost-effective, non-toxic, and environment friendly approach that involves the use of biological components as reducing and stabilizing agents for the synthesis of nanoparticles. In the present study, heavy metals such as cadmium (Cd II) and lead (Pb II) were successfully removed from its aqueous solution by an adsorption process using the silver nanoparticles of size ~15nm biosynthesized using freshwater algal extract. The adsorption peak at 411 nm confirms the formation of silver nanoparticles. The maximum value of metal ion adsorption capacity (23.98 mg/g) was observed for Pb (II). The higher value of R2 showed that the experimental data were fitted best with Langmuir isotherm. The rate kinetics study showed that Pb (II) adsorption on Ag nanoparticles followed pseudo-second order kinetics (R2>0.9) indicating that Pb (II) was attached to the nanoparticles surface through electrostatic force of attraction, also referred to as chemisorption whereas Cd (II) adsorption on Ag nanoparticles followed pseudo-first order kinetics (R2 >0.8) indicating physical adsorption between adsorbate and adsorbent.


2018 ◽  
Vol 10 (37) ◽  
pp. 4518-4524 ◽  
Author(s):  
Qijun Dai ◽  
Te Wei ◽  
Changli Lv ◽  
Fang Chai

In this study, we have reported a facile, cost-effective method for the synthesis of silver nanoparticles (Ag NPs) using uric acid (UA) as the reducing agent.


2020 ◽  
Vol 13 ◽  
Author(s):  
Kumari Jyoti ◽  
Punyasloka Pattnaik ◽  
Tej Singh

Background:: Synthesis of metallic nanoparticles has attracted extensive vitality in numerous research areas such as drug delivery, biomedicine, catalysis etc. where continuous efforts are being made by scientists and engineers to investigate new dimensions for both technological and industrial advancements. Amongst numerous metallic nanoparticles, silver nanoparticle (AgNPs) is a novel metal species with low toxicity, higher stability and significant chemical, physical and biological properties. Methods:: In this, various methods for the fabrication of AgNPs are summarized. Importantly, we concentrated on the role of reducing agents of different plants parts, various working conditions such as AgNO3 concentration; ratio of AgNO3/extract; incubation time; centrifugal conditions, size and shapes. Results:: This study suggested that eco-friendly and non toxic biomolecules present in the extracts (e.g. leaf, stem and root) of plants are used as reducing and capping agents for silver nanoparticles fabrication. This method of fabrication of silver nanoparticles using plants extracts is comparatively cost-effective and simple. A silver salt is simply reduced by biomolecules present in the extracts of these plants. In this review, we have emphasized the synthesis and antibacterial potential of silver nanoparticles using various plant extracts. Conclusion:: Fabrication of silver nanoparticles using plant extracts have advantage over the other physical methods, as it is safe, eco-friendly and simple to use. Plants have huge potential for the fabrication of silver nanoparticles of wide potential of applications with desired shape and size.


2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Ram Prasad ◽  
Vyshnava Satyanarayana Swamy

The unique property of the silver nanoparticles having the antimicrobial activity drags the major attention towards the present nanotechnology. The environmentally nontoxic, ecofriendly, and cost-effective method that has been developed for the synthesis of silver nanoparticles using plant extracts creates the major research interest in the field of nanobiotechnology. The synthesized silver nanoparticles have been characterized by the UV-visible spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM). Further, the antibacterial activity of silver nanoparticles was evaluated by well diffusion method, and it was found that the biogenic silver nanoparticles have antibacterial activity against Escherichia coli (ATCC 25922), Staphylococcus aureus (ATCC 29213), Pseudomonas aeruginosa (ATCC 27853), Azotobacter chroococcum WR 9, and Bacillus licheniformis (MTCC 9555).


2012 ◽  
Vol 1371 ◽  
Author(s):  
M.I. Hernández-Castillo ◽  
O. Zaca-Moran ◽  
P. Zaca-Moran ◽  
M. Rojas-López ◽  
V.L. Gayou ◽  
...  

ABSTRACTBy using the citrate reduction procedure we have synthesized Ag nanoparticles, applying several conditions of preparation, being after characterized by UV-visible spectrophotometry. Following a logical sequence, the starting experiment was realized varying the reaction time, after that it was varied the concentration of the reductor agent, and finally it was varied the volume of the reductor agent. According to this methodology, TEM measurements show that firstly we have nanostructures with different shape and size, whereas in the last part of the experiment we have Ag nanoparticles with homogeneous shape and size.


2013 ◽  
Vol 756 ◽  
pp. 99-105
Author(s):  
Rajasingam Ratnamalar ◽  
Mustapha Mariatti ◽  
Zulkifli Ahmad ◽  
Sharif Zein Sharif Hussein

This work reports a simple chemical reduction route for the preparation of uniformed Ag nanoparticles whereby a fine control over the sizes of the Ag nanoparticles was studied by varying the concentrations of the reducing agents used. In characterization, UV-Vis spectroscopy showed the changes in optical properties of the Ag nanoparticles with regards to their sizes, where as the XRD patterns of the synthesized Ag nanoparticles confirmed the distinct peaks approximately at 2θ = 38.1°, 44.3°, 64.4°, 77.4°, and 81.5 representing Bragg’s reflections from (111), (200), (220), (311), and (222) planes of the face centred cubic lattice phase. This route of synthesis is feasible to produce Ag nanoparticles with diameters in the range of 30-45 nm.


2020 ◽  
Vol 36 (6) ◽  
pp. 1103-1106
Author(s):  
Darwin F. Reyes ◽  
Gil Fabien S. Cabrera ◽  
Shemma Mica V. Mata ◽  
azmin Pariz D. San Pedro ◽  
add Christian C. Palioc ◽  
...  

The synthesis of silver nanoparticles via plant-mediated approach is an emerging area of research interest worldwide. The procedure is cost-effective and does not require the use of toxic chemicals and complicated reaction conditions. In the present investigation, silver nanoparticles were prepared using the leaf extracts of Ixora coccinea Linn., a common ornamental shrub in the Philippines, as the reducing agent. The effect of pH on the synthesis was investigated, and results showed that the quality of the synthesized silver nanoparticles changes in varying pH of the reducing agent.


2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Moira Carmalita Dharsika Niluxsshun ◽  
Koneswaran Masilamani ◽  
Umaramani Mathiventhan

Wide application of nanoparticles motivates the need for synthesising them. Here, a nontoxic, eco-friendly, and cost-effective method has been established for the synthesis of silver nanoparticles using extracts of lemon peel (Citrus limon), green orange peel (Citrus sinensis), and orange peel (Citrus tangerina). The synthesised nanoparticles have been characterised using UV-visible absorptionspectroscopy, Fourier transform infrared spectroscopy, and transmission electron microscopy (TEM). The UV-visible absorption spectrum of these synthesised silver nanoparticles shows an absorption peak at around 440 nm. TEM images show different shaped particles with various sizes. Furthermore, the antibacterial activity of silver nanoparticles was appraised by a well-diffusion method and it was observed that the green synthesised silver nanoparticles have an effective antibacterial activity against Escherichia coli and Staphylococcus aureus. The outcome of this study could be beneficial for nanotechnology-based biomedical applications.


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